Safety Data Sheet
Product Identifier Big D Water Soluble Deodorant, Natural
Other Means of
Identification
161700, 361700, 431700, 561700, C0431703
Other Identification Water Soluble Deodorant, Natural
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Liquid Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Manufacturer
Restroom Odor Counteractant.
0402
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
Hazard Statement(s):
May cause an allergic skin reaction.
Causes serious eye damage.
May cause genetic defects.
May cause cancer.
Precautionary Statement(s):
Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Avoid breathing dust, fume, gas, mist, vapours or spray.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
GHS Classification
Serious eye damage/eye irritation - Category 1; Skin sensitization - Category 1; Germ cell mutagenicity - Category 1B;
Carcinogenicity - Category 1A
SDS No.:
Date of Preparation:
0402 Page
of
0701
March 26, 2015
Product Identifier: Big D Water Soluble Deodorant, Natural
Big D Water Soluble Deodorant, Natural
Response:
IF ON SKIN: Wash with plenty of water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Immediately call a POISON CENTRE/doctor.
Specific treatment (see on this label).
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Storage:
Store locked up.
Disposal:
Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Other components below reportable Levels No CAS 90.94
Poly(oxy-1,2-ethanediyl), alpha-octyl- omega
-hydroxy-
27252-75-1 5.55
2-Propanol 67-63-0 1.67
Dipropylene glycol monomethyl ether 34590-94-8 0.50
Pine oil 8002-09-3 0.28
Terpenes and Terpenoids, sweet orange-oil 68647-72-3 0.26
n-Amyl acetate 628-63-7 0.26
Terpineol, acetate 8007-35-0 0.20
ALPHA-TERPINEOL 98-55-5 0.20
2-Methylbutyl acetate 624-41-9 0.14
Inhalation
Move to fresh air.
Skin Contact
Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open.
Ingestion
Call a Poison Centre or doctor if you feel unwell or are concerned. Rinse mouth with water.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Most Important Symptoms and Effects, Acute and Delayed
SDS No.:
Date of Preparation:
0402 Page
of
0702
March 26, 2015
Product Identifier: Big D Water Soluble Deodorant, Natural
Special Instructions
Not applicable.
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
If on skin:
May cause mild irritation.
Extinguishing Media
Suitable Extinguishing Media
Not combustible. Use extinguishing agent suitable for surrounding fire.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Does not burn.
This product presents no unusual hazards in a fire situation.
Not known to generate any hazardous decomposition products in a fire.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
See Skin Protection in Section 8 (Exposure Controls/Personal Protection) for advice on suitable chemical protective
materials.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
Contain and soak up spill with absorbent that does not react with spilled product.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
No special handling precautions are necessary.
Conditions for Safe Storage
No special requirements for storage area.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
2-Propanol 200 ppm 400 ppm 980 mg/m3
Dipropylene glycol monomethyl ether 100 ppm 150 ppm 600 mg/m3
2-Methylbutyl acetate 50 ppm 100 ppm
n-Amyl acetate 50 ppm 100 ppm 525 mg/m3
SDS No.:
Date of Preparation:
0402 Page
of
0703
March 26, 2015
Product Identifier: Big D Water Soluble Deodorant, Natural
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Eye/Face Protection
ACGIH® = American Conference of Governmental Industrial Hygienists. TWA = Time-Weighted Average. STEL =
Short-term Exposure Limit.
Not required, if used as directed.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
The hazard potential of this product is relatively low. General ventilation is usually adequate.
pH Not available
Appearance Clear liquid.
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Odour Fragrant
Vapour Pressure Not available
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range > 212 ºF (100 ºC)
Evaporation Rate Not available
Flash Point > 200 ºF (93 ºC)
Melting Point/Freezing Point Not available (melting); Not available (freezing)
Relative Density (water = 1) ~ 1 at 68 ºF (20 ºC)
Upper/Lower Flammability or
Explosive Limit
Not available (upper); Not available (lower)
Solubility Soluble in all proportions in water; Not available (in other liquids)
Auto-ignition Temperature Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Not availableDecomposition Temperature
Viscosity Not available (kinematic)
Basic Physical and Chemical Properties
LiquidPhysical State
Other Information
Flammability (solid, gas) Will not burn.
Chemical Stability
Normally stable.
Conditions to Avoid
None known.
Incompatible Materials
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
SDS No.:
Date of Preparation:
0402 Page
of
0704
March 26, 2015
Product Identifier: Big D Water Soluble Deodorant, Natural
Hazardous Decomposition Products
None known.
