Product Identifier Big D dumpster D plus C
Other Means of
Identification
017700, 017800, & C0417703
Other Identification Granular Deodorant
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Dry Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Manufacturer /
Supplier
Dry Deodorants.
0329
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
Hazard Statement(s):
H317 May cause an allergic skin reaction.
H320 Causes eye irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer if inhaled.
Precautionary Statement(s):
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
GHS Classification
Serious eye damage/eye irritation - Category 2B; Skin sensitization - Category 1; Germ cell mutagenicity - Category 2;
Carcinogenicity - Category 1A
SDS No.:
Date of Preparation:
0329 Page
of
0701
February 23, 2015
Product Identifier: Big D dumpster D plus C
Safety Data Sheet
Big D dumpster D plus C
Response:
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P321 Specific treatment (see on this label).
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P363 Wash contaminated clothing before reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Silica, quartz 14808-60-7 6
Montmorillonite ((Al1.33-1.67Mg0.33-0.
67)(Ca0-1Na0-1)0.33Si4(OH)2O10.xH2O),
calcined
70892-59-0 75
Silica, cristobalite 14464-46-1 2.4
Other components below reportable Levels No CAS 16.55
Citronella oil 8000-29-1 0.0476
Inhalation
Move to fresh air. Call a Poison Centre or doctor if you feel unwell or are concerned.
Skin Contact
Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes. Call a Poison Centre
or doctor if you feel unwell or are concerned.
Eye Contact
Rinse the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding the eyelid(s) open.
Ingestion
Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing. Do not
induce vomiting. Immediately call a Poison Centre or doctor.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Most Important Symptoms and Effects, Acute and Delayed
If inhaled:
Can cause severe irritation of the nose and throat.
If in eyes:
May cause mild irritation.
If swallowed:
Large amounts symptoms may include nausea, vomiting, stomach cramps and diarrhea.
SDS No.:
Date of Preparation:
0329 Page
of
0702
February 23, 2015
Product Identifier: Big D dumpster D plus C
Special Instructions
Not applicable.
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Extinguishing Media
Suitable Extinguishing Media
Not combustible. Use extinguishing agent suitable for surrounding fire.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Does not burn.
This product presents no unusual hazards in a fire situation.
Not known to generate any hazardous decomposition products in a fire.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
See Skin Protection in Section 8 (Exposure Controls/Personal Protection) for advice on suitable chemical protective
materials.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
Do not allow into any sewer, on the ground or into any waterway.
Methods and Materials for Containment and Cleaning Up
Avoid generating dust.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
Do not breathe in this product. Only use where there is adequate ventilation.
Conditions for Safe Storage
Separate from incompatible materials (see Section 10: Stability and Reactivity).
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Montmorillonite ((Al1.33-1.67Mg0.
33-0.67)(Ca0-1Na0-1)0.
33Si4(OH)2O10.xH2O), calcined
0.05 mg/m3 5 mg/m3
Silica, cristobalite 0.05 mg/m3 5 mg/m3
Silica, quartz 0.05 mg/m3 5 mg/m3
Appropriate Engineering Controls
Use a local exhaust ventilation and enclosure, if necessary, to control amount in the air.
SDS No.:
Date of Preparation:
0329 Page
of
0703
February 23, 2015
Product Identifier: Big D dumpster D plus C
Individual Protection Measures
Skin Protection
Eye/Face Protection
Not required, if used as directed.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
pH Not applicable
Appearance Dark pellets.
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Odour Fragrant (Fragrance)
Vapour Pressure Not applicable
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range Not applicable
Evaporation Rate Not applicable
Flash Point > 200 ºF (estimated) (Montmorillonite ((Al1.33-1.67Mg0.33-0.
67)(Ca0-1Na0-1)0.33Si4(OH)2O10.xH2O), calcined)
Melting Point/Freezing Point Not applicable (freezing)
Relative Density (water = 1) Not applicable
Upper/Lower Flammability or
Explosive Limit
Not available (upper); Not available (lower)
Solubility Insoluble (less than 1 mg/L) in water
Auto-ignition Temperature Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Not availableDecomposition Temperature
Viscosity Not applicable (kinematic); Not applicable (dynamic)
Basic Physical and Chemical Properties
SolidPhysical State
Other Information
Flammability (solid, gas) Not available
Chemical Stability
Normally stable.
Conditions to Avoid
Incompatible materials.
Incompatible Materials
Unsaturated hydrocarbons (e.g. turpentine), strong acids (e.g. hydrochloric acid).
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Not reactive.
SDS No.:
Date of Preparation:
0329 Page
of
0704
February 23, 2015
Product Identifier: Big D dumpster D plus C
LC50: No information was located.
LD50 (oral): No information was located.
Skin Corrosion/Irritation
No information was located.
Serious Eye Damage/Irritation
No information was located.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
Development of Offspring
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
No information was located.
Interactive Effects
No information was located.
LD50 (dermal): No information was located.
Acute Toxicity
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
Not known to be an aspiration hazard.
Aspiration Hazard
Inhalation; skin contact; eye contact; ingestion.
Likely Routes of Exposure
Chemical Name IARC ACGIH® NTP OSHA
Montmorillonite ((Al1.
33-1.67Mg0.33-0.
67)(Ca0-1Na0-1)0.
33Si4(OH)2O10.xH2O),
calcined
Known carcinogen
Silica, cristobalite Known carcinogen
Silica, quartz Known carcinogen
SDS No.:
Date of Preparation:
0329 Page
of
0705
February 23, 2015
Product Identifier: Big D dumpster D plus C
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
SECTION 13. DISPOSAL CONSIDERATIONS
The required hazard evaluation of the waste and compliance with the applicable hazardous waste laws are the
responsibility of the user.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions
for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL/NDSL.
USA
US OSHA HazCom 1994 Regulatory Status
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200 (1994)).
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are listed on the TSCA Inventory.
Additional USA Regulatory Lists
California Proposition 65. (Silica, cristobalite). (Silica, quartz) SARA Title III - Section 311/312. (Silica, cristobalite).
(Silica, quartz)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
Safety, Health and Environmental Regulations
Class D2A
D2A - Very Toxic
Key to Abbreviations
ACGIH® = American Conference of Governmental Industrial Hygienists
NFPA = National Fire Prevention Association
NTP = National Toxicology Program
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
February 23, 2015
Health - 1 Flammability - 0 Instability - 0
SDS No.:
Date of Preparation:
0329 Page
of
0706
February 23, 2015
Product Identifier: Big D dumpster D plus C
Key to Abbreviations
OSHA = US Occupational Safety and Health Administration
NTP = National Toxicology Program
SDS No.:
Date of Preparation:
0329 Page
of
0707
February 23, 2015
Product Identifier: Big D dumpster D plus C
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