Product Identifier Big D Carpet Freshener
Other Means of
Identification
241
Other Identification Textile Deodorant
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Aerosol Products
Emergency Phone No.
SECTION 1. IDENTIFICATION
Manufacturer
Deodorant.
0280
Big D Industries, 800 535 5053, 24hr (Infotrac)
Date of Preparation
January 23, 2015
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Danger
Hazard Statement(s):
H222 Extremely flammable aerosol.
H332 Harmful if inhaled.
Precautionary Statement(s):
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P261 Avoid breathing vapours.
P271 Use only outdoors or in a well-ventilated area.
Response:
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
GHS Classification
Flammable aerosol - Category 1; Acute toxicity (Inhalation) - Category 4
SDS No.:
Date of Preparation:
0280 Page
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0701
January 23, 2015
Product Identifier: Big D Carpet Freshener
Safety Data Sheet
Big D Carpet Freshener
P312 Call a POISON CENTRE/doctor/ if you feel unwell.
Storage:
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
Note:
% of the mixture consists of ingredient(s) of unknown acute toxicity.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Other components below reportable Levels No CAS 80-90
n-Butane 106-97-8 2.5-10
Ethanol 64-17-5 2.5-10
Propane 74-98-6 1.0-2.5
Inhalation
Move to fresh air. Get medical advice/attention if you feel unwell or are concerned.
Skin Contact
Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes. Get medical
advice/attention if you feel unwell or are concerned.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the
eyelid(s) open. Remove contact lenses, if present and easy to do. If eye irritation persists, get medical
advice/attention.
Ingestion
Rinse mouth with water. Immediately call a Poison Centre or doctor.
First-aid Comments
Get medical advice/attention if you feel unwell or are concerned.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Extinguishing Media
Suitable Extinguishing Media
Special "alcohol resistant fire-fighting foams". Carbon dioxide, dry chemical powder or appropriate foam.
Unsuitable Extinguishing Media
Water is not effective for extinguishing a fire. It may not cool product below its flash point.
Specific Hazards Arising from the Chemical
Extremely flammable aerosol.
Very toxic carbon monoxide, carbon dioxide.
Special Protective Equipment and Precautions for Fire-fighters
SECTION 5. FIRE-FIGHTING MEASURES
SDS No.:
Date of Preparation:
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Product Identifier: Big D Carpet Freshener
Special Protective Equipment and Precautions for Fire-fighters
Use extreme caution.
Chemical protective clothing (e.g. chemical splash suit) and positive pressure SCBA may be necessary.
Personal Precautions, Protective Equipment, and Emergency Procedures
Evacuate downwind locations. Use the personal protective equipment recommended in Section 8 of this safety data
sheet.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
Do not use absorbents. Contain spill using noncombustible material such as vermiculite, earth or sand. Place used
absorbent into suitable, covered, labelled containers for disposal.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
Prevent skin contact. Avoid repeated or prolonged skin contact. Do not get in eyes. Only use where there is adequate
ventilation. Do not spray on an open flame or other ignition source. Do not pierce or burn container, even after use.
Conditions for Safe Storage
Store in an area that is: cool, dry, well-ventilated, out of direct sunlight and away from heat and ignition sources.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
n-Butane 1000 ppm 800 ppm
Ethanol 1000 ppm 1000 ppm
Propane 1000 ppm 1000 ppm
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Not normally required if product is used as directed.
Wear chemical protective clothing e.g. gloves, aprons, boots.
Wear chemical safety goggles and face shield when contact is possible.
General ventilation is usually adequate.
pH Not available
Appearance Clear gas.
Odour Fragrant
Odour Threshold Not available
Initial Boiling Point/Range ~ 212 ºF (100 ºC)
Flash Point -156.0 ºF (-104.4 ºC) (estimated)
Melting Point/Freezing Point Not applicable (melting)
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
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Product Identifier: Big D Carpet Freshener
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Vapour Pressure 184.03 kPa (1380.21 mm Hg) at 68 ºF (20 ºC) (estimated)
Vapour Density (air = 1) Not available
Evaporation Rate Not available
Relative Density (water = 1) Not available
Upper/Lower Flammability or
Explosive Limit
9.5% (estimated) (upper); 3.5% (estimated) (lower)
Solubility Not available in water; Not available (in other liquids)
Auto-ignition Temperature 699.8 ºF (371.0 ºC) (estimated)
Not availableDecomposition Temperature
Viscosity Not available (kinematic); Not available (dynamic)
Other Physical Property 3 Specific Gravity 0.943 estimated
Other Information
Flammability (solid, gas) Not available
Chemical Stability
Normally stable.
Conditions to Avoid
None known.
Incompatible Materials
None known.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None expected under normal conditions of storage and use.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions of use.
Skin Corrosion/Irritation
There is limited evidence of very mild irritation.
Serious Eye Damage/Irritation
There is limited evidence of serious eye irritation.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Ingestion; inhalation; skin contact; eye contact.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
n-Butane 1237 mg/L (mouse) (2-hour
exposure)
Ethanol > 115.9 ppm (rat) (4-hour
exposure)
7800 mg/kg (rat)
Propane 658 mg/L (rat) (4-hour
exposure)
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Date of Preparation:
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Product Identifier: Big D Carpet Freshener
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located. May be harmful based on limited evidence.
