
Product Identifier Big D D'Vour
Other Means of
Identification
166, 167, 168, 170, C0416603, & a kit component of 169 & 173
Other Identification D'vour
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Dry Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Manufacturer
Dry Deodorants.
0332
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Warning
Hazard Statement(s):
H315 Causes skin irritation.
H320 Causes eye irritation.
Precautionary Statement(s):
Prevention:
P264 Wash thoroughly after handling.
P280 Wear protective gloves.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
GHS Classification
Skin corrosion/irritation - Category 2; Serious eye damage/eye irritation - Category 2B
SDS No.:
Date of Preparation:
0332 Page
of
0601
February 24, 2015
Product Identifier: Big D D'Vour
Safety Data Sheet
Big D D'Vour

P321 Specific treatment (see on this label).
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
Storage:
P401 Store in accordance with local, regional, national and international regulations.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Sodium poly acrylate 9003-04-7 98.9
Other components below reportable Levels No CAS 0.313
Terpenes and Terpenoids, sweet orange-oil 68647-72-3 0.193
Precipitated silica 112926-00-8 0.462
Hydrocarbons, terpene processing by-products 68956-56-9 0.132
Inhalation
Call a Poison Centre or doctor if you feel unwell or are concerned.
Skin Contact
Rinse with lukewarm, gently flowing water for 5 minutes.
Eye Contact
Rinse the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding the eyelid(s) open.
If eye irritation persists, get medical advice/attention.
Ingestion
Rinse mouth with water. Call a Poison Centre or doctor if you feel unwell or are concerned.
Special Instructions
Not applicable.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
If on skin:
May cause mild irritation.
If in eyes:
May cause mild irritation.
If swallowed:
Can irritate the mouth, throat and stomach.
Extinguishing Media
Suitable Extinguishing Media
SECTION 5. FIRE-FIGHTING MEASURES
SDS No.:
Date of Preparation:
0332 Page
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0602
February 24, 2015
Product Identifier: Big D D'Vour

Suitable Extinguishing Media
Carbon dioxide, dry chemical powder, appropriate foam, water spray or fog.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Can ignite if strongly heated.
This product presents no unusual hazards in a fire situation.
Not known to generate any hazardous decomposition products in a fire.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
Chemical protective clothing (e.g. chemical splash suit) and positive pressure SCBA may be necessary.
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
No special clean-up methods are necessary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
No special handling precautions are necessary.
Conditions for Safe Storage
No special requirements for storage area.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLVĀ® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
Precipitated silica 3 mg/m3 5 mg/m3
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Do not breathe in this product.
Not required, if used as directed.
Not required if product is used as directed.
The hazard potential of this product is relatively low. General ventilation is usually adequate.
pH Not applicable
Appearance powder. Particle Size: Not available
Odour Fragrant (Fragrance)
Odour Threshold Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
SDS No.:
Date of Preparation:
0332 Page
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0603
February 24, 2015
Product Identifier: Big D D'Vour

pH
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not applicable
Vapour Pressure Not applicable
Vapour Density (air = 1) Not applicable
Initial Boiling Point/Range Not applicable
Evaporation Rate Not applicable
Flash Point Not applicable
Melting Point/Freezing Point Not available (melting); Not applicable (freezing)
Relative Density (water = 1) Not applicable
Upper/Lower Flammability or
Explosive Limit
Not applicable (upper); Not applicable (lower)
Solubility Not applicable in water; Not available (in other liquids)
Auto-ignition Temperature Not applicable
Molecular Formula Not available
Molecular Weight Not available
Not availableDecomposition Temperature
Bulk Density Not available
Viscosity Not available (kinematic); Not available (dynamic)
Surface Tension Not available
Vapour Pressure at 50 deg C Not available
Saturated Vapour Concentration Not available
Critical Temperature Not available
Electrical Conductivity Not available
SolidPhysical State
Flammability (solid, gas) Not available
Chemical Stability
Normally stable.
Conditions to Avoid
None known.
Incompatible Materials
None known.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Ingestion; eye contact; skin contact; inhalation.
Likely Routes of Exposure
SDS No.:
Date of Preparation:
0332 Page
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0604
February 24, 2015
Product Identifier: Big D D'Vour

LC50: No information was located.
LD50 (oral): No information was located.
Skin Corrosion/Irritation
No information was located.
Serious Eye Damage/Irritation
There is limited evidence of very mild irritation.
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
Not harmful.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
Not known to cause cancer.
Development of Offspring
No information was located.
Reproductive Toxicity
Not known to cause effects on sexual function or fertility.
Germ Cell Mutagenicity
Not known to be a mutagen.
Interactive Effects
No information was located.
LD50 (dermal): No information was located.
Acute Toxicity
No information was located for: Skin Corrosion/Irritation, Serious Eye Damage/Irritation, STOT (Specific Target Organ
Toxicity) - Single Exposure, STOT (Specific Target Organ Toxicity) - Repeated Exposure, Respiratory and/or Skin
Sensitization, Carcinogenicity, Development of Offspring, Sexual Function and Fertility, Germ Cell Mutagenicity,
Interactive Effects
Sexual Function and Fertility
Effects on or via Lactation
Not known to cause effects on or via lactation.
No information was located.
Aspiration Hazard
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Precipitated silica > 10000 mg/kg (rat) > 5000 mg/kg (rabbit)
No information was located.
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
Toxicity
Persistence and Degradability
SDS No.:
Date of Preparation:
0332 Page
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0605
February 24, 2015
Product Identifier: Big D D'Vour

No information was located.
No information was located.
There is no information available.
No information was located.
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
SECTION 13. DISPOSAL CONSIDERATIONS
Contact local environmental authorities for approved disposal or recycling methods in your jurisdiction.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions
for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
Not listed on the DSL or NDSL.
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
Additional USA Regulatory Lists
Massachusetts Right To Know: 2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) 0.0033% wt/wt
New Jersey Right To Know: 2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) 0.0033% wt/wt
Pennsylvania Right To Know: 2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) 0.0033% wt/wt.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
Not a WHMIS controlled product.
Safety, Health and Environmental Regulations
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
February 24, 2015
Revision Indicators
Not applicable.
Health - 0 Flammability - 0 Instability - 0
SDS No.:
Date of Preparation:
0332 Page
of
0606
February 24, 2015
Product Identifier: Big D D'Vour