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SAFETY DATA SHEET
Revision Date 25-Jun-2015 Revision Number 2Issuing Date 11-May-2015
_____________________________________________________________________________________________
The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
_____________________________________________________________________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name Bic Mark-It Permanent Markers
Other means of identification
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Supplier Name
Supplier Address
Supplier Phone Number
Supplier Email
Emergency telephone number
Company Emergency Phone
Number
None
Writing Instrument
No information available
Bic USA Inc
One BIC Way
Suite 1
Shelton
Ct
06484
US
Phone:202 484 7616
Contact Phone913 327 1242
jay.wimsett@bicworld.com
202 484 7616
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Acute toxicity - Oral Category 4
Skin corrosion/irritation Category 1 Sub-category B
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Serious eye damage/eye irritation Category 1
Specific target organ toxicity (single exposure) Category 3
Specific target organ toxicity (repeated exposure) Category 2
GHS Label elements, including precautionary statements
Emergency Overview
Signal word Danger
Hazard Statements
Harmful if swallowed
Causes severe skin burns and eye damage
May cause respiratory irritation. May cause drowsiness or dizziness
May cause damage to organs through prolonged or repeated exposure
.
Odor AlcoholAppearance Varies Physical state Semi-Solid Solid
containing liquid
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Do not breathe dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Precautionary Statements - Response
Immediately call a POISON CENTER or doctor/physician
Specific treatment (see supplemental first aid instructions on this label)
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor/physician
Skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Immediately call a POISON CENTER or doctor/physician
Call a POISON CENTER or doctor/physician if you feel unwell
Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Do NOT induce vomiting
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Precautionary Statements - Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
20% of the mixture consists of ingredient(s) of unknown toxicity
Other information
Toxic to aquatic life
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION
Interactions with Other Chemicals
Use of alcoholic beverages may enhance toxic effects.
3. COMPOSITION/INFORMATION ON INGREDIENTS
.
Chemical Name CAS No Weight-% Trade Secret
Propylene glycol monomethyl ether 107-98-2 40 - 70 *
Ethyl alcohol 64-17-5 40 - 70 *
Ethylene glycol 107-21-1 10 - 30 *
n-Propyl alcohol 71-23-8 7 - 13 *
Diacetone alcohol 123-42-2 7 - 13 *
2-Butoxyethanol
Phosphoric acid, 2-ethylhexyl ester 12645-31-7 3 - 7 *
Isopropyl alcohol 67-63-0 1 - 5 *
Sorbitan monooctadecanoate 1338-41-6 1 - 5 *
Polyvinyl butyral resin 63148-65-2 1 - 5 *
*The exact percentage (concentration) of composition has been withheld as a trade secret
111-76-2 5 - 10 *
4. FIRST AID MEASURES
First aid measures
General Advice
Eye contact
Immediate medical attention is required. Show this safety data sheet to the doctor
in attendance.
Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove
contact lenses, if present and easy to do. Continue rinsing. Seek immediate
medical attention/advice.
Skin contact
Wash off immediately with soap and plenty of water while removing all
contaminated clothes and shoes. Seek immediate medical attention/advice.
Inhalation
Remove to fresh air. If breathing has stopped, give artificial respiration. Get
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medical attention immediately. Do not use mouth-to-mouth method if victim
ingested or inhaled the substance; give artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory medical device. If
breathing is difficult, (trained personnel should) give oxygen. Delayed pulmonary
edema may occur. Get medical attention immediately if symptoms occur.
Ingestion
Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water.
Never give anything by mouth to an unconscious person. Call a physician or
poison control center immediately.
Self-protection of the first aider
Ensure that medical personnel are aware of the material(s) involved, take
precautions to protect themselves and prevent spread of contamination. Avoid
contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier to
give mouth-to-mouth resuscitation. Use personal protective equipment as
required. Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Burning sensation.
Effects
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Product is a corrosive material. Use of gastric lavage or emesis is
contraindicated. Possible perforation of stomach or esophagus should be
investigated. Do not give chemical antidotes. Asphyxia from glottal edema may
occur. Marked decrease in blood pressure may occur with moist rales, frothy
sputum, and high pulse pressure.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the chemical
The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating gases
and vapors.
