Safety Data Sheet
Product Identifier Big D Deodorant Concentrate, Cherry
Other Means of
Identification
121300, 321300, 421300, 521300, & C0421303
Other Identification Deodorant Concentrate, Cherry
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Liquid Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Manufacturer
Deodorant.
0408
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
Hazard Statement(s):
Causes serious eye damage.
Precautionary Statement(s):
Prevention:
Wear eye protection/face protection.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a POISON CENTRE/doctor.
GHS Classification
Serious eye damage/eye irritation - Category 1
SDS No.:
Date of Preparation:
0408 Page
of
0701
March 27, 2015
Product Identifier: Big D Deodorant Concentrate, Cherry
Big D Deodorant Concentrate, Cherry
Storage:
Store in accordance with local, regional, national and international regulations.
Disposal:
Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Other components below reportable Levels No CAS 92.76
Poly(oxy-1,2-ethanediyl), alpha-octyl- omega
-hydroxy-
27252-75-1 3.50
2-Propanol 67-63-0 1.81
Benzaldehyde 100-52-7 0.92
Dipropylene glycol monomethyl ether 34590-94-8 0.48
Ethyl acetate 141-78-6 0.23
Benzyl acetate 140-11-4 0.15
n-Amyl acetate 628-63-7 0.15
Inhalation
Move to fresh air.
Skin Contact
Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open.
Ingestion
Call a Poison Centre or doctor if you feel unwell or are concerned. Rinse mouth with water.
Special Instructions
Not applicable.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
If on skin:
May cause mild irritation.
Extinguishing Media
Suitable Extinguishing Media
Not combustible. Use extinguishing agent suitable for surrounding fire.
SECTION 5. FIRE-FIGHTING MEASURES
SDS No.:
Date of Preparation:
0408 Page
of
0702
March 27, 2015
Product Identifier: Big D Deodorant Concentrate, Cherry
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Does not burn.
This product presents no unusual hazards in a fire situation.
Not known to generate any hazardous decomposition products in a fire.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
Chemical protective clothing (e.g. chemical splash suit) and positive pressure SCBA may be necessary.
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
Contain and soak up spill with absorbent that does not react with spilled product.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
No special handling precautions are necessary.
Conditions for Safe Storage
No special requirements for storage area.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
2-Propanol 200 ppm 400 ppm 980 mg/m3
Dipropylene glycol monomethyl ether 100 ppm 150 ppm 600 mg/m3
Ethyl acetate 400 ppm 1400
mg/m3
Benzyl acetate 10 ppm
n-Amyl acetate 50 ppm 100 ppm 525 mg/m3
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Eye/Face Protection
ACGIH® = American Conference of Governmental Industrial Hygienists. TWA = Time-Weighted Average. STEL =
Short-term Exposure Limit.
Not required, if used as directed.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
The hazard potential of this product is relatively low. General ventilation is usually adequate.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
SDS No.:
Date of Preparation:
0408 Page
of
0703
March 27, 2015
Product Identifier: Big D Deodorant Concentrate, Cherry
pH Not available
Appearance liquid. Particle Size: Not applicable
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Odour Fragrant (Fragrance)
Vapour Pressure Not available
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range > 212 ºF (100 ºC)
Evaporation Rate Not available
Flash Point > 200 ºF (93 ºC) (closed cup)
Melting Point/Freezing Point Not available (melting); Not available (freezing)
Relative Density (water = 1) ~ 1 at 68 ºF (20 ºC)
Upper/Lower Flammability or
Explosive Limit
Not available (upper); Not available (lower)
Solubility Soluble in all proportions in water; Not available (in other liquids)
Auto-ignition Temperature Not available
Molecular Formula Not applicable
Molecular Weight Not applicable
Not availableDecomposition Temperature
Bulk Density Not available
Viscosity Not available (kinematic)
Surface Tension Not available
Vapour Pressure at 50 deg C Not available
Saturated Vapour Concentration Not available
Critical Temperature Not available
Electrical Conductivity Not available
LiquidPhysical State
Other Information
Flammability (solid, gas) Not applicable
Chemical Stability
Normally stable.
Conditions to Avoid
None known.
