Big D Aerosol Room Deodorant
Product Identifier Big D Aerosol Room Deodorant
Other Means of
Identification
351, 425, 426, 429, 430, 431, 433, & 434
Other Identification Aerosol Room Deodorant
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Aerosol Products
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Manufacturer
Air Freshener.
0245
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
Extremely flammable aerosol.
Harmful to aquatic life.
Harmful to aquatic life with long lasting effects.
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Avoid release to the environment.
Note:
17.52% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment.
17.52% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment.
GHS Classification
Flammable aerosol - Category 1; Aquatic hazard (Acute) - Category 3; Aquatic hazard (Chronic) - Category 3
SDS No.:
Date of Preparation:
0245 Page
of
0601
July 12, 2014
Product Identifier: Big D Aerosol Room Deodorant
Safety Data Sheet
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Other components below reportable Levels No CAS 80-90
Ethanol 64-17-5 2.5-10
n-Butane 106-97-8 2.5-10
Propane 74-98-6 2.5-10
Sodium nitrite 7632-00-0 0.1-1.0
Inhalation
Move to fresh air. Call a Poison Centre or doctor if you feel unwell or are concerned.
Skin Contact
Immediately rinse with lukewarm, gently flowing water for 15-20 minutes. Call a Poison Centre or doctor if you feel
unwell or are concerned.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open. If eye irritation persists, get medical advice/attention.
Ingestion
Call a Poison Centre or doctor if you feel unwell or are concerned.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Target Organs
Nervous system, lungs.
Most Important Symptoms and Effects, Acute and Delayed
If inhaled:
Can irritate the nose and throat. A severe exposure can cause unconsciousness.
If on skin:
Causes mild irritation.
If swallowed:
Can irritate the mouth, throat and stomach.
Extinguishing Media
Suitable Extinguishing Media
Carbon dioxide, dry chemical powder, appropriate foam, water spray or fog.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Flammable aerosol.
Closed containers may rupture violently when heated releasing contents.
Irritating chemicals; toxic chemicals.
Special Protective Equipment and Precautions for Fire-fighters
Toxic gases or vapours.
Chemical protective clothing (e.g. chemical splash suit) and positive pressure SCBA may be necessary.
SECTION 5. FIRE-FIGHTING MEASURES
SDS No.:
Date of Preparation:
0245 Page
of
0602
July 12, 2014
Product Identifier: Big D Aerosol Room Deodorant
Personal Precautions, Protective Equipment, and Emergency Procedures
Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. May
accumulate in hazardous amounts in low-lying areas especially inside confined spaces, if ventilation is not sufficient.
Evacuate downwind locations. Use the personal protective equipment recommended in Section 8 of this safety data
sheet.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
Small spills or leaks: contain and soak up spill with absorbent that does not react with spilled product.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
Only use where there is adequate ventilation.
Conditions for Safe Storage
Store in an area that is: cool, ventilated, out of direct sunlight and away from heat and ignition sources.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Ethanol 1000 ppm 1000 ppm
n-Butane 1000 ppm 800 ppm
Propane 1000 ppm 1000 ppm
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Concentrated product: wear a NIOSH approved air-purifying respirator with an organic vapour cartridge. Not
normally required if product is used as directed.
Wear chemical protective clothing e.g. gloves, aprons, boots.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
General ventilation is usually adequate.
pH Not available
Appearance compressed gas.
Odour Floral
Odour Threshold Not available
Initial Boiling Point/Range Not available
Evaporation Rate Not available
Flash Point -87.51 ºF (-66.39 ºC) (estimated)
Melting Point/Freezing Point Not available (melting); Not available (freezing)
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
SDS No.:
Date of Preparation:
0245 Page
of
0603
July 12, 2014
Product Identifier: Big D Aerosol Room Deodorant
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Vapour Pressure Not available
Vapour Density (air = 1) Not available
Relative Density (water = 1) ~ 0.9451 at 20 ºC
Upper/Lower Flammability or
Explosive Limit
Not available (upper); Not available (lower)
Solubility Slightly soluble in water
Auto-ignition Temperature Not available
Molecular Formula Not applicable
Molecular Weight Not applicable
Not availableDecomposition Temperature
Viscosity Not available (kinematic)
LiquidPhysical State
Other Information
Flammability (solid, gas) Extremely flammable gas.
Chemical Stability
Normally stable.
Conditions to Avoid
High temperatures. Open flames, sparks, static discharge, heat and other ignition sources.
Incompatible Materials
None known.
Hazardous Decomposition Products
Irritating chemicals; toxic chemicals.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
SECTION 11. TOXICOLOGICAL INFORMATION
Carcinogenicity
Acute Toxicity
Not known to be an aspiration hazard.
Aspiration Hazard
Inhalation; skin contact; eye contact; ingestion.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Ethanol 20000 ppm (rat) 7060 mg/kg (rat)
n-Butane 680 mg/L (mouse) (2-hour
exposure)
Propane 658 mg/L (rat) (4-hour
exposure)
Sodium nitrite 85 mg/kg (rat) 186 mg/kg (rabbit)
SDS No.:
Date of Preparation:
0245 Page
of
0604
July 12, 2014
Product Identifier: Big D Aerosol Room Deodorant
Reproductive Toxicity
No information was located for: Skin Corrosion/Irritation, Serious Eye Damage/Irritation, STOT (Specific Target Organ
Toxicity) - Single Exposure, STOT (Specific Target Organ Toxicity) - Repeated Exposure, Respiratory and/or Skin
Sensitization, Development of Offspring, Sexual Function and Fertility, Germ Cell Mutagenicity, Interactive Effects
Effects on or via Lactation
No information was located.
Chemical Name IARC ACGIH® NTP OSHA
Ethanol Group 1 A3
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
Toxicity
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea
ErC50 Aquatic
Plants
ErC50 Algae
Sodium nitrite 0.15-0.25 mg/L
(Oncorhynchus
mykiss (rainbow
trout); 96-hour)
16.14-26.61 mg/L
(48-hour)
SECTION 13. DISPOSAL CONSIDERATIONS
The required hazard evaluation of the waste and compliance with the applicable hazardous waste laws are the
responsibility of the user.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
UN No. Proper Shipping Name
Packing
Group
Transport Hazard
Class(es)
Regulation
1950
AEROSOLS
2.1
US DOT
1950
AEROSOLS
2.1
Canadian TDG
Special Precautions
for User
Please note: US DOT Exceptions: LTD QTY (See CFR)(Ground)
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Safety, Health and Environmental Regulations
Class B5 Class D2B
B5 - Flammable Aerosol; D2B - Toxic
SDS No.:
Date of Preparation:
0245 Page
of
0605
July 12, 2014
Product Identifier: Big D Aerosol Room Deodorant
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
USA
US OSHA HazCom 1994 Regulatory Status
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200 (1994)).
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
Additional USA Regulatory Lists
Pennsylvania Right To Know. (Ethanol). (n-Butane). (Propane)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
July 12, 2014
Health - 1 Flammability - 2
SDS No.:
Date of Preparation:
0245 Page
of
0606
July 12, 2014
Product Identifier: Big D Aerosol Room Deodorant
Loading...