Safety Data Sheet
Product Identifier Big D Drip Deodorant Concentrate, Mountain Air
Other Means of
Identification
159100 & C0459103
Other Identification Drip Deodorant Concentrate, Mountain Air
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Liquid Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Manufacturer
Deodorant.
0440
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
Hazard Statement(s):
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H361 Suspected of damaging fertility or the unborn child.
Precautionary Statement(s):
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
P264 Wash hands and skin thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
GHS Classification
Skin corrosion/irritation - Category 2; Serious eye damage/eye irritation - Category 1; Skin sensitization - Category 1;
Toxic to reproduction - Category 2
SDS No.:
Date of Preparation:
0440 Page
of
0701
April 08, 2015
Product Identifier: Big D Drip Deodorant Concentrate, Mountain Air
Big D Drip Deodorant Concentrate, Mountain Air
Response:
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P310 Immediately call a POISON CENTRE/doctor.
P321 Specific treatment (see on this label).
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Other components below reportable Levels No CAS 62.88
1,2-Propylene glycol 57-55-6 14.3
Poly(oxy-1,2-ethanediyl), alpha-octyl- omega
-hydroxy-
27252-75-1 18.93
7-Octen-2-ol, 2-methyl-6-methylene-, dihydro
deriv.
53219-21-9 0.62
Linalyl Acetate 115-95-7 0.43
LINALYL ALCOHOL 78-70-6 0.31
Eucalyptus oil 8000-48-4 0.25
2-Propanol 67-63-0 2.08
Acetic acid, (4-tert-butylcyclohexyl) ester 32210-23-4 0.15
COUMARIN 91-64-5 0.13
4,7-Methanoinden-6-ol, 3a,4,5,6,7,7a-hexahydro-,
acetate
5413-60-5 0.13
2-Heptanol, 2,6-dimethyl- 13254-34-7 0.12
Terpenes and Terpenoids, lime-oil 68917-71-5 0.10
Inhalation
Move to fresh air.
Skin Contact
Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes.
Eye Contact
SECTION 4. FIRST-AID MEASURES
First-aid Measures
SDS No.:
Date of Preparation:
0440 Page
of
0702
April 08, 2015
Product Identifier: Big D Drip Deodorant Concentrate, Mountain Air
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open.
Ingestion
Call a Poison Centre or doctor if you feel unwell or are concerned. Rinse mouth with water.
Special Instructions
Not applicable.
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
If on skin:
May cause mild irritation.
Extinguishing Media
Suitable Extinguishing Media
Not combustible. Use extinguishing agent suitable for surrounding fire.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Does not burn.
This product presents no unusual hazards in a fire situation.
Not known to generate any hazardous decomposition products in a fire.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
Chemical protective clothing (e.g. chemical splash suit) and positive pressure SCBA may be necessary.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
Contain and soak up spill with absorbent that does not react with spilled product.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
No special handling precautions are necessary.
Conditions for Safe Storage
No special requirements for storage area.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
SDS No.:
Date of Preparation:
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0703
April 08, 2015
Product Identifier: Big D Drip Deodorant Concentrate, Mountain Air
2-Propanol 200 ppm 400 ppm 980 mg/m3
Poly(oxy-1,2-ethanediyl), alpha-octyl-
omega -hydroxy-
10 mg/m3
1,2-Propylene glycol 10 mg/m3
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
ACGIH® = American Conference of Governmental Industrial Hygienists. TWA = Time-Weighted Average. STEL =
Short-term Exposure Limit.
Not normally required if product is used as directed.
Not required, if used as directed.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
The hazard potential of this product is relatively low. General ventilation is usually adequate.
