Hard As Nails
Not available.
Liquid.
Chemtrec (800) 424-9300 24 hour
SAFETY DATA SHEET
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:::
:
Supplier's details
: Betco Corporation
Hard As Nails
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
Section 2. Hazards identification
Not classified.
Classification of the
substance or mixture
:
Signal word
:
No signal word.
Hazard statements
:
No known significant effects or critical hazards.
Precautionary statements
Prevention
:
Not applicable.
Response
:
Not applicable.
Storage
:
Not applicable.
Disposal
:
Not applicable.
GHS label elements
OSHA/HCS status
:
While this material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the
safe handling and proper use of the product. This SDS should be retained and available
for employees and other users of this product.
Hazards not otherwise
classified
:
None known.
Section 3. Composition/information on ingredients
tris(2-butoxyethyl) phosphate
≥1 - <3
78-51-3
Ingredient name
CAS number
%
Other means of
identification
:
Not available.
CAS number
:
Not applicable.
Substance/mixture
Product code
:
659
CAS number/other identifiers
:
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Date of issue/Date of revision
:
1/27/2017
Date of previous issue
:
3/17/2015
Version
:
0.02
1/10
400 Van Camp Road
Bowling Green, Ohio 43402
www.betco.com
888-462-3826
Hard As Nails
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
Wash out mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. Get medical attention if symptoms occur.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if symptoms occur.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training.
Notes to physician
:
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments
:
No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation
No specific data.
No specific data.
No specific data.
:
::Eye contact
:
No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
phosphorus oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Date of issue/Date of revision
:
1/27/2017
Date of previous issue
:
3/17/2015
Version
:
0.02
2/10
Hard As Nails
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill
:
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
:
:
Protective measures
Put on appropriate personal protective equipment (see Section 8).
:
Precautions for safe handling
None.
Section 8. Exposure controls/personal protection
Appropriate engineering
controls
:
Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Control parameters
Occupational exposure limits
Date of issue/Date of revision
:
1/27/2017
Date of previous issue
:
3/17/2015
Version
:
0.02
3/10
Hard As Nails
Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. < 1 hour (breakthrough time): disposable vinyl
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with sideshields. Recommended: safety glasses with side-shields
Eye/face protection
Respiratory protection
:
:
:
Body protection
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Environmental exposure
controls
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures
:
Individual protection measures
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.0265
Not available.
Not available.
Partially soluble in the following materials: cold water.
Insoluble in the following materials: hot water.
Characteristic.
Odor
pH
White.
Color
Evaporation rate
Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: >120°C (>248°F) [Product does not sustain combustion.]
Not available.
8.1 to 8.9
Not available.
Odor threshold
Partition coefficient: noctanol/water
:
:::
:
:
:::
:
:
:
:
:
Appearance
Boiling point
:
Not available.
Flammability (solid, gas)
:
Not available.
Lower and upper explosive
(flammable) limits
:
Not available.
Decomposition temperature
:
Not available.
Date of issue/Date of revision
:
1/27/2017
Date of previous issue
:
3/17/2015
Version
:
0.02
4/10
Hard As Nails
Section 9. Physical and chemical properties
Viscosity
Not available.
:
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.
Chemical stability
No specific data.
:
:
:
Incompatible materials
:
Possibility of hazardous
reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
tris(2-butoxyethyl) phosphate
LD50 Oral
Rat
3 g/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
tris(2-butoxyethyl) phosphate
Eyes - Mild irritant
Rabbit
-
24 hours 500
milligrams
-
Skin - Mild irritant
Rabbit
-
24 hours 500
milligrams
-
Product/ingredient name
Result
Score
Exposure
Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
tris(2-butoxyethyl) phosphate
Category 3
Not applicable.
Respiratory tract
irritation
Name
Category
Not available.
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
Date of issue/Date of revision
:
1/27/2017
Date of previous issue
:
3/17/2015
Version
:
0.02
5/10
Hard As Nails
Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Eye contact
No known significant effects or critical hazards.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation
No specific data.
No specific data.
No specific data.
