Big D Industrial Deodorant, Natural
Product Identifier Big D Industrial Deodorant, Natural
Other Means of
Identification
030700, 031000, 130700, 530700, 630700, C0430703
Other Identification Industrial Deodorant, Natural
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Liquid Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Manufacturer
Deodorant.
0358
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
Hazard Statement(s):
H227 Combustible liquid.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H340 May cause genetic defects.
H350 May cause cancer.
Precautionary Statement(s):
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
GHS Classification
Flammable liquid - Category 4; Skin corrosion/irritation - Category 2; Serious eye damage/eye irritation - Category 1;
Skin sensitization - Category 1; Germ cell mutagenicity - Category 1B; Carcinogenicity - Category 1A; Aspiration hazard
- Category 1
SDS No.:
Date of Preparation:
0358 Page
of
0801
March 12, 2015
Product Identifier: Big D Industrial Deodorant, Natural
Safety Data Sheet
P210 Keep away from flames and hot surfaces. – No smoking.
P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
P264 Wash hands and skin thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE/doctor.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P321 Specific treatment (see on this label).
P331 Do NOT induce vomiting.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Contains no hazardous ingredients. Mixture:
Hydrotreated kerosene 64742-47-8 82.70
Other components below reportable Levels No CAS 6.90
2-Propanol 67-63-0 2.47
Pine oil 8002-09-3 1.33
n-Amyl acetate 628-63-7 1.25
Terpenes and Terpenoids, sweet orange-oil 68647-72-3 1.22
ALPHA-TERPINEOL 98-55-5 0.97
Terpineol, acetate 8007-35-0 0.96
2-Methylbutyl acetate 624-41-9 0.67
CITRAL 5392-40-5 0.42
METHYL ANTHRANILATE 134-20-3 0.30
METHYL SALICYLATE 119-36-8 0.25
Ethyl acetate 141-78-6 0.21
Ethyl butyrate 105-54-4 0.18
Benzyl acetate 140-11-4 0.15
CINNAMALDEHYDE 104-55-2 0.10
VANILLIN 121-33-5 0.10
SECTION 4. FIRST-AID MEASURES
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Date of Preparation:
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Product Identifier: Big D Industrial Deodorant, Natural
Inhalation
Move to fresh air. Call a Poison Centre or doctor if you feel unwell or are concerned.
Skin Contact
Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Immediately wash gently and
thoroughly with lukewarm, gently flowing water and mild soap for 15-20 minutes.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open. If eye irritation persists, get medical advice/attention.
Ingestion
Rinse mouth with water. Immediately call a Poison Centre or doctor.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Most Important Symptoms and Effects, Acute and Delayed
If inhaled:
Can irritate the nose and throat.
If on skin:
May cause mild irritation.
If in eyes:
Causes moderate to severe irritation.
If swallowed:
Can irritate the mouth, throat and stomach. Can burn the lips, tongue, throat and stomach.
Extinguishing Media
Suitable Extinguishing Media
Not combustible. Use extinguishing agents compatible with product and suitable for surrounding fire.
Unsuitable Extinguishing Media
DO NOT use water or water-based extinguishing agents.
Specific Hazards Arising from the Chemical
Can ignite if strongly heated.
Liquid can float on water and may travel to distant locations and/or spread fire.
Very toxic carbon monoxide, carbon dioxide.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
Fire-fighters may enter the area if positive pressure SCBA and full Bunker Gear is worn.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
Small spills or leaks: contain and soak up spill with absorbent that does not react with spilled product. Large spills or
leaks: dike spilled product to prevent runoff.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
No special handling precautions are necessary.
Wash hands thoroughly after handling this product and before eating, using the washroom or leaving work area.
SECTION 7. HANDLING AND STORAGE
SDS No.:
Date of Preparation:
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March 12, 2015
Product Identifier: Big D Industrial Deodorant, Natural
Conditions for Safe Storage
Store in an area that is: cool, dry, ventilated.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
2-Propanol 200 ppm 400 ppm 980 mg/m3
Hydrotreated kerosene 400 ppm 400 ppm
n-Amyl acetate 50 ppm 100 ppm 525 mg/m3
2-Methylbutyl acetate 50 ppm 100 ppm
CITRAL 5 ppm
Ethyl acetate 400 ppm 1400
mg/m3
Benzyl acetate 10 ppm
VANILLIN 10 mg/m3
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Not normally required if product is used as directed.
Not required, if used as directed.
Not required if product is used as directed.