Uniform Fire Code
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
Irritant: Solid
No.
No.
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6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate
ventilation. Use personal protective equipment as required. Evacuate personnel to safe
areas. Keep people away from and upwind of spill/leak.
Other Information
Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental precautions
Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so. Should not be released into the environment. Do not allow to enter into
soil/subsoil. Prevent product from entering drains.
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Prevent further leakage or spillage if safe to do so.
Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory
equipment. Use only with adequate ventilation and in closed systems. Do not eat, drink or
smoke when using this product. Take off contaminated clothing and wash before reuse.
Conditions for safe storage, including any incompatibilities
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from
moisture. Store locked up. Keep out of the reach of children. Store away from other
materials.
Incompatible Products
Acids. Bases. Oxidizing agent. Chlorinated compounds.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Propylene glycol monomethyl ether
107-98-2
Ethyl alcohol
64-17-5
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STEL: 100 ppm
TWA: 50 ppm
STEL: 1000 ppm TWA: 1000 ppm
(vacated) TWA: 100 ppm
(vacated) TWA: 360 mg/m
(vacated) STEL: 150 ppm
(vacated) STEL: 540 mg/m
TWA: 1900 mg/m
(vacated) TWA: 1000 ppm
3
3
3
TWA: 100 ppm
TWA: 360 mg/m
STEL: 150 ppm
STEL: 540 mg/m
IDLH: 3300 ppm 10% LEL
TWA: 1000 ppm
TWA: 1900 mg/m
3
3
3
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3
3
3
3
3
3
3
3
3
IDLH: 800 ppm
TWA: 200 ppm
TWA: 500 mg/m
STEL: 250 ppm
STEL: 625 mg/m
IDLH: 1800 ppm
TWA: 50 ppm
TWA: 240 mg/m
IDLH: 700 ppm
TWA: 5 ppm
TWA: 24 mg/m
3
3
3
3
Ethylene glycol
107-21-1
n-Propyl alcohol
71-23-8
Diacetone alcohol
123-42-2
2-Butoxyethanol
111-76-2
(vacated) TWA: 1900 mg/m
Ceiling: 100 mg/m3 aerosol only (vacated) Ceiling: 50 ppm
(vacated) Ceiling: 125 mg/m
TWA: 100 ppm TWA: 200 ppm
TWA: 500 mg/m
(vacated) TWA: 200 ppm
(vacated) TWA: 500 mg/m
(vacated) STEL: 250 ppm
(vacated) STEL: 625 mg/m
TWA: 50 ppm TWA: 50 ppm
TWA: 240 mg/m
(vacated) TWA: 50 ppm
(vacated) TWA: 240 mg/m
TWA: 20 ppm TWA: 50 ppm
TWA: 240 mg/m
(vacated) TWA: 25 ppm
(vacated) TWA: 120 mg/m
(vacated) S*
Isopropyl alcohol
67-63-0
Sorbitan monooctadecanoate
1338-41-6
STEL: 400 ppm
TWA: 200 ppm
TWA: 10 mg/m3 except
stearates of toxic metals
TWA: 400 ppm
TWA: 980 mg/m
3
(vacated) TWA: 400 ppm
(vacated) TWA: 980 mg/m
(vacated) STEL: 500 ppm
(vacated) STEL: 1225 mg/m
-
IDLH: 2000 ppm 10% LEL
TWA: 980 mg/m
3
3
TWA: 400 ppm
STEL: 500 ppm
STEL: 1225 mg/m
3
3
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits Immediately Dangerous to Life or Health
Other Exposure Guidelines
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992) See section 15 for national exposure control parameters
Appropriate engineering controls
Engineering Measures
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
None required for consumer use. If there is a risk of contact:. Face protection shield.
None required for consumer use. If there is a risk of contact:. Wear protective gloves and
protective clothing.
Respiratory protection
No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
smoke when using this product. Take off contaminated clothing and wash before reuse.
Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection.
