Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 1
Safety Data Sheet
According to regulation (EG) No. 1907/2006, attachment II
This safety data sheet should be retained and accessible to users of the battery modules.
06.07.2020
1: Designation of the products and the company
Product description: Rechargeable, intelligent battery modules with cell assemblies of highperformance phospate-based lithium-ion cells.
Information about the manufacturer:
Bicker Elektronik GmbH
Ludwig-Auer-Strasse 23
86609 Donauwörth
Germany
Website: www.bicker.de
Phone:+49 906 70595-0
Contact person:
Thomas Böhmer
Email: thomas.boehmer@bicker.de
Phone:+49 906 70595-54
Emergency number:
Counseling center Giftnotruf München (poison emergency call munich): +49 89 19240
(24/7 emergency phone number)
2: Possible dangers
Classification of the substance or mixture:
Classification according to Regulation (EG) No. 1272/2008 (CLP):
Not classified as dangerous, if the product is used in accordance with the manufacturer's
instructions.
Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 2
NFPA classification (USA)
EG classification
HMIS
Is not subject to the labelling
requirements for hazardous
substances
Health hazard: 0
Fire hazard: 1
Reactivity hazard: 0
Hazards Identification
Classification of the substance or mixture:
Preparation Hazards and Classification: The product is a Lithium ion cell or battery and is
therefore classified as an article and is not hazardous when used according to the
recommendations of the manufacturer. The hazard is associated with the contents of the cell
or battery. Under recommended use conditions, the electrode materials and liquid
electrolyte are non-reactive provided that the cell or battery integrity remains and the seals
remain intact. The potential for exposure should not exist unless the cell or battery leaks, is
exposed to high temperatures or is mechanically, electrically or physically abused/damaged.
If the cell or battery is compromised and starts to leak, based upon the battery ingredients,
the contents are classified as Hazardous.
Hazard Summary
Physical hazards: Not classified for physical hazards.
Health hazards: Not classified for health hazards.
Environmental hazards: Not classified for hazards to the environment.
Specific hazards: Exposure to contents of an open or damaged cell or battery: contact with
this material will cause burns to the skin, eyes and mucous membranes. May cause
sensitization by skin contact.
Main Symptoms: Symptoms include itching, burning, redness and tearing.
Hazardous Materials Information Label (HMIS)
Health: 0
Flammability: 1
Physical Hazard: 0
NFPA Hazard Ratings
Health: 0
Flammability: 1
Reactivity: 0
Unique Hazard:
Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 3
GHS precautionary statements
Precautionary
Statement(s)
Prevention
P102: Keep out of reach of children.
P103: Read label prior to use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P234: Keep only in original container.
P254: Wash hands thoroughly after handling.
Response
(If cell/battery
leaks)
P260: Do not breathe vapor or spray.
P280: Wear protective gloves/protective clothing/eye protection/face
protection.
P301/330/331: IF SWALLOWED: Rinse mouth. DO NOT induce vomiting.
P303/361/353: IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P304/340: If INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305/351/338: IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P363: Wash contaminated clothing before reuse.
P370: In case of fire: Use carbon dioxide, dry chemical or water extinguisher.
Storage
(Store as indicated
in Section 7)
P402: Store in a dry place.
P405: Store locked up.
P410: Protect from sunlight.
Disposal
P406: Store any spilled/leaking electrolyte material in a corrosive resistant
container with a resistant inner liner.
P501: Dispose of batteries in accordance with applicable hazardous waste
regulations.
Protective clothing is not required under normal use.
Possible health hazards:
Mechanical damage to the batteries or improper use can cause violent reactions that endanger
human health and the environment.
In particular, high risk potential exists when a battery module is exposed to temperatures in excess of
+150°C (e.g., in contact with fire). Is this case, there may be a critical ignition of the battery cells
(thermal runaway) – severe fires and bursting oft he battery module are possible in a row.
Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 4
If cell damage occurs, the electrolyte solution in the cell is corrosive and can cause a burn of skin and
eye:
Vapors or mists escaping from a damaged cell can cause respiratory irritation.
Ingestion of the contents of an open cell can cause severe chemical burns to the mouth,
esophagus and gastrointestinal tract.
Skin contact with the contents of an open cell can cause severe skin irritation or skin burns.
Eye contact with the contents of an open cell can cause serious eye irritation or eye burns.
Direct contact with leaked electrolyte may have a long-term carcinogenic effect.
Warning!
Never use chargers that are not intended for lithium-iron phosphate chemistry.
Do not short circuit. Do not mechanically damage (puncture, deform, disassemble, etc.). Do not heat
or burn beyond the allowable temperature. Keep battery modules away from children and animals.