Skin Corrosion/Irritation
No information was located.
May cause mild irritation.
Serious Eye Damage/Irritation
No information was located.
EYE IRRITANT.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
A4 – Not classifiable as a human carcinogen.
No information was located.
Development of Offspring
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
No information was located.
Acute Toxicity
Information presented below is for the entire product, unless otherwise specified.
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
No information was located.
Aspiration Hazard
Skin contact; eye contact; ingestion; inhalation.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
2-Propanol 72.6 mg/L (rat) (vapour) 4396 mg/kg (rat) 12870 mg/kg (rabbit)
Dipropylene glycol
monomethyl ether
5135 mg/kg 9500 mg/kg
Chemical Name IARC ACGIH® NTP OSHA
2-Propanol A4
SDS No.:
Date of Preparation:
0402 Page
of
0705
March 26, 2015
Product Identifier: Big D Water Soluble Deodorant, Natural
Interactive Effects
No information was located.
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
Toxicity
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea
ErC50 Aquatic
Plants
ErC50 Algae
Poly(oxy-1,2-ethanediyl),
alpha-octyl- omega
-hydroxy-
> 100 mg/L (Daphnia
magna (water flea);
48-hour)
2-Propanol 9640 mg/L
(Pimephales
promelas (fathead
minnow); 96-hour)
13299 mg/L
(Daphnia magna
(water flea); 48-hour)
> 1000 mg/L
(96-hour)
n-Amyl acetate 65 mg/L (96-hour)
SECTION 13. DISPOSAL CONSIDERATIONS
This product is a non-hazardous waste.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions
for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
CEPA - National Pollutant Release Inventory (NPRI)
Part 1A. (2-Propanol) Part 5. (2-Propanol)
USA
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
Safety, Health and Environmental Regulations
Class D2B
D2B - Toxic (Eye irritant)
SDS No.:
Date of Preparation:
0402 Page
of
0706
March 26, 2015
Product Identifier: Big D Water Soluble Deodorant, Natural
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are listed on the TSCA Inventory.
Additional USA Regulatory Lists
Pennsylvania Right To Know. (Poly(oxy-1,2-ethanediyl), alpha-octyl- omega -hydroxy-) Ethyl Acetate (CAS
141-78-6) Ethyl Butyrate (CAS 105-54-4) Methyl Salicylate (CAS 119-36-8) n-Amyl acetate (CAS 628-63-7)
Pin-2(3)-ene (CAS 80-56-8) Propylene Glycol (CAS 57-55-6). (2-Propanol). (Dipropylene glycol monomethyl ether)
New Jersey Right To Know. (Poly(oxy-1,2-ethanediyl), alpha-octyl- omega -hydroxy-). (Pine oil) Benzyl Acetate
(CAS 140-11-4) Ethyl Acetate (CAS 141-78-6) Ethyl Butyrate (CAS 105-54-4) n-Amyl acetate (CAS 628-63-7)
Pin-2(3)-ene (CAS 80-56-8). (2-Propanol). (Dipropylene glycol monomethyl ether)
California Proposition 65: 1,4-Dioxane (CAS 123-91-1) Ethylene Oxide (CAS 75-21-8) Formaldehyde (CAS
50-00-0) Acetaldehyde (CAS 75-07-0)
California Proposition 65 - Developmental Toxin: Ethylene Oxide (CAS 75-21-8)
Massachusetts Right To Know. (Dipropylene glycol monomethyl ether) n-Amyl acetate (CAS 628-63-7) Ethyl
Acetate (CAS 141-78-6) Ethyl Butyrate (CAS 105-54-4) Pin-2(3)-ene (CAS 80-56-8). (2-Propanol)
Rhode Island Right To Know. (2-Propanol) n-Amyl acetate (CAS 628-63-7) Ethyl Acetate (CAS 141-78-6)
CERCLA: 2-Methylbutyl acetate (CAS 624-41-9) Ethyl Acetate (CAS 141-78-6) Ethyl Butyrate (CAS 105-54-4)
n-Amyl acetate (CAS 628-63-7) Pin-2(3)-ene (CAS 80-56-8).
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
March 26, 2015
Revision Indicators
Not applicable.
Health - 0 Flammability - 0 Instability - 0
SDS No.:
Date of Preparation:
0402 Page
of
0707
March 26, 2015
Product Identifier: Big D Water Soluble Deodorant, Natural
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