Contaminated work clothing should not be allowed out of the workplace. Regular cleaning
of equipment, work area and clothing is recommended. Wash hands before breaks and
immediately after handling the product. For environmental protection, remove and wash all
contaminated protective equipment before re-use.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical state
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Semi-Solid, Solid containing liquid
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Appearance
Color
Property
pH
Melting / freezing point
Boiling point / boiling range
Flash Point
Evaporation Rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit
Lower flammability limit
Vapor pressure
Vapor density
Specific Gravity
Water Solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Other Information
Varies
No information available
Values
UNKNOWN
No data available
No data available
22 C / 72 F
No data available
No data available
No data available
No data available
No data available
No data available
0.840
Soluble in water
No data available
No data available
No data available
No data available
No data available
No data available None known
No data available
No data available
Odor
Odor Threshold
Remarks Method
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
Alcohol
No information available
Softening Point
VOC Content (%)
Particle Size
Particle Size Distribution
No data available
No data available
No data available
10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Exposure to air or moisture over prolonged periods.
Incompatible materials
Acids. Bases. Oxidizing agent. Chlorinated compounds.
Hazardous Decomposition Products
Carbon oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
.
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Inhalation
Specific test data for the substance or mixture is not available. Corrosive by inhalation.
(based on components). Inhalation of corrosive fumes/gases may cause coughing, choking,
headache, dizziness, and weakness for several hours. Pulmonary edema may occur with
tightness in the chest, shortness of breath, bluish skin, decreased blood pressure, and
increased heart rate. Inhaled corrosive substances can lead to a toxic edema of the lungs.
Pulmonary edema can be fatal. May cause irritation of respiratory tract.
Eye contact
Specific test data for the substance or mixture is not available. Causes burns. (based on
components). Corrosive to the eyes and may cause severe damage including blindness.
Causes serious eye damage. May cause irreversible damage to eyes.
Skin contact
Specific test data for the substance or mixture is not available. Corrosive. (based on
components). Causes burns.
Ingestion
Specific test data for the substance or mixture is not available. Causes burns. (based on
components). Ingestion causes burns of the upper digestive and respiratory tracts. May
cause severe burning pain in the mouth and stomach with vomiting and diarrhea of dark
blood. Blood pressure may decrease. Brownish or yellowish stains may be seen around the
mouth. Swelling of the throat may cause shortness of breath and choking. May cause lung
damage if swallowed. May be fatal if swallowed and enters airways. Ingestion may cause
irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhea. May be harmful if swallowed.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Propylene glycol monomethyl ether
107-98-2
Ethyl alcohol
64-17-5
Ethylene glycol
107-21-1
n-Propyl alcohol
71-23-8
Diacetone alcohol
123-42-2
2-Butoxyethanol
111-76-2
Isopropyl alcohol
67-63-0
= 5200 mg/kg ( Rat ) = 13 g/kg ( Rabbit ) = 54.6 mg/L ( Rat ) 4 h
> 24 mg/L ( Rat ) 1 h
- - = 124.7 mg/L ( Rat ) 4 h
= 4000 mg/kg ( Rat ) - -
= 1870 mg/kg ( Rat ) - > 13548 ppm ( Rat ) 4 h
= 4 g/kg ( Rat ) - -
= 470 mg/kg ( Rat ) = 220 mg/kg ( Rabbit ) = 450 ppm ( Rat ) 4 h
= 4396 mg/kg ( Rat ) = 12800 mg/kg ( Rabbit ) = 16000 ppm ( Rat ) 8 h
Information on toxicological effects
Symptoms
Erythema (skin redness). Burning. May cause blindness. Coughing and/ or wheezing.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Mutagenic Effects
Carcinogenicity
No information available.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Ethanol has been shown to be carcinogenic in long-term studies only when consumed as
alcoholic beverage.
Chemical Name ACGIH IARC NTP OSHA
Ethyl alcohol
64-17-5
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A3 Group 1 Known X
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2-Butoxyethanol
111-76-2
Isopropyl alcohol
67-63-0
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
Group 3 - Not Classifiable as to Carcinogenicity in Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
A3 Group 3
Group 3 X
No information available.
No information available.
Causes damage to organs through prolonged or repeated exposure. Based on
classification criteria from the 2012 OSHA Hazard Communication Standard (29 CFR
1910.1200), this product has been determined to cause systemic target organ toxicity from
chronic or repeated exposure. (STOT RE).
