Big D Industries 374 User Manual

Big D Odor Control Fogger
Product Identifier Big D Odor Control Fogger Other Means of
Identification
341, 342, 343, 344, 345, & 374
Other Identification Odor Control Fogger
Recommended Use
SDS No.
Product Family aerosol
Emergency Phone No.
SECTION 1. IDENTIFICATION
Supplier
Manufacturer
Air Freshener.
0241
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word: Danger
H222 Extremely flammable aerosol. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H402 Harmful to aquatic life. H412 Harmful to aquatic life with long lasting effects.
P210 Keep away from sparks and open flames. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P261 Avoid breathing gas. P264 Wash hands and skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear eye protection/face protection. P273 Avoid release to the environment.
GHS Classification
Flammable aerosol - Category 1; Serious eye damage/eye irritation - Category 2A; Specific target organ toxicity (single exposure) - Category 3; Aquatic hazard (Acute) - Category 2; Aquatic hazard (Chronic) - Category 2
SDS No.: Date of Preparation:
0241 Page
of
0701
Product Identifier: Big D Odor Control Fogger
Safety Data Sheet
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Acetone 67-64-1 60-80 n-Butane 106-97-8 10-20 Propane 74-98-6 10-20 Other components below reportable Levels No CAS 2.5-10
Inhalation
Move to fresh air. Call a Poison Centre or doctor if you feel unwell or are concerned.
Skin Contact
Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes. If skin irritation occurs get medical advice/attention.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the eyelid(s) open. Remove contact lenses, if present and easy to do. If eye irritation persists, get medical advice/attention.
Ingestion
Call a Poison Centre or doctor if you feel unwell or are concerned.
First-aid Comments
Get medical advice/attention if you feel unwell or are concerned.
Special Instructions
Not applicable.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
May cause moderate to severe irritation.
Extinguishing Media
Suitable Extinguishing Media
Carbon dioxide, dry chemical powder or appropriate foam.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Closed containers may rupture violently when heated releasing contents. In a fire, the following hazardous materials may be generated: flammable chemicals; irritating chemicals; toxic chemicals; very toxic carbon monoxide, carbon dioxide.
Special Protective Equipment and Precautions for Fire-fighters
SECTION 5. FIRE-FIGHTING MEASURES
SDS No.: Date of Preparation:
0241 Page
of
0702
Product Identifier: Big D Odor Control Fogger
For a massive fire, immediately evacuate the area and use unmanned hose holder or monitor nozzles. Fire-fighters may enter the area if positive pressure SCBA and full Bunker Gear is worn.
Personal Precautions, Protective Equipment, and Emergency Procedures
Evacuate the area immediately. Isolate the hazard area. Keep out unnecessary and unprotected personnel. Use the personal protective equipment recommended in Section 8 of this safety data sheet. Do not touch damaged containers or spilled product unless wearing appropriate protective equipment.
Environmental Precautions
Do not allow into any sewer, on the ground or into any waterway. It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
Review Section 7 (Handling) of this safety data sheet before proceeding with clean-up. Ventilate the area to prevent the gas from accumulating, especially in confined spaces.
Other Information
Report spills to local health, safety and environmental authorities, as required.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
Do not puncture or incinerate container even when empty. Do not spray on an open flame or other ignition source. Do not pierce or burn container, even after use. Prevent heating. Do not use near welding operations or other high energy sources. Only use where there is adequate ventilation. Avoid breathing in this product. Prevent skin contact. Do not get in eyes. Wash hands thoroughly after handling this material.
Conditions for Safe Storage
Restrict access to authorized personnel only. Store in an area that is: temperature-controlled, well-ventilated, out of direct sunlight and away from heat and ignition sources.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Acetone 500 ppm 750 ppm 1000 n-Butane 1000 ppm 800 ppm Propane 1000 ppm 1000 ppm
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Not normally required if product is used as directed.
Wear chemical protective clothing e.g. gloves, aprons, boots.
Wear chemical safety goggles and face shield when contact is possible.
General ventilation is usually adequate.
