Product Identifier Big D Toilet Concentrate
Other Means of
Identification
067900, 167900, 367900, 367903, 467900, 567900, & C0467903
Other Identification Toilet Concentrate
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Liquid Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Manufacturer
Deodorant.
0450
Big D Industries, 405 682 2541, 8-4:30 Monday-Friday
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Warning
Hazard Statement(s):
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
Precautionary Statement(s):
Prevention:
P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
P264 Wash hands and skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing.
P280 Wear eye protection/face protection.
GHS Classification
Acute toxicity (Oral) - Category 4; Acute toxicity (Dermal) - Category 4; Acute toxicity (Inhalation) - Category 4; Serious
eye damage/eye irritation - Category 2A
SDS No.:
Date of Preparation:
0450 Page
of
0701
April 10, 2015
Product Identifier: Big D Toilet Concentrate
Safety Data Sheet
Big D Toilet Concentrate
Response:
P301 + P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P312 Call a POISON CENTRE/doctor if you feel unwell.
P321 Specific treatment (see on this label).
P330 Rinse mouth.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
Storage:
P401 Store in accordance with local, regional, national and international regulations.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Other components below reportable Levels No CAS 95.8
Poly(oxy-1,2-ethanediyl), alpha-octyl- omega
-hydroxy-
27252-75-1 1.97
Benzaldehyde 100-52-7 1.06
Quaternary ammonium compounds,
benzyl-C12-C16-alkyldimethyl, chlorides
68424-85-1 0.56
Ethyl acetate 141-78-6 0.26
Benzyl acetate 140-11-4 0.18
n-Amyl acetate 628-63-7 0.17
Inhalation
Move to fresh air.
Skin Contact
Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open.
Ingestion
Call a Poison Centre or doctor if you feel unwell or are concerned. Rinse mouth with water.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Most Important Symptoms and Effects, Acute and Delayed
SDS No.:
Date of Preparation:
0450 Page
of
0702
April 10, 2015
Product Identifier: Big D Toilet Concentrate
Special Instructions
Not applicable.
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
If on skin:
May cause mild irritation.
If swallowed:
Can irritate the mouth, throat and stomach.
Extinguishing Media
Suitable Extinguishing Media
Not combustible. Use extinguishing agent suitable for surrounding fire.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Does not burn.
This product presents no unusual hazards in a fire situation.
Not known to generate any hazardous decomposition products in a fire.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
Chemical protective clothing (e.g. chemical splash suit) and positive pressure SCBA may be necessary.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
Contain and soak up spill with absorbent that does not react with spilled product.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
No special handling precautions are necessary.
Conditions for Safe Storage
No special requirements for storage area.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Poly(oxy-1,2-ethanediyl), alpha-octylomega -hydroxy-
10 mg/m3
n-Amyl acetate 50 ppm 100 ppm 525 mg/m3
Benzyl acetate 10 ppm
SDS No.:
Date of Preparation:
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of
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April 10, 2015
Product Identifier: Big D Toilet Concentrate
Ethyl acetate 400 ppm 1400
mg/m3
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Eye/Face Protection
ACGIH® = American Conference of Governmental Industrial Hygienists. TWA = Time-Weighted Average. STEL =
Short-term Exposure Limit.
Not required, if used as directed.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
The hazard potential of this product is relatively low. General ventilation is usually adequate.
pH Not available
Appearance liquid. Particle Size: Not applicable
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Odour Fragrant (Fragrance)
Vapour Pressure Not available
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range > 212 ºF (100 ºC)
Evaporation Rate Not available
Flash Point > 200 ºF (93 ºC) (closed cup)
Melting Point/Freezing Point Not available (melting); Not available (freezing)
Relative Density (water = 1) ~ 1 at 68 ºF (20 ºC)
Upper/Lower Flammability or
Explosive Limit
Not available (upper); Not available (lower)
Solubility Soluble in all proportions in water; Not available (in other liquids)
Auto-ignition Temperature Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Molecular Formula Not applicable
Molecular Weight Not applicable
Not availableDecomposition Temperature
Bulk Density Not available
Viscosity Not available (kinematic)
Surface Tension Not available
Vapour Pressure at 50 deg C Not available
Saturated Vapour Concentration Not available
Critical Temperature Not available
Electrical Conductivity Not available
Basic Physical and Chemical Properties
LiquidPhysical State
Other Information
Flammability (solid, gas) Not applicable
SECTION 10. STABILITY AND REACTIVITY
SDS No.:
Date of Preparation:
0450 Page
of
0704
April 10, 2015
Product Identifier: Big D Toilet Concentrate
Chemical Stability
Normally stable.
Conditions to Avoid
None known.
Incompatible Materials
None known.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
LC50: No information was located.
LD50 (oral): No information was located.
Skin Corrosion/Irritation
No information was located.
Serious Eye Damage/Irritation
No information was located.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
ACGIH®: A4 – Not classifiable as a human carcinogen.
LD50 (dermal): No information was located.
Acute Toxicity
No information was located.
Aspiration Hazard
Skin contact; eye contact; ingestion; inhalation.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Benzyl acetate 830 mg/kg (mouse) > 5000 mg/kg (rabbit)
Ethyl acetate 16000 mg/L (rat) 5600 mg/m3 (rat) (2-hour
exposure)
Benzaldehyde > 1300 mg/kg (rat) > 2000 mg/kg (guinea pig)
SDS No.:
Date of Preparation:
0450 Page
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0705
April 10, 2015
Product Identifier: Big D Toilet Concentrate
Development of Offspring
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
No information was located.
Interactive Effects
No information was located.
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
Toxicity
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea
ErC50 Aquatic
Plants
ErC50 Algae
n-Amyl acetate 65 mg/L (96-hour)
Ethyl acetate 200.32-225.42 mg/L
(48-hour)
Benzaldehyde 0.8-1.44 mg/L
(Lepomis
macrochirus
(bluegill); 96-hour)
SECTION 13. DISPOSAL CONSIDERATIONS
This product is a non-hazardous waste.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions
for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Safety, Health and Environmental Regulations
Class D2B
SDS No.:
Date of Preparation:
0450 Page
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0706
April 10, 2015
Product Identifier: Big D Toilet Concentrate
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are listed on the TSCA Inventory.
Additional USA Regulatory Lists
California Proposition 65: Ethylene Oxide (CAS 75-21-8) Formaldehyde (CAS 50-00-0) 1,4-Dioxane (CAS
123-91-1) Acetaldehyde (CAS 75-07-0)
California Proposition 65 - Developmental Toxin: Ethylene Oxide (CAS 75-21-8)
Pennsylvania Right To Know. (Poly(oxy-1,2-ethanediyl), alpha-octyl- omega -hydroxy-). (Benzaldehyde). (Ethyl
acetate). (n-Amyl acetate) Ethanol (CAS 64-17-5)
New Jersey Right To Know. (Poly(oxy-1,2-ethanediyl), alpha-octyl- omega -hydroxy-). (Benzyl acetate). (Ethyl
acetate). (Benzaldehyde). (n-Amyl acetate) Ethanol (CAS 64-17-5)
Massachusetts Right To Know. (n-Amyl acetate). (Ethyl acetate). (Benzaldehyde)
Rhode Island Right To Know. (Ethyl acetate). (n-Amyl acetate)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
D2B - Toxic (Eye irritant)
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
April 10, 2015
Revision Indicators
Not applicable.
Health - 0 Flammability - 0 Instability - 0
SDS No.:
Date of Preparation:
0450 Page
of
0707
April 10, 2015
Product Identifier: Big D Toilet Concentrate
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