Chronic Toxicity
No known effect based on information supplied. Chronic exposure to corrosive fumes/gases
may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic
cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may
also be seen. Contains a known or suspected carcinogen. Avoid repeated exposure.
Prolonged exposure may cause chronic effects. May cause adverse effects on the bone
marrow and blood-forming system. May cause adverse liver effects. Contains a known or
suspected reproductive toxin. Ethanol has been shown to be a reproductive toxin only when
consumed as an alcoholic beverage. Ethanol has been shown to be carcinogenic in
long-term studies only when consumed as alcoholic beverage.
Target Organ Effects
Respiratory system. Eyes. Skin. Gastrointestinal tract (GI). Blood. Central Nervous System
(CNS). Hematopoietic system. Kidney. Liver. Reproductive System. Heart. Spleen.
Systemic Toxicity.
Aspiration Hazard
No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
1,312.00 mg/kg
ATEmix (dermal)
7,134.00 mg/kg (ATE)
ATEmix (inhalation-gas)
51,429.00 ppm (4 hr)
ATEmix (inhalation-dust/mist)
12.81 mg/l
ATEmix (inhalation-vapor)
116.00 ATEmix
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12. ECOLOGICAL INFORMATION
Ecotoxicity
Toxic to aquatic organisms.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to
Propylene glycol
monomethyl ether
107-98-2
Ethyl alcohol
64-17-5
Ethylene glycol
107-21-1
n-Propyl alcohol
71-23-8
Diacetone alcohol
123-42-2
2-Butoxyethanol
111-76-2
Isopropyl alcohol
67-63-0
96h EC50: 6500 - 13000
mg/L (Pseudokirchneriella
subcapitata)
96h EC50: > 1000 mg/L
(Desmodesmus
subspicatus) 72h EC50: >
1000 mg/L (Desmodesmus
subspicatus)
96h LC50: = 20.8 g/L
(Pimephales promelas) 96h
LC50: 4600 - 10000 mg/L
(Leuciscus idus)
96h LC50: > 100 mg/L
(Pimephales promelas) 96h
LC50: 13400 - 15100 mg/L
(Pimephales promelas) 96h
LC50: 12.0 - 16.0 mL/L
(Oncorhynchus mykiss)
96h LC50: = 41000 mg/L
(Oncorhynchus mykiss) 96h
LC50: 14 - 18 mL/L
(Oncorhynchus mykiss) 96h
LC50: = 40761 mg/L
(Oncorhynchus mykiss) 96h
LC50: = 27540 mg/L
(Lepomis macrochirus) 96h
LC50: = 16000 mg/L
(Poecilia reticulata) 96h
LC50: 40000 - 60000 mg/L
(Pimephales promelas)
96h LC50: = 4480 mg/L
(Pimephales promelas)
96h LC50: = 420 mg/L
(Lepomis macrochirus)
96h LC50: = 1490 mg/L
(Lepomis macrochirus) 96h
LC50: = 2950 mg/L
(Lepomis macrochirus)
96h LC50: > 1400000 µg/L
(Lepomis macrochirus) 96h
LC50: = 11130 mg/L
(Pimephales promelas) 96h
LC50: = 9640 mg/L
(Pimephales promelas)
Microorganisms
EC50 = 34634 mg/L 30 min
EC50 = 35470 mg/L 5 min
EC50 = 10000 mg/L 16 h
EC50 = 620 mg/L 30 min
EC50 = 620.0 mg/L 30 min
EC50 = 17700 mg/L 5 min
EC50 = 45000 mg/L 5 h
EC50 = 8686 mg/L 15 min
EC50 = 980 mg/L 12 h
Daphnia Magna (Water
Flea)
48h EC50: = 23300 mg/L
48h LC50: 9268 - 14221
mg/L 48h EC50: = 2 mg/L
24h EC50: = 10800 mg/L
48h EC50: = 46300 mg/L
48h EC50: 3339 - 3977
mg/L 48h EC50: = 3642
mg/L
24h EC50: = 8750 mg/L
48h EC50: > 1000 mg/L 24h
EC50: 1698 - 1940 mg/L
48h EC50: = 13299 mg/L
Persistence and Degradability
No information available.
