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SAFETY DATA SHEET
1. Identification
Product number
Product identifier 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Company information
Company phone
Emergency telephone US
Emergency telephone outside
US
Version #
Recommended use
Recommended restrictions
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
1000026160
BIG D INDUSTRIES
OKLAHOMA CITY, OK 73148-0219 United States
General Assistance 405-682-2541
1-866-836-8855
1-952-852-4646
01
Cleaner
None known.
Category 1Flammable aerosols
Category 1Reproductive toxicity
Not classified.
Not classified.
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Danger
Extremely flammable aerosol. May damage fertility or the unborn child.
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not
spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn,
even after use. Wear protective gloves/protective clothing/eye protection/face protection.
If exposed or concerned: Get medical advice/attention.
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Dispose of contents/container in accordance with local/regional/national/international regulations.
None known.
None.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
106-97-8Butane
112-34-5Diethylene Glycol Monobutyl Ether
74-98-6Propane
Other components below reportable levels 80 - 90
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
2.5 - 10
2.5 - 10
1 - 2.5
4. First-aid measures
Inhalation
Product name: 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Product #: 1000026160 Version #: 01 Issue date: 03-20-2015
If symptoms develop move victim to fresh air. Get medical attention if symptoms persist.
SDS US
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Skin contact
water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
when handling the product must be grounded. Do not re-use empty containers. Use only in
well-ventilated areas. Should be handled in closed systems, if possible. Pregnant or breastfeeding
women must not handle this product. Wear appropriate personal protective equipment. Observe
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
Specific methods
General fire hazards
Wash off with soap and water. Get medical attention if irritation develops and persists.
Rinse with water. Get medical attention if irritation develops and persists.
In the unlikely event of swallowing contact a physician or poison control center.
Direct contact with eyes may cause temporary irritation.
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in
attendance.
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Move containers from fire area if you can do so without risk. Containers should be cooled with
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Use standard firefighting procedures and consider the hazards of other involved materials. Move
containers from fire area if you can do so without risk. In the event of fire and/or explosion do not
breathe fumes.
Extremely flammable aerosol.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no
smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)
away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and
open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in
vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray
button is missing or defective. Do not spray on a naked flame or any other incandescent material.
Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill,
grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used
good industrial hygiene practices.
Product name: 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Product #: 1000026160 Version #: 01 Issue date: 03-20-2015
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Conditions for safe storage,
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
wash work clothing and protective equipment to remove contaminants.
Level 1 Aerosol.
including any incompatibilities
Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures
exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open
flame, heat or other sources of ignition. This material can accumulate static charge which may
cause spark and become an ignition source. Refrigeration recommended. Store away from
incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
PEL 1800 mg/m3Propane (CAS 74-98-6)
ValueComponents Type
1000 ppm
Type
STEL 1000 ppmButane (CAS 106-97-8)
Diethylene Glycol
TWA 10 ppm Inhalable fraction and
Monobutyl Ether (CAS
112-34-5)
TWA 1900 mg/m3Butane (CAS 106-97-8)
TWA 1800 mg/m3Propane (CAS 74-98-6)
Biological limit values
Appropriate engineering
controls
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection
Hand protection
Chemical respirator with organic vapor cartridge and full facepiece.
Wear appropriate chemical resistant gloves.
Skin protection
Other
Use of an impervious apron is recommended.
Skin protection
Respiratory protection
Thermal hazards
General hygiene
considerations
Chemical respirator with organic vapor cartridge and full facepiece.
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
ValueComponents
ValueComponents Type
800 ppm
1000 ppm
Form
vapor.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Product name: 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Product #: 1000026160 Version #: 01 Issue date: 03-20-2015
Liquid.
Aerosol.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
-156.0 °F (-104.4 °C) Propellant estimated
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Evaporation rate
Ingestion
Inhalation
Skin contact
Eye contact
Acute toxicity
Flammability (solid, gas)
Not available.
Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
1.9 % estimated
(%)
Flammability limit - upper
9.5 % estimated
(%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Relative density
Not available.
Not available.
65 psig @70F estimated
Not available.
Not available.
Solubility(ies)
Solubility (water)
Partition coefficient
Not available.
Not available.
(n-octanol/water)
Auto-ignition temperature
Decomposition temperature
Viscosity
Not available.
Not available.
Not available.
Other information
Specific gravity
0.977 estimated
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
Hazardous polymerization does not occur.
Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Strong oxidizing agents.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Expected to be a low ingestion hazard.
