Big D 98 User Manual
SAFETY DATA SHEET
1. Identification
Product number
Product identifier 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Company information
Company phone
Emergency telephone US
Emergency telephone outside
US
Version #
Recommended use
Recommended restrictions
2. Hazard(s) identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
1000026160
BIG D INDUSTRIES
OKLAHOMA CITY, OK 73148-0219 United States
General Assistance 405-682-2541
1-866-836-8855
1-952-852-4646
01
Cleaner
None known.
Category 1Flammable aerosols
Category 1Reproductive toxicity
Not classified.
Not classified.
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
Danger
Extremely flammable aerosol. May damage fertility or the unborn child.
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not
spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn,
even after use. Wear protective gloves/protective clothing/eye protection/face protection.
If exposed or concerned: Get medical advice/attention.
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Dispose of contents/container in accordance with local/regional/national/international regulations.
None known.
None.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
106-97-8Butane
112-34-5Diethylene Glycol Monobutyl Ether
74-98-6Propane
Other components below reportable levels 80 - 90
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
2.5 - 10
2.5 - 10
1 - 2.5
4. First-aid measures
Inhalation
Product name: 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Product #: 1000026160 Version #: 01 Issue date: 03-20-2015
If symptoms develop move victim to fresh air. Get medical attention if symptoms persist.
SDS US
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Skin contact
water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
when handling the product must be grounded. Do not re-use empty containers. Use only in
well-ventilated areas. Should be handled in closed systems, if possible. Pregnant or breastfeeding
women must not handle this product. Wear appropriate personal protective equipment. Observe
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
Specific methods
General fire hazards
Wash off with soap and water. Get medical attention if irritation develops and persists.
Rinse with water. Get medical attention if irritation develops and persists.
In the unlikely event of swallowing contact a physician or poison control center.
Direct contact with eyes may cause temporary irritation.
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in
attendance.
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Move containers from fire area if you can do so without risk. Containers should be cooled with
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Use standard firefighting procedures and consider the hazards of other involved materials. Move
containers from fire area if you can do so without risk. In the event of fire and/or explosion do not
breathe fumes.
Extremely flammable aerosol.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no
smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)
away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and
open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in
vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray
button is missing or defective. Do not spray on a naked flame or any other incandescent material.
Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill,
grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used
good industrial hygiene practices.
Product name: 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Product #: 1000026160 Version #: 01 Issue date: 03-20-2015
SDS US
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Conditions for safe storage,
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
US. ACGIH Threshold Limit Values
US. NIOSH: Pocket Guide to Chemical Hazards
wash work clothing and protective equipment to remove contaminants.
Level 1 Aerosol.
including any incompatibilities
Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures
exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open
flame, heat or other sources of ignition. This material can accumulate static charge which may
cause spark and become an ignition source. Refrigeration recommended. Store away from
incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
PEL 1800 mg/m3Propane (CAS 74-98-6)
ValueComponents Type
1000 ppm
Type
STEL 1000 ppmButane (CAS 106-97-8)
Diethylene Glycol
TWA 10 ppm Inhalable fraction and
Monobutyl Ether (CAS
112-34-5)
TWA 1900 mg/m3Butane (CAS 106-97-8)
TWA 1800 mg/m3Propane (CAS 74-98-6)
Biological limit values
Appropriate engineering
controls
No biological exposure limits noted for the ingredient(s).
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection
Hand protection
Chemical respirator with organic vapor cartridge and full facepiece.
Wear appropriate chemical resistant gloves.
Skin protection
Other
Use of an impervious apron is recommended.
Skin protection
Respiratory protection
Thermal hazards
General hygiene
considerations
Chemical respirator with organic vapor cartridge and full facepiece.
Wear appropriate thermal protective clothing, when necessary.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
ValueComponents
ValueComponents Type
800 ppm
1000 ppm
Form
vapor.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Product name: 18 OZ BIG D CARPET SPOT REMOVER LB 12PK
Product #: 1000026160 Version #: 01 Issue date: 03-20-2015
Liquid.
Aerosol.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
-156.0 °F (-104.4 °C) Propellant estimated
SDS US
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