:::
Eye contact
:
No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral
27624.3 mg/kg
Dermal
60773.5 mg/kg
Route
ATE value
Acute toxicity estimates
:
Routes of entry anticipated: Oral, Dermal.
Routes of entry not anticipated: Inhalation.
Potential acute health effects
Potential immediate
effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate
effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
Section 12. Ecological information
Toxicity
tris(2-butoxyethyl) phosphate
Acute LC50 11200 µg/l Fresh water
Fish - Pimephales promelas
96 hours
Product/ingredient name
Species
Result
Exposure
Persistence and degradability
Not available.
Date of issue/Date of revision
:
1/27/2017
Date of previous issue
:
3/17/2015
Version
:
0.02
6/10
Hard As Nails
Section 12. Ecological information
LogP
ow
BCF
Potential
Bioaccumulative potential
Other adverse effects
:
No known significant effects or critical hazards.
Product/ingredient name
tris(2-butoxyethyl) phosphate
3.75
5.8
low
Soil/water partition
coefficient (KOC)
:
Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
:
Disposal methods
Section 14. Transport information
-
-
-
-
-
-
-
Not regulated.
-
-
Not regulated.
Not regulated.
---
DOT
Classification
IMDG
IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.
No.
No.
Transport within user’s premises:
always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
ADR/RID
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Date of issue/Date of revision
:
1/27/2017
Date of previous issue
:
3/17/2015
Version
:
0.02
7/10
Hard As Nails
Section 15. Regulatory information
U.S. Federal regulations
None of the components are listed.
Clean Water Act (CWA) 307
: tetraamminezinc(2+) carbonate
Clean Water Act (CWA) 311
: ammonia
Massachusetts
:
:
SARA 313
Product name
CAS number
%
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
2-(2-ethoxyethoxy)ethanol
111-90-0
≥5 - <10
2-(2-ethoxyethoxy)ethanol
111-90-0
≥5 - <10
Form R - Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Listed
Clean Air Act Section 602
Class I Substances
:
Not listed
Clean Air Act Section 602
Class II Substances
:
Not listed
DEA List I Chemicals
(Precursor Chemicals)
:
Not listed
DEA List II Chemicals
(Essential Chemicals)
:
Not listed
New York
:
None of the components are listed.
New Jersey
:
The following components are listed: GLYCOL ETHERS
Pennsylvania
:
The following components are listed: GLYCOL ETHERS
State regulations
TSCA 8(a) PAIR
: tris(2-butoxyethyl) phosphate; octamethylcyclotetrasiloxane;
(2-methoxymethylethoxy)propanol
TSCA 8(a) CDR Exempt/Partial exemption
: Not determined
TSCA 8(c) calls for record of SAR
: tris(2-butoxyethyl) phosphate
Not determined.
SARA 302/304
SARA 304 RQ
:
Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification
:
Not applicable.
tris(2-butoxyethyl) phosphate
≥1 - <3
No.
No.
No.
Yes.
No.
Name
%
Fire
hazard
Sudden
release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Not listed.
Date of issue/Date of revision
:
1/27/2017
Date of previous issue
:
3/17/2015
Version
:
0.02
8/10
Hard As Nails
Section 15. Regulatory information
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Inform Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventory
Australia
:
Not determined.
Canada
:
Not determined.
China
:
Not determined.
Europe
:
Not determined.
Japan
:
Japan inventory (ENCS)
: Not determined.
Japan inventory (ISHL)
: Not determined.
Republic of Korea
:
Not determined.
Malaysia
:
Not determined.
New Zealand
:
Not determined.
Philippines
:
Not determined.
Taiwan
:
Not determined.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
1
0
012
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Date of issue/Date of revision
:
1/27/2017
Date of previous issue
:
3/17/2015
Version
:
0.02
9/10
Hard As Nails
Section 16. Other information
4/25/2017
History
Date of printing
Date of issue/Date of
revision
Version
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:::
:
Indicates information that has changed from previously issued version.
References
:
Not available.
Key to abbreviations
:
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
1/27/2017
3/17/2015
0.02
Classification
Justification
Not classified.
Date of issue/Date of revision
:
1/27/2017
Date of previous issue
:
3/17/2015
Version
:
0.02
10/10
Loading...