Skin Absorption
Not harmful based on limited evidence.
Ingestion
No information was located.
Not Classified.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located.
Carcinogenicity
Conclusions cannot be drawn from the limited studies available.
Development of Offspring
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
Not known to be a mutagen.
Interactive Effects
No information was located.
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
No information was located.
Aspiration Hazard
Chemical Name IARC ACGIH® NTP OSHA
Ethanol Group 1 A3
No information was located.
Studies are not available.
There is no information available.
SECTION 12. ECOLOGICAL INFORMATION
No information was located.
Toxicity
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea
ErC50 Aquatic
Plants
ErC50 Algae
Ethanol > 100.1 mg/L
(Pimephales
promelas (fathead
minnow); 96-hour)
7700-11200 mg/L
(Daphnia magna
(water flea); 48-hour)
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Date of Preparation:
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January 23, 2015
Product Identifier: Big D Carpet Freshener
SECTION 13. DISPOSAL CONSIDERATIONS
Contact local environmental authorities for approved disposal or recycling methods in your jurisdiction.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
UN No. Proper Shipping Name
Packing
Group
Transport Hazard
Class(es)
Regulation
1950 AEROSOLS (Aerosols, Flammable, (each not
exceeding 1 L capacity))
2.1 Not
Applicable
US DOT
1950 AEROSOLS (Aerosols, Flammable) 2.1 Not
Applicable
Canadian TDG
1950
AEROSOLS (Aerosols, Flammable)
2.1
II
Canadian TDG
Other Information
DOT: This material may ship by passenger plane as: UN1950, Aerosols, 2.1, Limited
Quantity. Must have a flammable label and Limited Quantity (Y) label if shipping by air. DOT:
This product meets the exception requirements of section 173.306 as a limited quantity and
may be shipped as a limited quantity. IATA: This product meets the exception requirements
as a limited quantity and may be shipped as a limited quantity. Follow all rules and regulations
to do so.
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
Not listed on the DSL or NDSL.
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
Additional USA Regulatory Lists
SARA Title III - Section 313: Diethanolamine CAS 111-42-2 0.1 - 1.0% by wt.
Pennsylvania Right To Know. (2-Propanol)
Rhode Island Right To Know. (1,1-Difluoroethane). (2-Propanol)
California Proposition 65: Diethanolamine CAS 111-42-2 0.1 - 1.0% by wt.
SARA Title III - Section 302: Ethylene Oxide (CAS 75-21-8) Reportable Quantity 10 Threshold Planning Quantity
1000lbs
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
the SDS contains all of the information required by the Controlled Products Regulations.
Safety, Health and Environmental Regulations
Class B5 Class D2B
B5 - Flammable Aerosol; D2B - Toxic (Eye irritant)
SDS No.:
Date of Preparation:
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Product Identifier: Big D Carpet Freshener
Formaldehyde (CAS 50-00-0) Reportable Quantity 100lbs Threshold Planning Quantity 500lbs
SARA Title III - Section 313: 1,4-Dioxane (CAS 123-91-1) 0.01-0.1 % by weight
Acetaldehyde (CAS 75-07-0) 0.01-0.1 % by weight
Ethylene Oxide (CAS 75-21-8) 0.01-0.1 % by weight
Formaldehyde (CAS 50-00-0) 0.01-0.1 % by weight
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130). (n-Butane). (Propane)
Massachusetts Right To Know. (Propane). (Ethanol). (n-Butane)
New Jersey Right To Know. (n-Butane). (Ethanol). (Propane)
Pennsylvania Right To Know. (Propane). (Ethanol). (n-Butane)
Rhode Island Right To Know. (n-Butane). (Propane)
California Proposition 65: California Proposition 65 - Carcinogenic Substance: Ethylene Oxide (CAS 75-21-8)
Formaldehyde (CAS 50-00-0) 1,4-Dioxane (CAS 123-91-1) Acetaldehyde (CAS 75-07-0)
California Proposition 65 - Developmental Toxin: Ethylene Oxide (CAS 75-21-8)
California Proposition 65 - Female Reproductive Toxin: Ethylene Oxide (CAS 75-21-8)
California Proposition 65 - Male Reproductive Toxin: Ethylene Oxide (CAS 75-21-8).
SECTION 16. OTHER INFORMATION
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
January 23, 2015
Revision Indicators
The following MSDS content was changed on January 08, 2015:
Section 11 - Toxicological Information; LC50/LD50 values.
The following MSDS content was changed on January 08, 2015:
Section 11 - Toxicological Information; LC50/LD50 values.
The following SDS content was changed on January 08, 2015:
SECTION 12. ECOLOGICAL INFORMATION; Acute Aquatic Toxicity.
SDS No.:
Date of Preparation:
0280 Page
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0707
January 23, 2015
Product Identifier: Big D Carpet Freshener
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