Store batteries dry and ideally at room temperature (see also section 7).
The lithium battery modules are safe to use when handled properly under the parameters specified
in the operating instructions. Improper treatment or conditions that result in improper operation
may result in leaking and leakage of battery ingredients and decomposition products, and associated
with severe health and environmental hazard reactions.
Basically, the contact with leaked battery components can pose a risk to health and the environment.
It is therefore necessary to provide adequate body and respiratory protection when in contact with
conspicuous batteries (leakage of contents, deformation, discoloration, dentures, etc.) (see section 8:
Personal protective equipment). Battery packs may e.g. react very violently in combination with fire.
In this case, battery components can be emitted with high risk potential.
Handling and operational safety:
The lithium battery modules should always be handled in accordance with the operating instructions.
This applies in particular to compliance with the limits for maximum current load, charge and
discharge firing voltages as well as mechanical and thermal loads..
The lithium battery modules may under no circumstances be modified or manipulated as this can
lead to considerable safety risks. Charging methods tailored to lithium iron phosphate are to be used.
Danger!
As with other batteries, lithium batteries are considered to continue to pose a potential hazard in the
supposedly discharged state, as they can supply a very high short-circuit current..
Too deep discharge leads to lasting damage. Deeply discharged battery modules may no longer be
charged or operated. Deep discharge can occur, for example, during very long storage of a previously
discharged to the discharge limit battery module.
Excessive charging voltages and overcharging should be avoided under all circumstances. They can
lead directly to critical situations, but also have a negative impact on battery life.
Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 5
3: Composition, information on ingredients
Chemical composition of the high-performance phosphate-based lithium-ion cells installed in the
battery modules:
Cell component
Chemical name
CAS No.
Mass range in cell
(g/g %)
Elektrolyte
Contains Electrolyte salt and
solvents.
5-20
Elektrolyte salt
Lithium hexafluorophosphate
21324-40-3
0.05-5
Elektrolyte solvent
Includes one or more of the
following:
Ethylene Carbonate
Propylene Carbonate
Diethyl Carbonate
96-49-1
108-32-7
105-58-8
5-20
PVDF
Polyvinylidenfluoride
24937-79-9
<1
Copper
Cu
7440-50-8
3-15
Aluminium
Al
7429-90-5
2-10
Cathode
Lithium cobalt oxide
12190-79-3
20-50
Anode
Graphite
7782-42-5
10-30
Steel, Nickel and
inert components
Various
Balance
Note: Lithium batteries are products that do not release any substance when used properly.
4: First aid measures
Lithium battery modules are not hazardous if handled and stored properly..
If cell damage occurs, the electrolyte solution in the cell is corrosive and can cause skin and eye
burns. Following are the first-aid measures recommended by the cell manufacturer when in contact
with the electrolyte solution that has leaked out of the batteries:
Inhalation:
Vapors or mists escaping from a damaged cell can cause respiratory irritation. When inhaling the
contents of an open cell, remove the source of contamination or remove the affected person to fresh
air. Seek medical help.
Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 6
Eye contact:
Contact with the contents of an opened cell can cause severe burns or eye irritation. If eye contact
occurs with the contents of an opened cell, immediately rinse the contaminated eye (s) with a
lukewarm, slightly flowing stream of water for at least 30 minutes. Keep eyelids open. Neutral saline
may be used as soon as available. If necessary, further rinse the eyes during transport to the
emergency supply station. Take care that contaminated water is not flushed to the naked eye or
face. Immediately transfer the affected person to an emergency care center.
Skin contact:
Contact with the contents of an opened cell can cause burns. If skin contact occurs with the contents
of an open cell, remove contaminated clothing, shoes and leather parts. Rinse immediately with
lukewarm, low-flow water for at least 30 minutes. Seek medical attention if irritation symptoms or
pain persist. Thoroughly wash or dispose of clothing, shoes and leather goods before reuse.
Swallow:
Contact with the contents of an opened cell can cause severe chemical burns to the mouth,
esophagus and gastrointestinal tract. If you swallow the contents of an open cell, DO NOT deliver
anything by mouth if the subject becomes unconscious, unconscious, or has seizures. Rinse mouth
thoroughly with water. DO NOT INDUCE VOMITING. In case of spontaneous vomiting, place the
affected person in a forward bent position to reduce the risk of suffocation. Rinse mouth again with
water. Immediately transfer the affected person to an emergency care center.
Burns:
If burns are caused, they should be treated accordingly. It is strongly advised to contact a doctor.
5: Fire-fighting measures
Fires of lithium batteries can basically be combated with water.
There are no additional or special extinguishing agents available. Ambient fires of the batteries are to
be combated with conventional extinguishing agents. The fire of a battery can’t be considered
separately from the surrounding fire.
