Big D Industries 150 User Manual

Product Identifier Big D Granular Deodorant Other Means of
Identification
147, 150, & 151
Other Identification Granular Deodorant
Recommended Use
SDS No.
Product Family Dry Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Supplier
Manufacturer
Dry Deodorants.
0288
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word: Danger
May cause cancer if inhaled.
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection.
Response: IF exposed or concerned: Get medical advice/attention.
Storage: Store locked up.
GHS Classification
Carcinogenicity - Category 1
SDS No.: Date of Preparation:
0288 Page
of
0601
February 19, 2015
Product Identifier: Big D Granular Deodorant
Safety Data Sheet
Big D Granular Deodorant
Disposal: Dispose of contents/container to An appropriate waste container to minimize dust. Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Silica, quartz 14808-60-7 6 Montmorillonite ((Al1.33-1.67Mg0.33-0.
67)(Ca0-1Na0-1)0.33Si4(OH)2O10.xH2O), calcined
70892-59-0 75
Silica, cristobalite 14464-46-1 2.4 Other components below reportable Levels No CAS 17.47 Fragrance No CAS 0.04
Inhalation
Move to fresh air. Call a Poison Centre or doctor if you feel unwell or are concerned.
Skin Contact
Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes. Call a Poison Centre or doctor if you feel unwell or are concerned.
Eye Contact
Rinse the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding the eyelid(s) open.
Ingestion
Never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing. Do not induce vomiting. Immediately call a Poison Centre or doctor.
Special Instructions
Not applicable.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
If inhaled: Can cause severe irritation of the nose and throat. If in eyes: May cause mild irritation. If swallowed: Large amounts symptoms may include nausea, vomiting, stomach cramps and diarrhea.
Extinguishing Media
Suitable Extinguishing Media
SECTION 5. FIRE-FIGHTING MEASURES
SDS No.: Date of Preparation:
0288 Page
of
0602
February 19, 2015
Product Identifier: Big D Granular Deodorant
Suitable Extinguishing Media
Not combustible. Use extinguishing agent suitable for surrounding fire.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Does not burn. This product presents no unusual hazards in a fire situation. Not known to generate any hazardous decomposition products in a fire.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary. See Skin Protection in Section 8 (Exposure Controls/Personal Protection) for advice on suitable chemical protective materials.
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary.
Environmental Precautions
Do not allow into any sewer, on the ground or into any waterway.
Methods and Materials for Containment and Cleaning Up
Avoid generating dust.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
Do not breathe in this product. Only use where there is adequate ventilation.
Conditions for Safe Storage
Separate from incompatible materials (see Section 10: Stability and Reactivity).
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Montmorillonite ((Al1.33-1.67Mg0. 33-0.67)(Ca0-1Na0-1)0. 33Si4(OH)2O10.xH2O), calcined
0.05 mg/m3 5 mg/m3
Silica, cristobalite 0.05 mg/m3 5 mg/m3 Silica, quartz 0.05 mg/m3 5 mg/m3
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Eye/Face Protection
Not required, if used as directed.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
Use a local exhaust ventilation and enclosure, if necessary, to control amount in the air.
Appearance Dark pellets.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
SDS No.: Date of Preparation:
0288 Page
of
0603
February 19, 2015
Product Identifier: Big D Granular Deodorant
pH Not applicable
Partition Coefficient, n-Octanol/Water (Log Kow)
Not available
Odour Fragrant (Fragrance)
Vapour Pressure Not applicable
Odour Threshold Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range Not applicable
Evaporation Rate Not applicable
Flash Point > 200 ºF (estimated) (Montmorillonite ((Al1.33-1.67Mg0.33-0.
67)(Ca0-1Na0-1)0.33Si4(OH)2O10.xH2O), calcined)
Melting Point/Freezing Point Not applicable (freezing)
Relative Density (water = 1) Not applicable
Upper/Lower Flammability or Explosive Limit
Not available (upper); Not available (lower)
Solubility Insoluble (less than 1 mg/L) in water
Auto-ignition Temperature Not available
Not availableDecomposition Temperature
Viscosity Not applicable (kinematic); Not applicable (dynamic)
SolidPhysical State
Other Information
Flammability (solid, gas) Not available
Chemical Stability
Normally stable.
Conditions to Avoid
Incompatible materials.
Incompatible Materials
Unsaturated hydrocarbons (e.g. turpentine), strong acids (e.g. hydrochloric acid).
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Not reactive.
LC50: No information was located. LD50 (oral): No information was located.
Skin Corrosion/Irritation
No information was located.
SECTION 11. TOXICOLOGICAL INFORMATION
LD50 (dermal): No information was located.
Acute Toxicity
Inhalation; skin contact; eye contact; ingestion.
Likely Routes of Exposure
SDS No.: Date of Preparation:
0288 Page
of
0604
February 19, 2015
Product Identifier: Big D Granular Deodorant
Serious Eye Damage/Irritation
No information was located.
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
Development of Offspring
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
No information was located.
Interactive Effects
No information was located.
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
Not known to be an aspiration hazard.
Aspiration Hazard
Chemical Name IARC ACGIH® NTP OSHA
Montmorillonite ((Al1. 33-1.67Mg0.33-0.
67)(Ca0-1Na0-1)0. 33Si4(OH)2O10.xH2O), calcined
Known carcinogen
Silica, cristobalite Known carcinogen Silica, quartz Known carcinogen
SECTION 12. ECOLOGICAL INFORMATION
Environmental information was not located.
SECTION 13. DISPOSAL CONSIDERATIONS
The required hazard evaluation of the waste and compliance with the applicable hazardous waste laws are the responsibility of the user.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
SDS No.: Date of Preparation:
0288 Page
of
0605
February 19, 2015
Product Identifier: Big D Granular Deodorant
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL/NDSL.
USA
US OSHA HazCom 1994 Regulatory Status
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200 (1994)).
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are listed on the TSCA Inventory.
Additional USA Regulatory Lists
California Proposition 65. (Silica, cristobalite). (Silica, quartz) SARA Title III - Section 311/312. (Silica, cristobalite). (Silica, quartz)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all of the information required by the Controlled Products Regulations.
Safety, Health and Environmental Regulations
Class D2A
D2A - Very Toxic
Key to Abbreviations
ACGIH® = American Conference of Governmental Industrial Hygienists NFPA = National Fire Prevention Association NTP = National Toxicology Program OSHA = US Occupational Safety and Health Administration NTP = National Toxicology Program
SECTION 16. OTHER INFORMATION
NFPA Rating SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
February 19, 2015
Revision Indicators
The following SDS content was changed on February 17, 2015: (English SDS).
Health - 1 Flammability - 0 Instability - 0
SDS No.: Date of Preparation:
0288 Page
of
0606
February 19, 2015
Product Identifier: Big D Granular Deodorant
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