pH Not available
Appearance Clear liquid. Particle Size: Not applicable
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Odour Fragrant (Fragrance)
Vapour Pressure Not available
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range > 212 ºF (100 ºC)
Evaporation Rate Not available
Flash Point > 200 ºF (93 ºC) (closed cup)
Melting Point/Freezing Point Not available (melting); Not available (freezing)
Relative Density (water = 1) ~ 1 at 68 ºF (20 ºC)
Upper/Lower Flammability or
Explosive Limit
Not available (upper); Not available (lower)
Solubility Soluble in all proportions in water; Not available (in other liquids)
Auto-ignition Temperature Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Molecular Formula Not applicable
Molecular Weight Not applicable
Not availableDecomposition Temperature
Bulk Density Not available
Viscosity Not available (kinematic)
Surface Tension Not available
Vapour Pressure at 50 deg C Not available
Critical Temperature Not available
Electrical Conductivity Not available
Basic Physical and Chemical Properties
LiquidPhysical State
Other Information
Flammability (solid, gas) Not applicable
SDS No.:
Date of Preparation:
0440 Page
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0704
April 08, 2015
Product Identifier: Big D Drip Deodorant Concentrate, Mountain Air
Saturated Vapour Concentration Not available
Chemical Stability
Normally stable.
Conditions to Avoid
None known.
Incompatible Materials
None known.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
Skin Corrosion/Irritation
No information was located.
Serious Eye Damage/Irritation
No information was located.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
Acute Toxicity
No information was located.
Aspiration Hazard
Skin contact; eye contact; ingestion; inhalation.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
2-Propanol 72.6 mg/L (rat) (vapour) 4396 mg/kg (rat) 12870 mg/kg (rabbit)
1,2-Propylene glycol 22000 mg/kg (mouse) 20800 mg/kg (rabbit)
Linalyl Acetate 14550 mg/kg (rat) > 5000 mg/kg (rabbit)
LINALYL ALCOHOL 3000 mg/kg (mouse) 5610 mg/kg (rat)
COUMARIN 293 mg/kg (rat)
SDS No.:
Date of Preparation:
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0705
April 08, 2015
Product Identifier: Big D Drip Deodorant Concentrate, Mountain Air
Carcinogenicity
ACGIH®: A4 – Not classifiable as a human carcinogen.
Development of Offspring
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
No information was located.
Interactive Effects
No information was located.
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
Chemical Name IARC ACGIH® NTP OSHA
2-Propanol A4
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
Toxicity
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea
ErC50 Aquatic
Plants
ErC50 Algae
2-Propanol 9640 mg/L
(Pimephales
promelas (fathead
minnow); 96-hour)
13299 mg/L
(Daphnia magna
(water flea); 48-hour)
> 1000 mg/L
(96-hour)
COUMARIN 32-100 mg/L
(96-hour)
SECTION 13. DISPOSAL CONSIDERATIONS
This product is a non-hazardous waste.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions
for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Safety, Health and Environmental Regulations
SDS No.:
Date of Preparation:
0440 Page
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0706
April 08, 2015
Product Identifier: Big D Drip Deodorant Concentrate, Mountain Air
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
CEPA - National Pollutant Release Inventory (NPRI)
Part 1A. (Polyethylene glycol octylphenyl ether, liquids)
Part 1A. (2-Propanol)
Part 5. (2-Propanol)
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
Additional USA Regulatory Lists
California Proposition 65: Ethylene Oxide (CAS 75-21-8) Formaldehyde (CAS 50-00-0) 1,4-Dioxane (CAS
123-91-1) Acetaldehyde (CAS 75-07-0)
California Proposition 65 - Developmental Toxin: Ethylene Oxide (CAS 75-21-8)
Massachusetts Right To Know. (2-Propanol) Pin-2(3)-ene (CAS 80-56-8)
New Jersey Right To Know. (2-Propanol) p-Mentha-1,4(8)-diene (CAS 586-62-9) Pin-2(3)-ene (CAS 80-56-8)
Benzyl Acetate (CAS 140-11-4)
Pennsylvania Right To Know. (2-Propanol) Pin-2(3)-ene (CAS 80-56-8)
Rhode Island Right To Know. (2-Propanol)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
Class D2B
D2B - Toxic (Eye irritant)
Additional Information
Please Note: This MSDS pertains to batch labels 292000 and higher of the above referenced
product (see section 1). Batches before January 1st, 2013 should use the previously issued
MSDS. Contact Big D Industries for the prior MSDS.
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
April 08, 2015
Health - 1 Flammability - 0 Instability - 0
SDS No.:
Date of Preparation:
0440 Page
of
0707
April 08, 2015
Product Identifier: Big D Drip Deodorant Concentrate, Mountain Air
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