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Big D Deodorant Powder Lemon
Product Identifier Big D Deodorant Powder Lemon
Other Means of
Identification
015200 & C0415203
Big D Industries, Inc., 5620 SW 29th St, Oklahoma City, OK, 73179, 405 682 2541,
BigDInd.com
Recommended Use
SDS No.
Product Family Dry Deodorants
Emergency Phone No.
SECTION 1. IDENTIFICATION
Manufacturer
Dry Deodorants.
0324
Big D Industries, 800 535 5053, 24hr (Infotrac)
Restrictions on Use None known.
GHS Label Elements
SECTION 2. HAZARDS IDENTIFICATION
Signal Word:
Warning
Hazard Statement(s):
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H320 Causes eye irritation.
Precautionary Statement(s):
Prevention:
P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
P264 Wash hands and skin thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
GHS Classification
Skin corrosion/irritation - Category 2; Serious eye damage/eye irritation - Category 2B; Skin sensitization - Category 1B
SDS No.:
Date of Preparation:
0324 Page
of
0601
February 23, 2015
Product Identifier: Big D Deodorant Powder Lemon
Safety Data Sheet
Page 2
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
Storage:
P401 Store in accordance with local, regional, national and international regulations.
Disposal:
P501 Dispose of contents/container in accordance with local, regional, national and international regulations.
Other Hazards
0.538% of the mixture consists of component(s) of unknown acute oral toxicity. 0.32% of the mixture consists of
component(s) of unknown acute hazards to the aquatic environment. 0.187% Of the mixture consists of component(s)
of unknown long term hazards to the aquatic environment.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Sodium sulfate 7757-82-6 99.2
Precipitated silica 112926-00-8 0.281
Terpenes and Terpenoids, sweet orange-oil 68647-72-3 0.186
Other components below reportable Levels No CAS 0.205
Hydrocarbons, terpene processing by-products 68956-56-9 0.128
Inhalation
Move to fresh air.
Skin Contact
Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes.
Eye Contact
Rinse the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding the eyelid(s) open.
Ingestion
Rinse mouth with water. Call a Poison Centre or doctor if you feel unwell or are concerned.
Special Instructions
Not applicable.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
None known.
Most Important Symptoms and Effects, Acute and Delayed
If in eyes:
Causes mild irritation.
Extinguishing Media
Suitable Extinguishing Media
SECTION 5. FIRE-FIGHTING MEASURES
SDS No.:
Date of Preparation:
0324 Page
of
0602
February 23, 2015
Product Identifier: Big D Deodorant Powder Lemon
Page 3
Suitable Extinguishing Media
Not combustible. Use extinguishing agent suitable for surrounding fire.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
Does not burn.
Corrosive sulfur oxides.
Special Protective Equipment and Precautions for Fire-fighters
No special precautions are necessary.
Chemical protective clothing (e.g. chemical splash suit) and positive pressure SCBA may be necessary.
Personal Precautions, Protective Equipment, and Emergency Procedures
Use the personal protective equipment recommended in Section 8 of this safety data sheet.
Environmental Precautions
It is good practice to prevent releases into the environment.
Methods and Materials for Containment and Cleaning Up
No special clean-up methods are necessary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Precautions for Safe Handling
Only use where there is adequate ventilation.
Conditions for Safe Storage
Store in an area that is: dry, separate from incompatible materials (see Section 10: Stability and Reactivity).
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Precipitated silica 3 mg/m3 5 mg/m3
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Not usually required when working with small quantities.
Not required.
Not required but it is good practice to wear safety glasses or chemical safety goggles.
The hazard potential of this product is relatively low. General ventilation is usually adequate.
pH Not available
Appearance White crystalline. Particle Size: Not available
Odour Fragrant
Odour Threshold Not available
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
SDS No.:
Date of Preparation:
0324 Page
of
0603
February 23, 2015
Product Identifier: Big D Deodorant Powder Lemon
Page 4
Partition Coefficient,
n-Octanol/Water (Log Kow)
Not available
Vapour Pressure Not available
Vapour Density (air = 1) Not available
Initial Boiling Point/Range Not available
Evaporation Rate Not available
Flash Point > 93 ºC (200 ºF)
Melting Point/Freezing Point Not available (melting); Not applicable (freezing)
Relative Density (water = 1) Not applicable
Upper/Lower Flammability or
Explosive Limit
Not available (upper); Not available (lower)
Solubility Soluble in water; Not available (in other liquids)
Auto-ignition Temperature Not available
Molecular Formula Not available
Molecular Weight Not available
Not availableDecomposition Temperature
Bulk Density Not available
Viscosity Not available (kinematic); Not available (dynamic)
Surface Tension Not applicable
Vapour Pressure at 50 deg C Not available
Saturated Vapour Concentration Not available
Critical Temperature Not available
Electrical Conductivity Not available
SolidPhysical State
Other Information
Flammability (solid, gas) Not available
Chemical Stability
Normally stable.
Conditions to Avoid
None known.
Incompatible Materials
None known.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Eye contact; skin contact.
Likely Routes of Exposure
SDS No.:
Date of Preparation:
0324 Page
of
0604
February 23, 2015
Product Identifier: Big D Deodorant Powder Lemon
Page 5
Skin Corrosion/Irritation
Not a skin irritant.
Serious Eye Damage/Irritation
There is limited evidence of very mild irritation.
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
No information was located.
Skin Absorption
No information was located.
Ingestion
No information was located.
No information was located.
Not harmful.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
Not known to be a respiratory sensitizer.
Carcinogenicity
Not known to cause cancer.
Development of Offspring
No information was located.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
Not known to be a mutagen.
Interactive Effects
No information was located.
Acute Toxicity
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
Not known to be an aspiration hazard.
Aspiration Hazard
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Precipitated silica > 10000 mg/kg (rat) > 5000 mg/kg (rabbit)
Sodium sulfate 5989 mg/kg (mouse)
Not harmful to aquatic life.
This product and its degradation products are not expected to bioaccumulate.
If released into the environment, this product can move rapidly through the soil.
SECTION 12. ECOLOGICAL INFORMATION
No information was located.
Toxicity
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
SDS No.:
Date of Preparation:
0324 Page
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0605
February 23, 2015
Product Identifier: Big D Deodorant Powder Lemon
Page 6
There is no information available.
Other Adverse Effects
SECTION 13. DISPOSAL CONSIDERATIONS
The required hazard evaluation of the waste and compliance with the applicable hazardous waste laws are the
responsibility of the user.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions
for User
Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15. REGULATORY INFORMATION
Canada
WHMIS Classification
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL or are not required to be listed.
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.
Additional USA Regulatory Lists
Massachusetts Right To Know: (2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) 0.0032% wt/wt
New Jersey Right To Know: (2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) 0.0032% wt/wt
Pennsylvania Right To Know: (2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) 0.0032% wt/wt.
Not a WHMIS controlled product.
Safety, Health and Environmental Regulations
Key to Abbreviations
ACGIH® = American Conference of Governmental Industrial Hygienists
OSHA = US Occupational Safety and Health Administration
SECTION 16. OTHER INFORMATION
NFPA Rating
SDS Prepared By
Wayne Hegstrom
Phone No.
405 682 2541
Date of Preparation
February 23, 2015
Revision Indicators
Not applicable.
Health - 1 Flammability - 0 Instability - 0
Based on
Precipitated silica
SDS No.:
Date of Preparation:
0324 Page
of
0606
February 23, 2015
Product Identifier: Big D Deodorant Powder Lemon
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