The cooling effect of water effectively inhibits the spread of fire to battery cells that have not yet
reached the critical temperature for thermal runaway.
The battery module may release toxic fumes when burned or exposed to fire. Damage to the jacket
can release dangerous fumes that contain extremely hazardous HF (hydrofluoric acid). The fumes can
cause serious health damage by inhalation. For adequate ventilation care must therefore be taken.
Extinguishing media recommended by the manufacturer of the batteries used:
Small fires: dry chemicals, CO2, water spray or commercial foam.
Large fires: splashing water, fogging or commercial foam. Container from the
Remove fire area if this is possible without danger.
Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 7
Specific dangers of the used battery cells arising from the chemical:
Water in reaction with released lithium (Li PF6) can lead to the formation of hydrogen or hydrogen
fluoride gas (HF). Contact with battery electrolyte can irritate skin, eyes and mucous membranes. A
fire causes irritating, corrosive and / or toxic gases. Inhaled vapors can cause dizziness or suffocation.
Recommended precautions for the fire department and special protective equipment
recommended by the manufacturer of the batteries used:
Wear a self-contained breathing apparatus.
The protective clothing of the firefighting personnel offers only limited protection. Fight the fire from
a safe distance.
6: Accidental release measures
With damage to the battery casing of a cell electrolyte may leak.
Recommended personal protection measures by the manufacturer of the batteries used:
As an immediate precaution, insulate the spill area or leakage area for at least 25 m in all directions.
Keep away from unauthorized persons. Stop the wind. Avoid low lying areas. Ventilate closed areas
before entering.
Direct contact with escaped electrolyte is to be avoided in any case. Just use the situation adapted
personal protective equipment. When handling an open or leaking cell, the manufacturer of the
batteries recommends wearing the following protective equipment: neoprene or natural rubber
gloves, goggles and respiratory protection.
Environmental precautions:
Avoid soil contamination and penetration of material into drains and waterways.
Containment:
Stop the loss of substances, if this is without risk. Contain spilled liquid with dry sand or earth. Clean
the affected area immediately.
Recommended cleaning methods by the manufacturer of the batteries used:
Absorb spilled material with an inert, absorbent sorbent (dry sand or earth). Shovel contaminated
sorbent into a suitable waste container. Collect all contaminated sorbent and dispose of properly.
Scrub the affected area with detergent and water; Collect contaminated wash water and dispose of
properly.
Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 8
7: Handling and storage
Handling:
The battery modules are to be used in accordance with the operating instructions. Do not open,
disassemble, crush or burn the battery modules. Do not expose to temperatures exceeding + 55 °C.
Storage:
Store the battery modules in a dry place, ideally at room temperature (25 ° C +/- 5 ° C). Increased
temperatures can shorten the life of the battery modules. Keep out of reach of children and animals
(e.g. rats or mice). High temperature fluctuations in the storage area should be avoided, for example
storage next to heaters. Battery modules do not permanently expose to solar radiation. Protect from
moisture and water.
8: Exposure controls / personal protection
Lithium battery modules are products from which no hazardous substances are released under
normal and wise conditions of use.
Recommended technical precautions:
Use local exhaust ventilation or other technical measures to control dust, mist, smoke and vapor
sources.
Personal security:
In the immediate work area an eyewash and ideally a safety shower should be available.
Under normal conditions, no protective clothing is required. When handling an open or leaking cell is
recommended by the manufacturer of the batteries used to carry the following protective
equipment: gloves made from neoprene or natural rubber, safety glasses and respirators.
Hygiene measures:
Do not eat, drink or smoke in work areas. Ensure order and cleanliness.
9: Physical and chemical properties
Physical and chemical properties of the batteries used according to the manufacturer's
instructions:
Physical condition:
Solid
Water solution:
insoluble
Appearance:
Cell
Odor:
odorless
Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 9
10: Stability and reactivity
Contact of the battery module with fire or very high temperatures above + 80 ° C is a risk of bursting
of the battery module. Do not disassemble, crush, short circuit or connect with twisted polarity.
Avoid mechanical and electrical abuse. Do not immerse in salt water or other high conductivity
liquids.
The battery module may release toxic fumes when burned or exposed to fire. Damage to the jacket
can release dangerous fumes that contain extremely hazardous HF (hydrofluoric acid).
11: Toxicological information
There is no danger when used as intended. Mechanical, thermal or electrical abuse can cause severe
irritation and burns to the skin, eyes and respiratory tract..
When used the battery module as intended, the user is not exposed to any substances, listed as
being carcinogenic to humans by the IARC (International Cancer Research Center), the American
Conference of Governmental Industrial Hygienists (ACGIH), OSHA or the National Toxicology Program
(NTP).