Appearance Clear gas.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
SDS No.: Date of Preparation:
0241 Page
of
0703
Product Identifier: Big D Odor Control Fogger
pH Not available
Partition Coefficient, n-Octanol/Water (Log Kow)
2.36 at 20 ºC (68 ºF) (estimated) (Propane)
Odour Not available
Vapour Pressure ~ 18009.40 mm Hg (2401.25 kPa) at 68 ºF (estimated)
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range Not available
Evaporation Rate Not available
Flash Point < -156.00 ºF (-104.44 ºC) (estimated) (Acetone)
Melting Point/Freezing Point Not available (melting)
Relative Density (water = 1) ~ 0.701 (estimated) at 20 ºC (68 ºF)
Upper/Lower Flammability or Explosive Limit
Not available (upper); Not available (lower)
Solubility Not available in water; Not available (in other liquids)
Auto-ignition Temperature Not available
Not availableDecomposition Temperature
Viscosity Not available (kinematic); Not available (dynamic)
Other Physical Property 3 Color: Not Available
Form: Aerosol Physical State: Gas
GasPhysical State
Other Information
Flammability (solid, gas) Not available
Chemical Stability
Normally stable.
Conditions to Avoid
High temperatures. Temperatures above 122.0 ºF (50.0 ºC)
Incompatible Materials
None known. Not corrosive to metals.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None expected under normal conditions of storage and use.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions of use.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Information presented below is for the entire product, unless otherwise specified.
Ingestion; inhalation; skin contact; eye contact.
Likely Routes of Exposure
SDS No.: Date of Preparation:
0241 Page
of
0704
Product Identifier: Big D Odor Control Fogger
Skin Corrosion/Irritation
Human experience and animal tests show no or very mild irritation.
Serious Eye Damage/Irritation
Human experience shows serious eye irritation.
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
May be harmful based on information for closely related materials.
Skin Absorption
No information was located.
Ingestion
Not a relevant route of exposure (gas).
Not harmful based on information for closely related chemicals.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
Not known to be a respiratory sensitizer. Not known to be a skin sensitizer.
Carcinogenicity
Not known to cause cancer.
Development of Offspring
Not known to harm the unborn child.
Reproductive Toxicity
Not known to cause effects on sexual function or fertility.
Germ Cell Mutagenicity
Not mutagenic.
Interactive Effects
No information was located.
Sexual Function and Fertility
Effects on or via Lactation
Not known to cause effects on or via lactation.
Not known to be an aspiration hazard.
Aspiration Hazard
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Acetone 76 mg/kg (mouse) (4-hour
exposure) (gas)
5800 mg/kg (rat) 20000 mg/kg (rabbit)
n-Butane 680 mg/L (mouse) (2-hour
exposure)
Propane 658 mg/L (rat) (4-hour
exposure)
Chemical Name IARC ACGIH® NTP OSHA
Acetone A4
Harmful, with long lasting effects to aquatic life.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Acute Aquatic Toxicity
SDS No.: Date of Preparation:
0241 Page
of
0705
Product Identifier: Big D Odor Control Fogger
This product or its degradation products are expected to bioaccumulate.
Studies are not available.
There is no information available.
No information was located.
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea
ErC50 Aquatic Plants
ErC50 Algae
Acetone 4740-6330 mg/L
(Oncorhynchus mykiss (rainbow trout); 96-hour; fresh water)
21.6-23.9 mg/L (Daphnia magna (water flea); 48-hour; fresh water)
SECTION 13. DISPOSAL CONSIDERATIONS
This product and its container must be disposed of as hazardous waste. Do NOT dump into any sewers, on the ground or into any body of water. The required hazard evaluation of the waste and compliance with the applicable hazardous waste laws are the responsibility of the user.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
UN No. Proper Shipping Name
Packing
Group
Transport Hazard
Class(es)
Regulation
1950
Aerosols, flammable
2.1
US DOT
1950
Aerosols, flammable
2.1
IATA (Air)
1950
Aerosols,Marine Pollutant
2
IMO (Marine)
Special Precautions for User
Please note: This material is classified as a Marine Pollutant per IMDG
Other Information
DOT: This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity.
Emergency Response Guide No.
10L
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
USA
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all of the information required by the Controlled Products Regulations.
Safety, Health and Environmental Regulations
SDS No.: Date of Preparation:
0241 Page
of
0706
Product Identifier: Big D Odor Control Fogger
Additional USA Regulatory Lists
CERCLA. (Acetone) US Federal. (Acetone) New Jersey Right To Know. (Propane). (n-Butane) Pennsylvania Right To Know. (Acetone). (n-Butane). (Propane)
SECTION 16. OTHER INFORMATION
NFPA Rating SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Health - 1 Flammability - 3 Instability - 0
SDS No.: Date of Preparation:
0241 Page
of
0707
Product Identifier: Big D Odor Control Fogger
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