Bioaccumulation
Chemical Name Log Pow
Propylene glycol monomethyl ether
107-98-2
Ethyl alcohol
64-17-5
Ethylene glycol
107-21-1
n-Propyl alcohol
71-23-8
Diacetone alcohol
123-42-2
-0.437
-0.32
-1.93
0.34
1.03
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2-Butoxyethanol
111-76-2
Isopropyl alcohol
67-63-0
0.81
0.05
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal methods
Contaminated Packaging
California Hazardous Waste Codes
This product contains one or more substances that are listed with the State of California as a hazardous waste.
This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.
Dispose of contents/containers in accordance with local regulations.
331
DOT
Proper Shipping Name
Hazard Class
TDG
MEX
ICAO
IATA
Proper Shipping Name
Hazard Class
IMDG/IMO
Hazard Class
Chemical Name California Hazardous Waste
Ethyl alcohol
64-17-5
n-Propyl alcohol
71-23-8
Isopropyl alcohol
67-63-0
Toxic
Ignitable
Toxic
Ignitable
Toxic
Ignitable
14. TRANSPORT INFORMATION
NOT REGULATED
NON REGULATED
N/A
Not regulated
Not regulated
Not regulated
Not regulated
NON REGULATED
N/A
Not regulated
N/A
RID
ADR
Not regulated
Not regulated
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ADN
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name CAS No Weight-% SARA 313 - Threshold
Ethylene glycol - 107-21-1 107-21-1 10 - 30 1.0
2-Butoxyethanol - 111-76-2 111-76-2 5 - 10 1.0
Isopropyl alcohol - 67-63-0 67-63-0 1 - 5 1.0
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden release of pressure hazard
Reactive Hazard
Yes
Yes
No
No
No
Values %
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs Extremely Hazardous Substances
Ethylene glycol
107-21-1
5000 lb RQ 5000 lb final RQ
RQs
RQ 2270 kg final RQ
RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
.
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois
Propylene glycol monomethyl ether
_____________________________________________________________________________________________
107-98-2
Ethyl alcohol
64-17-5
n-Propyl alcohol
71-23-8
2-Butoxyethanol
111-76-2
Diacetone alcohol X X X
X X X
X
X X X
X X X X X
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1012091 - Bic Mark-It Permanent Markers
Revision Date 25-Jun-2015
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123-42-2
Isopropyl alcohol
67-63-0
X X X X
International Regulations
Mexico
National occupational exposure limits
Component Carcinogen Status Exposure Limits
Ethyl alcohol
64-17-5 ( 40 - 70 )
Ethylene glycol
107-21-1 ( 10 - 30 )
n-Propyl alcohol
71-23-8 ( 7 - 13 )
Diacetone alcohol
123-42-2 ( 7 - 13 )
2-Butoxyethanol
111-76-2 ( 5 - 10 )
Isopropyl alcohol
67-63-0 ( 1 - 5 )
Mexico - Occupational Exposure Limits - Carcinogens
Mexico: TWA 1000 ppm
Mexico: TWA 1900 mg/m
Mexico: Ceiling 100 mg/m
Mexico: TWA 200 ppm
Mexico: TWA 500 mg/m
Mexico: STEL 250 ppm
Mexico: STEL 625 mg/m
Mexico: TWA 50 ppm
Mexico: TWA 240 mg/m
Mexico: STEL 75 ppm
Mexico: STEL 360 mg/m
Mexico: TWA 26 ppm
Mexico: TWA 120 mg/m
Mexico: STEL 75 ppm
Mexico: STEL 360 mg/m
Mexico: TWA 400 ppm
Mexico: TWA 980 mg/m
Mexico: STEL 500 ppm
Mexico: STEL 1225 mg/m
3
3
3
3
3
3
3
3
3
3
Canada
WHMIS Hazard Class
Not determined
16. OTHER INFORMATION
NFPA
HMIS
Chronic Hazard Star Legend * = Chronic Health Hazard
Prepared By
Issuing Date
Revision Date
Revision Note
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
Health Hazards 3 Flammability 1
Instability 0 Physical and
Chemical Hazards -
Health Hazards 3* Flammability 1 Physical Hazard 0 Personal Protection
X
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
11-May-2015
25-Jun-2015
No information available
End of Safety Data Sheet
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