Product Identifier Big D Pheno D +
Other Means of
Identification
033700
Other Identification Pheno D
Recommended Use
SDS No.
Product Family Aerosol Disinfectant
Emergency Phone No.
SECTION 1. IDENTIFICATION
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Supplier
Deodorant Disinfectant.
0940
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Warning
Hazard Statement(s):
H223 Flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
Precautionary Statement(s):
P210 Keep away from heat, sparks, open flames, and hot surfaces. – No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P264 Wash hands and skin thoroughly after handling.
P280 Wear eye protection/face protection.
Response:
GHS Classification
Flammable aerosol - Category 2; Gas under pressure - Compressed gas; Serious eye damage/eye irritation - Category
2A; Specific target organ toxicity (single exposure) - Category 3
SDS No.:
Date of Preparation:
0940 Page
of
0601
October 21, 2020
Product Identifier: Big D Pheno D +
Safety Data Sheet
Big D Pheno D +
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTRE/doctor if you feel unwell.
Storage:
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Ethanol 64-17-5 40-70
n-Butane 106-97-8 5-15
Propane 74-98-6 5-15
o-Phenylphenol 90-43-7 0.1-1
Inhalation
Move to fresh air. Call a Poison Centre or doctor if you feel unwell or are concerned. If breathing is difficult, trained
personnel should administer emergency oxygen if advised to do so by Poison Centre or doctor.
Skin Contact
Immediately rinse with lukewarm, gently flowing water for 15-20 minutes. Thoroughly clean clothing, shoes and
leather goods before reuse or dispose of safely. If skin irritation occurs get medical advice/attention.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open. If eye irritation persists, get medical advice/attention.
Ingestion
Call a Poison Centre or doctor if you feel unwell or are concerned. Rinse mouth with water.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
Eye conditions, skin conditions, respiratory conditions.
Most Important Symptoms and Effects, Acute and Delayed
If inhaled:
Can cause severe irritation of the nose and throat.
If on skin:
Repeated or prolonged exposure can irritate the skin.
If in eyes:
Causes moderate to severe irritation. Symptoms include sore, red eyes, and tearing.
If swallowed:
Can irritate the mouth, throat and stomach. Symptoms may include nausea, vomiting, stomach cramps and diarrhea.
SDS No.:
Date of Preparation:
0940 Page
of
0602
October 21, 2020
Product Identifier: Big D Pheno D +
Extinguishing Media
Suitable Extinguishing Media
Carbon dioxide, dry chemical powder, appropriate foam, water spray or fog.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Flammable aerosol.
Closed containers may rupture violently when heated releasing contents.
Special Protective Equipment and Precautions for Fire-fighters
A full-body encapsulating chemical protective suit with positive pressure SCBA may be necessary.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
Use the personal protective equipment recommended in Section 8 of this safety data sheet.
Environmental Precautions
Do not allow into any sewer, on the ground or into any waterway.
Methods and Materials for Containment and Cleaning Up
Do not use absorbents. Contain spill using noncombustible material such as vermiculite, earth or sand.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
Only use where there is adequate ventilation.
It is good practice to: avoid breathing product; avoid skin and eye contact and wash hands after handling.
Conditions for Safe Storage
Store in an area that is: cool, dry, out of direct sunlight and away from heat and ignition sources.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
n-Butane 1000 ppm
Propane 1000 ppm 1000 ppm
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Not normally required if product is used as directed. Wear NIOSH/MSHA approved respiratory protection if used in
confined, poorly ventilated areas.
Avoid repeated or prolonged skin contact.
Suitable materials are: neoprene rubber.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
General ventilation is usually adequate.
SDS No.:
Date of Preparation:
0940 Page
of
0603
October 21, 2020
Product Identifier: Big D Pheno D +
pH 6.9 - 7.7
Appearance Clear colourless - colourless.