Incompatible Materials
None known.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
SDS No.:
Date of Preparation:
0408 Page
of
0704
March 27, 2015
Product Identifier: Big D Deodorant Concentrate, Cherry
Skin Corrosion/Irritation
No information was located.
Serious Eye Damage/Irritation
No information was located.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
ACGIH®: A4 – Not classifiable as a human carcinogen.
Development of Offspring
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
No information was located.
Interactive Effects
No information was located.
Acute Toxicity
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
No information was located.
Aspiration Hazard
Skin contact; eye contact; ingestion; inhalation.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
2-Propanol 72.6 mg/L (rat) (vapour) 4396 mg/kg (rat) 12870 mg/kg (rabbit)
Dipropylene glycol
monomethyl ether
5135 mg/kg 9500 mg/kg
Benzaldehyde > 1300 mg/kg (rat) > 2000 mg/kg (guinea pig)
Ethyl acetate 16000 mg/L (rat) 5600 mg/m3 (rat) (2-hour
exposure)
Benzyl acetate 830 mg/kg (mouse) > 5000 mg/kg (rabbit)
Chemical Name IARC ACGIH® NTP OSHA
2-Propanol A4
SDS No.:
Date of Preparation:
0408 Page
of
0705
March 27, 2015
Product Identifier: Big D Deodorant Concentrate, Cherry
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
Toxicity
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea
ErC50 Aquatic
Plants
ErC50 Algae
2-Propanol 9640 mg/L
(Pimephales
promelas (fathead
minnow); 96-hour)
13299 mg/L
(Daphnia magna
(water flea); 48-hour)
> 1000 mg/L
(96-hour)
Poly(oxy-1,2-ethanediyl),
alpha-octyl- omega
-hydroxy-
> 100 mg/L (Daphnia
magna (water flea);
48-hour)
Benzaldehyde 0.8-1.44 mg/L
(Lepomis
macrochirus
(bluegill); 96-hour)
Ethyl acetate 200.32-225.42 mg/L
(48-hour)
n-Amyl acetate 65 mg/L (96-hour)
SECTION 13. DISPOSAL CONSIDERATIONS
This product is a non-hazardous waste.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions
for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
Safety, Health and Environmental Regulations
Class D2B
D2B - Toxic (Eye irritant)
SDS No.:
Date of Preparation:
0408 Page
of
0706
March 27, 2015
Product Identifier: Big D Deodorant Concentrate, Cherry
CEPA - National Pollutant Release Inventory (NPRI)
Part 1A. (Polyethylene glycol octylphenyl ether, liquids)
Part 1A. (2-Propanol)
Part 5. (2-Propanol)
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are listed on the TSCA Inventory.
Additional USA Regulatory Lists
Massachusetts Right To Know. (2-Propanol). (Dipropylene glycol monomethyl ether). (Benzyl acetate).
(Benzaldehyde). (Ethyl acetate). (n-Amyl acetate)
New Jersey Right To Know. (Dipropylene glycol monomethyl ether). (Poly(oxy-1,2-ethanediyl), alpha-octyl- omega
-hydroxy-). (Benzaldehyde). (2-Propanol). (n-Amyl acetate). (Ethyl acetate). (Benzyl acetate)
Pennsylvania Right To Know. (2-Propanol). (Poly(oxy-1,2-ethanediyl), alpha-octyl- omega -hydroxy-). (Dipropylene
glycol monomethyl ether). (Benzyl acetate). (Benzaldehyde). (Ethyl acetate). (n-Amyl acetate)
Rhode Island Right To Know. (2-Propanol). (Benzyl acetate). (n-Amyl acetate). (Ethyl acetate)
California Proposition 65: Ethylene Oxide (CAS 75-21-8) Formaldehyde (CAS 50-00-0) 1,4-Dioxane (CAS
123-91-1) Acetaldehyde (CAS 75-07-0)
California Proposition 65 - Developmental Toxin: 1,4-Dioxane (CAS 123-91-1).
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
March 27, 2015
Revision Indicators
Not applicable.
Health - 1 Flammability - 0 Instability - 0
SDS No.:
Date of Preparation:
0408 Page
of
0707
March 27, 2015
Product Identifier: Big D Deodorant Concentrate, Cherry
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