Direct contact with leaked electrolyte can have a long-term carcinogenic effect.
12: Environmental information
Further information
Ecological injuries are not known or expected under normal use. Do not flush into surface water or
sanitary sewer system.
Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 10
13: Disposal considerations
Used battery modules have to be returned at the point of sale or in a special disposal system
(industry, trade). Return is free.The battery modules must not be disposed of with household waste
and must be collected separately from any further waste. The battery modules must not enter the
sewage system or water bodies and not be buried in the ground. The used battery modules must also
be treated in accordance with section 7 "Handling and storage". They should preferably be given in a
discharged condition and in a plastic bag or in their original packaging for disposal.
When transporting used battery modules, observe the transport instructions in section 12.
14: Notes on transport
The battery modules have been designed to comply with all applicable industrial and regulatory
standards, including the UN Dangerous Goods Transport Regulations, the IATA Dangerous Goods
Regulations, and the US Department of Transportation regulations for the safe transportation of
lithium-ion cells and the International Law of the sea for dangerous goods.
The maximum transport temperature corresponds to the maximum storage temperature of + 55 ° C.
The battery modules have an energy content of less than 100Wh, therefore simplifying special
regulations of dangerous goods law can be applied:
Land transport (ADR/RID)
14.1. UN-Number: UN 3480 / UN 3481
14.2. UN proper shipping name: Lithium ion batteries
14.3. Transport hazard class: 9
Classification code: M4
Special provisions: 188 230 310 348 636 656
Packaging provisions: P903 P903a P903b
Transport category: 2
Tunnel restriction code: E
Packing instructions: P903 / P903a / P903B
Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 11
Sea transport (IMDG / AND)
14.1. UN-Number: UN 3480 / UN 3481
14.2. UN proper shipping name: Lithium ion batteries
14.3. Transport hazard class: 9
Classification code: M4
Special provisions: 188 230 310 957
Packaging provisions: P903
EMS: F-A, S-I
Packing instructions: P903
Packing instructions (for Inland waterway): P903 / P903a / P903b
Air transport (IATA)
14.1. UN-Number: UN 3480 / UN 3481
14.2. UN-proper shipping name: Lithium ion batteries
14.3. Transport hazard class: 9
Net Weight per package: Cargo 35kg
Special provision: A88, A99, A154, A164, A183, A 201, A206, A331, A802
IATA-Packaging provision - Cargo: 965
Packing instructions: P965 / P966 / P967
CAO-Cargo Aircraft Only!
The energy content of the battery pack in Wh is stated on the rating plate of the respective battery
module.
Lithium battery modules are subject to the following dangerous goods regulations: Class 9
UN 3480: LITHIUM ION BATTERIES
UN 3481: LITHIUM ION BATTERIES IN EQUIPMENTS or LITHIUM ION BATTERIES, PACKED WITH
EQUIPMENT
Packaging group: II
Transport of damaged or defective battery modules
Defective or damaged battery modules are moreover subject to the stricter transport special
regulation 376. These reach all the way to packaging in an aluminum box with vermiculite filling or a
complete transport ban.
Air transport of waste batteries
Waste batteries and batteries transported for purposes of recycling or disposal are excluded from air
freight unless authorized by the competent national authorities of the country of origin and the
country of the executing company. (IATA DGR SV A183)
Batteries for disposal and recycling (road/rail/sea)
Lithium batteries may be transported for disposal and recycling in accordance with ADR SV 230 and
SV 188, as applicable, or, if they have a gross mass of 500 g or less, according to ADR SV 636 b.
Safety Data Sheet
Bicker Elektronik GmbH
BP-LIO-1525, UPSI-2406DP1
_____________________________________________________________________________________________________
S. 12
Transport of used battery modules
When transporting used, intact and undamaged battery modules, the regulations for new batteries
can usually be applied. However, for the transport of used - but not damaged - batteries, please also
refer to the corresponding special regulations (636) or packing instructions (P903a and P903b / ADR).
15: Legislation
The battery modules are subject to the scope of the respective national implementation of the
European Battery Directive 2006/66 / EC. This contains regulations, inter alia for the placing on the
market, the collection, the treatment and the recycling of batteries.
The battery modules are provided with the "Separate collection symbol" (crossed-out wheeled bin)
and the battery system identification with Li-Ion.
16: Other informations
The instructions help to comply with legal requirements but do not replace them.
The above information has been complied to the best of our knowledge and belief. They do not
constitute an assurance of properties. Applicable laws and regulations have to be observed by the
distributors and users of the product on their own responsibility.
Bicker Elektronik GmbH excludes any liability!
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