No adverse effects due to inhalation are expected.
No adverse effects due to skin contact are expected.
Direct contact with eyes may cause temporary irritation.
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Butane (CAS 106-97-8)
Acute
Inhalation
LC50 Mouse
Direct contact with eyes may cause temporary irritation.
Rat 1355 mg/l
Test ResultsComponents Species
1237 mg/l, 120 Minutes
52 %, 120 Minutes
Product name: 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Product #: 1000026160 Version #: 01 Issue date: 03-20-2015
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Diethylene Glycol Monobutyl Ether (CAS 112-34-5)
Respiratory sensitization
Carcinogenicity
Aspiration hazard
Partition coefficient n-octanol / water (log Kow)
Acute
Dermal
LD50 Guinea pig
Rabbit 2764 mg/kg, 24 Hours
Oral
LD100 Rabbit
LD50 Guinea pig 2000 mg/kg
Mouse 2410 mg/kg
Rabbit 2500 - 3000 mg/kg
Rat 3306 mg/kg
Propane (CAS 74-98-6)
Acute
Inhalation
LC50 Mouse
Rat 1355 mg/l
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Serious eye damage/eye
Prolonged skin contact may cause temporary irritation.
Direct contact with eyes may cause temporary irritation.
irritation
Respiratory or skin sensitization
Not available.
Skin sensitization
Germ cell mutagenicity
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity
Specific target organ toxicity -
May damage fertility or the unborn child.
Not classified.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Not available.
Test ResultsComponents Species
2 ml/kg, 2 Days
4000 mg/kg
1237 mg/l, 120 Minutes
52 %, 120 Minutes
658 mg/l/4h
12. Ecological information
Ecotoxicity
Components Test ResultsSpecies
Diethylene Glycol Monobutyl Ether (CAS 112-34-5)
Aquatic
* Estimates for product may be based on additional component data not shown.
Persistence and degradability
Bioaccumulative potential
Butane 2.89
Diethylene Glycol Monobutyl Ether 0.56
Product name: 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Product #: 1000026160 Version #: 01 Issue date: 03-20-2015
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
LC50Fish 1300 mg/l, 96 hoursBluegill (Lepomis macrochirus)
No data is available on the degradability of this product.
No data available.
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Partition coefficient n-octanol / water (log Kow)
Propane 2.36
with local/regional/national/international regulations.
Mobility in soil
Other adverse effects
No data available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents
under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance
Local disposal regulations
Hazardous waste code
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
products
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Do not re-use empty containers.
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity.
Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond
mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20
and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
ERG Code
Special precautions for user
Other information
Passenger and cargo
aircraft
Cargo aircraft only
Packaging Exceptions
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Class
UN1950
Aerosols, flammable, (each not exceeding 1 L capacity)
2.1
-
2.1
Not applicable.
Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
N82
306
None
None
UN1950
Aerosols, flammable
2.1
-
2.1
Not applicable.
No.
10L
Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
Allowed.
Allowed.
LTD QTY
UN1950
AEROSOLS
2.1
Product name: 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Product #: 1000026160 Version #: 01 Issue date: 03-20-2015
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Subsidiary risk
Label(s)
Packing group
Environmental hazards
Marine pollutant
EmS
Special precautions for user
Packaging Exceptions
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
DOT
IATA; IMDG
None
Not applicable.
No.
F-D, S-U
Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
LTD QTY
Not applicable.
15. Regulatory information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
Immediate Hazard - No
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
No
Product name: 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Product #: 1000026160 Version #: 01 Issue date: 03-20-2015
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Other federal regulations
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
Safe Drinking Water Act
Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
US. New Jersey Worker and Community Right-to-Know Act
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
US. Pennsylvania Worker and Community Right-to-Know Law
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
US. Rhode Island RTK
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Substances (EINECS)
(PICCS)
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
NoAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
NoChina Inventory of Existing Chemical Substances in China (IECSC)
NoEurope European Inventory of Existing Commercial Chemical
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
NoKorea Existing Chemicals List (ECL)
NoNew Zealand New Zealand Inventory
NoPhilippines Philippine Inventory of Chemicals and Chemical Substances
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
country(s).
16. Other information, including date of preparation or last revision
Issue date
Version #
Disclaimer
Revision Information
Product name: 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Product #: 1000026160 Version #: 01 Issue date: 03-20-2015
03-20-2015
01
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Product and Company Identification: Product and Company Identification
GHS: Classification
SDS US
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