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Odour Citrus
Vapour Pressure 44 mm Hg (6 kPa) at 25 ºC (77 ºF)
Odour Threshold Not available
Vapour Density (air = 1) > 1.00
Initial Boiling Point/Range > 170 ºF (77 ºC)
Evaporation Rate 1.00 (n-butyl acetate = 1)
Flash Point Not available
Melting Point/Freezing Point Not available (freezing)
Relative Density (water = 1) 0.88 at 77 ºF (25 ºC)
Upper/Lower Flammability or
Explosive Limit
Not applicable (upper); Not applicable (lower)
Solubility Soluble in all proportions in water
Auto-ignition Temperature Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Not availableDecomposition Temperature
Viscosity Not available (kinematic); Not available (dynamic)
Basic Physical and Chemical Properties
Flammability (solid, gas) Flammable gas.
Chemical Stability
Normally stable.
Conditions to Avoid
Temperatures above 120.0 ºF (48.9 ºC)
Incompatible Materials
Strong alkalis, oxidizers, bases, reactive metals, and natural rubber.
Not corrosive to metals.
Hazardous Decomposition Products
Oxides of carbon.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Eye contact; ingestion; inhalation; skin contact.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Propane > 115.9 ppm (rat) (4-hour
exposure)
7800 mg/kg (rat)
SDS No.:
Date of Preparation:
0940 Page
of
0604
October 21, 2020
Product Identifier: Big D Pheno D +
Skin Corrosion/Irritation
Repeated or prolonged exposure can irritate the skin.
Serious Eye Damage/Irritation
Causes moderate to severe irritation. Symptoms include sore, red eyes, and tearing.
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
Acute exposure may cause nausea, vomiting, coughing and pulmonary irritation.
Skin Absorption
May cause mild irritation with prolonged or repeated contact.
Ingestion
Can irritate the mouth, throat and stomach. Symptoms may include nausea, vomiting, stomach cramps and
diarrhea.
Carcinogenicity
Not known to be an aspiration hazard.
Aspiration Hazard
Chemical Name IARC ACGIH® NTP OSHA
Propane Group 1 A3
This product is not expected to bioaccumulate.
This product is mobile in soil.
None known
SECTION 12. ECOLOGICAL INFORMATION
Component or components of this product are not biodegradable.
Toxicity
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea
ErC50 Aquatic
Plants
ErC50 Algae
Propane > 100.1 mg/L
(Pimephales
promelas (fathead
minnow); 96-hour)
7700-11200 mg/L
(Daphnia magna
(water flea); 48-hour)
SECTION 13. DISPOSAL CONSIDERATIONS
Contact local environmental authorities for approved disposal or recycling methods in your jurisdiction. The container
for this product can present explosion or fire hazards, even when emptied. Do not cut, puncture, or weld on or near this
container.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
UN No. Proper Shipping Name
Packing
Group
Transport Hazard
Class(es)
Regulation
SDS No.:
Date of Preparation:
0940 Page
of
0605
October 21, 2020
Product Identifier: Big D Pheno D +
1950
Aerosols, flammable
2.1
IATA (Air)
1950
Aerosols, flammable
2.1
US DOT
1950
Aerosols, flammable
2.1
IMO (Marine)
Special Precautions
for User
Please note: US DOT Exceptions: Limited Quantity
Other Information
DOT: This material may ship by passenger plane as: UN1950, Aerosols, 2.1, Limited
Quantity. Must have a flammable label and Limited Quantity (Y) label if shipping by air.
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
Additional USA Regulatory Lists
CERCLA: Fire Hazard
SARA Title III - Section 311/312. (Ethanol) acute, chronic, flammable.
SARA Title III - Section 313. (Ethanol) acute, chronic, flammable.
California Proposition 65. (o-Phenylphenol)
EPA Registration No.: 44446-67-7052.
Safety, Health and Environmental Regulations
Class A Class B5 Class D2B
A - Compressed Gas; B5 - Flammable Aerosol; D2B - Toxic
Disclaimer
This Safety Data Sheet has been prepared in accordance with the Globally Harmonized
System for the Classification and Labeling of Chemical (GHS) TO the best of our knowledge
the information herein is accurate. However, the supplier makes no warranty and assume no
liability resulting from its use. In No event shall the supplier be liable for any claims, losses, or
damages of any third party resulting from the use of or reliance upon this information.
SECTION 16. OTHER INFORMATION
NFPA Rating
Date of Preparation
October 21, 2020
Health - 1 Flammability - 3 Instability - 1
SDS No.:
Date of Preparation:
0940 Page
of
0606
October 21, 2020
Product Identifier: Big D Pheno D +
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