Safety Data Sheet
Product Identifier Big D Metered Insecticide (EPA Reg. 44446-56-7052)
Other Means of
Identification
047000 & A0447006
Other Identification Metered Insecticide
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Specialty Chemicals & Systems
Emergency Phone No.
SECTION 1. IDENTIFICATION
Manufacturer
Insecticide.
0444
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Warning
Hazard Statement(s):
Flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes eye irritation.
Precautionary Statement(s):
Prevention:
Keep away from heat, sparks, open flames, and hot surfaces. – No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Wash hands and skin thoroughly after handling.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
GHS Classification
Flammable aerosol - Category 2; Gas under pressure - Liquefied gas; Serious eye damage/eye irritation - Category 2B
SDS No.:
Date of Preparation:
0444 Page
of
0601
April 09, 2015
Product Identifier: Big D Metered Insecticide (EPA Reg. 44446-56-7052)
Big D Metered Insecticide (EPA Reg. 44446-56-7052)
Storage:
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
Disposal:
Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Hydrotreated kerosene 64742-47-8 60-100
Petroleum gases, liquefied, sweetened 68476-86-8 10-30
MGK 264 113-48-4 3.00
Piperonyl butoxide 51-03-6 1.80
Inhalation
Move to fresh air. If breathing has stopped, trained personnel should begin rescue breathing. Call a Poison Centre
or doctor.
Skin Contact
Take off immediately contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Immediately rinse
with lukewarm, gently flowing water for 15-20 minutes. If skin irritation occurs get medical advice/attention.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open. Seek medical advice.
Ingestion
Rinse mouth with water. Get medical advice/attention if you feel unwell or are concerned. Do not induce vomiting. If
vomiting occurs naturally, lie on your side in the recovery position. Rinse mouth with water again.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
Respiratory conditions, cardiovascular conditions.
Most Important Symptoms and Effects, Acute and Delayed
If inhaled:
A severe exposure can cause unconsciousness.
If on skin:
May cause mild irritation.
If in eyes:
May cause mild irritation.
If swallowed:
Symptoms may include nausea, vomiting, stomach cramps and diarrhea.
Suitable Extinguishing Media
SECTION 5. FIRE-FIGHTING MEASURES
SDS No.:
Date of Preparation:
0444 Page
of
0602
April 09, 2015
Product Identifier: Big D Metered Insecticide (EPA Reg. 44446-56-7052)
Suitable Extinguishing Media
Carbon dioxide, dry chemical powder or appropriate foam. Special "alcohol resistant fire-fighting foams".
Specific Hazards Arising from the Chemical
Can ignite if strongly heated.
Closed containers may rupture violently when heated releasing contents.
Very toxic carbon monoxide, carbon dioxide.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
A full-body encapsulating chemical protective suit with positive pressure SCBA may be necessary.
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
Do not allow into any sewer, on the ground or into any waterway.
Methods and Materials for Containment and Cleaning Up
Ventilate the area to prevent the gas from accumulating, especially in confined spaces. Contain and soak up spill with
absorbent that does not react with spilled product.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
No special handling precautions are necessary.
It is good practice to: avoid breathing product; avoid skin and eye contact and wash hands after handling.
Conditions for Safe Storage
Store in an area that is: cool, out of direct sunlight and away from heat and ignition sources. Protect from conditions
listed in Conditions to Avoid in Section 10 (Stability and Reactivity).
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Hydrotreated kerosene 400 ppm 400 ppm
Petroleum gases, liquefied,
sweetened
1000 ppm
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Not normally required if product is used as directed.
Not required, if used as directed.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
The hazard potential of this product is relatively low. General ventilation is usually adequate.
Appearance Amber - yellow.
Odour Gasoline-like
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
SDS No.:
Date of Preparation:
0444 Page
of
0603
April 09, 2015
Product Identifier: Big D Metered Insecticide (EPA Reg. 44446-56-7052)
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Odour
Vapour Pressure 0.4 mm Hg (0.1 kPa) at 77 ºF (25 ºC)
Odour Threshold Not available
Vapour Density (air = 1) < 6
Initial Boiling Point/Range 232 ºC (450 ºF)
Evaporation Rate < 1 (n-butyl acetate = 1)
Flash Point > 200 ºF (93 ºC)
Melting Point/Freezing Point Not available (melting); Not available (freezing)
Relative Density (water = 1) 0.82 at 77 ºF (25 ºC)
Upper/Lower Flammability or
Explosive Limit
6.0% (upper); 1.0% (lower)
Solubility Insoluble in water
Auto-ignition Temperature 188 ºC (370 ºF)
LiquidPhysical State
Other Information
Flammability (solid, gas) Flammable gas.
Chemical Stability
Normally stable.
Conditions to Avoid
Open flames, sparks, static discharge, heat and other ignition sources. Temperatures above 122.0 ºF (50.0 ºC)
Incompatible Materials
Strong oxidizing agents (e.g. perchloric acid).
Hazardous Decomposition Products
Very toxic carbon monoxide, carbon dioxide.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
Skin Corrosion/Irritation
No information was located.
Serious Eye Damage/Irritation
No information was located.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
Acute Toxicity
Inhalation; skin contact; ingestion.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Hydrotreated kerosene 5 mg/L (rat) (4-hour
exposure)
5000 mg/kg (rat) 2000 mg/kg (rabbit)
SDS No.:
Date of Preparation:
0444 Page
of
0604
April 09, 2015
Product Identifier: Big D Metered Insecticide (EPA Reg. 44446-56-7052)
Inhalation
A severe exposure can cause unconsciousness.
Skin Absorption
No information was located.
Ingestion
No information was located.
Symptoms may include nausea, vomiting, stomach cramps and diarrhea.
Concentrating vapors and inhaling material can lead to oxygen deprivation, loss of brain function and potential loss of
life.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
Not specifically listed.
No information was located.
Development of Offspring
No information was located.
No information was located.
Reproductive Toxicity
No information was located.
No information was located.
Germ Cell Mutagenicity
No information was located.
No information was located.
Interactive Effects
No information was located.
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
No information was located.
Aspiration Hazard
This product or its degradation products are expected to bioaccumulate.
If released into the environment, this product can move rapidly through the soil.
There is no information available.
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
No information was located.
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
SECTION 13. DISPOSAL CONSIDERATIONS
The required hazard evaluation of the waste and compliance with the applicable hazardous waste laws are the
responsibility of the user.
Disposal Methods
SDS No.:
Date of Preparation:
0444 Page
of
0605
April 09, 2015
Product Identifier: Big D Metered Insecticide (EPA Reg. 44446-56-7052)
SECTION 14. TRANSPORT INFORMATION
UN No. Proper Shipping Name
Packing
Group
Transport Hazard
Class(es)
Regulation
1950
AEROSOLS
2.1
US DOT
1950
AEROSOLS
2.1
IATA (Air)
1950
AEROSOLS
2.1
IMO (Marine)
Special Precautions
for User
Please note: US DOT Exceptions: LTD QTY (See CFR)(Ground)
Environmental
Hazards
Marine Pollutant
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
Safety, Health and Environmental Regulations
Additional Information
This product is not classified or registered for use outside the USA.
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
April 09, 2015
Revision Indicators
Not applicable.
Health - 2 Flammability - 3 Instability - 0
SDS No.:
Date of Preparation:
0444 Page
of
0606
April 09, 2015
Product Identifier: Big D Metered Insecticide (EPA Reg. 44446-56-7052)
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