General ventilation is usually adequate.
pH Not available
Appearance Clear amber liquid. Particle Size: Not applicable
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Odour Fragrant (Fragrance)
Vapour Pressure Not available
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range Not available
Evaporation Rate Not available
Flash Point 174 ºF (79 ºC)
Melting Point/Freezing Point Not available (melting); Not available (freezing)
Relative Density (water = 1) < 1 at 25 ºC
Upper/Lower Flammability or
Explosive Limit
Not available (upper); Not available (lower)
Solubility Practically insoluble in water; Highly soluble in alcohols (e.g. ethanol).
Auto-ignition Temperature Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Not availableDecomposition Temperature
Basic Physical and Chemical Properties
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March 12, 2015
Product Identifier: Big D Industrial Deodorant, Natural
Molecular Formula Not applicable
Molecular Weight Not applicable
Bulk Density Not available
Viscosity Not available (kinematic)
Surface Tension Not available
Vapour Pressure at 50 deg C Not available
LiquidPhysical State
Other Information
Chemical Stability
Normally stable.
Conditions to Avoid
None known.
Incompatible Materials
None known.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
Skin Corrosion/Irritation
No information was located.
May cause mild irritation.
Serious Eye Damage/Irritation
No information was located.
Causes moderate to severe irritation.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Acute Toxicity
Inhalation; skin contact; eye contact; ingestion.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
2-Propanol 72.6 mg/L (rat) (vapour) 4396 mg/kg (rat) 12870 mg/kg (rabbit)
Hydrotreated kerosene 5 mg/L (rat) (4-hour
exposure)
5000 mg/kg (rat) 2000 mg/kg (rabbit)
CITRAL 4950 mg/kg (rat) > 2000 mg/kg (rat)
METHYL ANTHRANILATE 2910 mg/kg (rat) 5000 mg/kg (rabbit)
Ethyl acetate 16000 mg/L (rat) 5600 mg/m3 (rat) (2-hour
exposure)
Benzyl acetate 830 mg/kg (mouse) > 5000 mg/kg (rabbit)
CINNAMALDEHYDE 3400 mg/kg (rat) > 1200 mg/kg (rat)
VANILLIN 1580 mg/kg (rat)
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Product Identifier: Big D Industrial Deodorant, Natural
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
No information was located.
Development of Offspring
No information was located.
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
May be mutagenic based on limited evidence.
Interactive Effects
No information was located.
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
May cause lung damage if aspirated based on physical properties (e.g. kinematic viscosity) and chemical family
(hydrocarbon).
Aspiration Hazard
Chemical Name IARC ACGIH® NTP OSHA
2-Propanol A4
No information was located.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea
ErC50 Aquatic
Plants
ErC50 Algae
2-Propanol 9640 mg/L
(Pimephales
promelas (fathead
minnow); 96-hour)
13299 mg/L
(Daphnia magna
(water flea); 48-hour)
> 1000 mg/L
(96-hour)
n-Amyl acetate 65 mg/L (96-hour)
METHYL
ANTHRANILATE
7.98-10.51 mg/L
(Lepomis
macrochirus
(bluegill); 96-hour)
Ethyl acetate 200.32-225.42 mg/L
(48-hour)
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Product Identifier: Big D Industrial Deodorant, Natural
No information was located.
No information was located.
There is no information available.
No information was located.
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
VANILLIN 53-61.3 mg/L
(Pimephales
promelas (fathead
minnow); 96-hour)
SECTION 13. DISPOSAL CONSIDERATIONS
The required hazard evaluation of the waste and compliance with the applicable hazardous waste laws are the
responsibility of the user.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions
for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
USA
Additional USA Regulatory Lists
CERCLA. (2-Methylbutyl acetate). (Ethyl acetate)
Massachusetts Right To Know. (2-Propanol). (Ethyl acetate). (Ethyl butyrate). (n-Amyl acetate) Pin-2(3)-ene (CAS
80-56-8)
New Jersey Right To Know. (2-Propanol). (Pine oil). (n-Amyl acetate). (Benzyl acetate). (Ethyl acetate). (Ethyl
butyrate) Pin-2(3)-ene (CAS 80-56-8)
Pennsylvania Right To Know. (2-Propanol). (Ethyl butyrate). (METHYL SALICYLATE). (n-Amyl acetate)
Pin-2(3)-ene (CAS 80-56-8)
Rhode Island RTK hazardous substances. (n-Amyl acetate). (Ethyl acetate). (2-Propanol)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
Safety, Health and Environmental Regulations
Class D2B
D2B - Toxic
SDS No.:
Date of Preparation:
0358 Page
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0807
March 12, 2015
Product Identifier: Big D Industrial Deodorant, Natural
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
March 12, 2015
Revision Indicators
Not applicable.
Health - 1 Flammability - 1 Instability - 0
SDS No.:
Date of Preparation:
0358 Page
of
0808
March 12, 2015
Product Identifier: Big D Industrial Deodorant, Natural
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