Big D Industrial Deodorant, Lemon
Product Identifier Big D Industrial Deodorant, Lemon
Other Means of
Identification
032000, 033100, 133100, 533100, & C0433103
Other Identification Industrial Deodorant, Lemon
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Liquid Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Manufacturer
Deodorant.
0449
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
Hazard Statement(s):
H227 Combustible liquid.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary Statement(s):
Prevention:
P210 Keep away from flames and hot surfaces. – No smoking.
P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
P264 Wash hands and skin thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.
GHS Classification
Flammable liquid - Category 4; Skin corrosion/irritation - Category 2; Skin sensitization - Category 1; Aspiration hazard Category 1; Aquatic hazard (Acute) - Category 1; Aquatic hazard (Chronic) - Category 1
SDS No.:
Date of Preparation:
0449 Page
of
0701
April 10, 2015
Product Identifier: Big D Industrial Deodorant, Lemon
Safety Data Sheet
P273 Avoid release to the environment.
P280 Wear protective gloves/eye protection/face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE/doctor.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P321 Specific treatment (see on this label).
P331 Do NOT induce vomiting.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P370 + P378 In case of fire: Use appropriate foam to extinguish.
P391 Collect spillage.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Contains no hazardous ingredients. Mixture:
Hydrotreated kerosene 64742-47-8 82.51
Terpenes and Terpenoids, sweet orange-oil 68647-72-3 12.19
CITRAL 5392-40-5 2.86
Terpenes and Terpenoids, citrus-oil 68608-34-4 1.26
Linalyl Acetate 115-95-7 0.37
Other components below reportable Levels No CAS 0.24
Terpenes and Terpenoids, lemon-oil 68917-33-9 0.21
LEMON OIL 8008-56-8 0.21
Hydrocarbons, terpene processing by-products 68956-56-9 0.15
Inhalation
Move to fresh air. Call a Poison Centre or doctor if you feel unwell or are concerned.
Skin Contact
Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Immediately wash gently and
thoroughly with lukewarm, gently flowing water and mild soap for 15-20 minutes.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open. If eye irritation persists, get medical advice/attention.
Ingestion
SECTION 4. FIRST-AID MEASURES
First-aid Measures
SDS No.:
Date of Preparation:
0449 Page
of
0702
April 10, 2015
Product Identifier: Big D Industrial Deodorant, Lemon
Rinse mouth with water. Immediately call a Poison Centre or doctor.
Most Important Symptoms and Effects, Acute and Delayed
If inhaled:
Can irritate the nose and throat.
If on skin:
May cause mild irritation.
If in eyes:
Causes moderate to severe irritation.
If swallowed:
Can irritate the mouth, throat and stomach. Can burn the lips, tongue, throat and stomach.
Extinguishing Media
Suitable Extinguishing Media
Not combustible. Use extinguishing agents compatible with product and suitable for surrounding fire.
Unsuitable Extinguishing Media
DO NOT use water or water-based extinguishing agents.
Specific Hazards Arising from the Chemical
Can ignite if strongly heated.
Liquid can float on water and may travel to distant locations and/or spread fire.
Very toxic carbon monoxide, carbon dioxide.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
Fire-fighters may enter the area if positive pressure SCBA and full Bunker Gear is worn.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
Small spills or leaks: contain and soak up spill with absorbent that does not react with spilled product. Large spills or
leaks: dike spilled product to prevent runoff.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
No special handling precautions are necessary.
Wash hands thoroughly after handling this product and before eating, using the washroom or leaving work area.
Conditions for Safe Storage
Store in an area that is: cool, dry, ventilated.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Hydrotreated kerosene 400 ppm 400 ppm
CITRAL 5 ppm
SDS No.:
Date of Preparation:
0449 Page
of
0703
April 10, 2015
Product Identifier: Big D Industrial Deodorant, Lemon
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Not normally required if product is used as directed.
Not required, if used as directed.
Not required if product is used as directed.
General ventilation is usually adequate.
pH Not available
Appearance Clear amber liquid. Particle Size: Not applicable
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Odour Fragrant (Fragrance)
Vapour Pressure Not available
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range Not available
Evaporation Rate Not available
Flash Point 174 ºF (79 ºC)
Melting Point/Freezing Point Not available (melting); Not available (freezing)
Relative Density (water = 1) < 1 at 25 ºC
Upper/Lower Flammability or
Explosive Limit
Not available (upper); Not available (lower)
Solubility Practically insoluble in water; Highly soluble in alcohols (e.g. ethanol).
Auto-ignition Temperature Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Molecular Formula Not applicable
Molecular Weight Not applicable
Not availableDecomposition Temperature
Bulk Density Not available
Viscosity Not available (kinematic)
Surface Tension Not available
Vapour Pressure at 50 deg C Not available
Basic Physical and Chemical Properties
LiquidPhysical State
Other Information
Chemical Stability
Normally stable.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
SDS No.:
Date of Preparation:
0449 Page
of
0704
April 10, 2015
Product Identifier: Big D Industrial Deodorant, Lemon
Conditions to Avoid
None known.
Incompatible Materials
None known.
Hazardous Decomposition Products
None known.
Skin Corrosion/Irritation
No information was located.
May cause mild irritation.
Serious Eye Damage/Irritation
No information was located.
Causes moderate to severe irritation.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
No information was located.
Development of Offspring
No information was located.
No information was located.
Reproductive Toxicity
No information was located.
Acute Toxicity
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
May cause lung damage if aspirated based on physical properties (e.g. kinematic viscosity) and chemical family
(hydrocarbon).
Aspiration Hazard
Inhalation; skin contact; eye contact; ingestion.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Hydrotreated kerosene 5 mg/L (rat) (4-hour
exposure)
5000 mg/kg (rat) 2000 mg/kg (rabbit)
Linalyl Acetate 14550 mg/kg (rat) > 5000 mg/kg (rabbit)
CITRAL 4950 mg/kg (rat) > 2000 mg/kg (rat)
SDS No.:
Date of Preparation:
0449 Page
of
0705
April 10, 2015
Product Identifier: Big D Industrial Deodorant, Lemon
Germ Cell Mutagenicity
May be mutagenic based on limited evidence.
Interactive Effects
No information was located.
No information was located.
No information was located.
No information was located.
There is no information available.
SECTION 12. ECOLOGICAL INFORMATION
No information was located.
Toxicity
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
SECTION 13. DISPOSAL CONSIDERATIONS
The required hazard evaluation of the waste and compliance with the applicable hazardous waste laws are the
responsibility of the user.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions
for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
Safety, Health and Environmental Regulations
Class D2B
D2B - Toxic
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Health - 1 Flammability - 1 Instability - 0
SDS No.:
Date of Preparation:
0449 Page
of
0706
April 10, 2015
Product Identifier: Big D Industrial Deodorant, Lemon
Phone No.
Date of Preparation
April 10, 2015
Revision Indicators
Not applicable.
SDS No.:
Date of Preparation:
0449 Page
of
0707
April 10, 2015
Product Identifier: Big D Industrial Deodorant, Lemon
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