Betco 3550400 User Manual

Betco pH7Q Dual
Not available. Liquid.
Chemtrec (800) 424-9300 24 hour
SAFETY DATA SHEET
Other means of identification
Product type
Emergency telephone number (with hours of operation)
Section 1. Identification
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Supplier's details
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Betco Corporation LTD 400 Van Camp Road Bowling Green, OH 43402 www.betco.com 888-462-3826
Betco pH7Q Dual
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
Section 2. Hazards identification
ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (dermal) - Category 4 SKIN CORROSION - Category 1B SERIOUS EYE DAMAGE - Category 1
Classification of the substance or mixture
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Signal word
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Danger
Hazard statements
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Causes severe skin burns and eye damage. (Previous statements per OSHA). CORROSIVE. Causes irreversible eye damage and skin burns. Harmful if swallowed or absorbed through the skin. (Previous statements per EPA).
Hazard pictograms
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Precautionary statements
Prevention
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Wear protective gloves: > 8 hours (breakthrough time): butyl rubber. Wear eye or face protection: Recommended: splash goggles. Wear protective clothing. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Response
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IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or physician. IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician.
GHS label elements
OSHA/HCS status
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This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of nonpesticide chemicals. Please read complete product label.
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:11/14
Betco pH7Q Dual
Section 2. Hazards identification
Storage
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Store locked up.
Disposal
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Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
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None known.
Section 3. Composition/information on ingredients
didecyldimethylammonium chloride
≥5 - <10
7173-51-5
Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides
≥5 - <10
68424-85-1
tetrasodium ethylene diamine tetraacetate
≥3 - <5
64-02-8
ethanol
≥1 - <3
64-17-5
Alcohols, C9-11, ethoxylated
≥1 - <3
68439-46-3
Terpenes and Terpenoids, sweet orange-oil
≥0.3 - <1
68647-72-3
Ingredient name
CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Other means of identification
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Not available.
CAS number
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Not applicable.
Substance/mixture
Product code
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355
CAS number/other identifiers
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Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
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Description of necessary first aid measures
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:12/14
Betco pH7Q Dual
Section 4. First aid measures
recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Protection of first-aiders
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No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician
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In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
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No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation
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No known significant effects or critical hazards.
No known significant effects or critical hazards. (Per OSHA). Harmful if swallowed. (Per EPA).
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Ingestion
Skin contact
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Causes severe burns. (Per OSHA). Corrosive. Causes skin burns. Harmful if absorbed through the skin. (Per EPA).
Causes serious eye damage. (Per OSHA) Corrosive. Causes irreversible eye damage. (Per EPA).
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Eye contact Over-exposure signs/symptoms
Skin contact
Ingestion Inhalation
No specific data.
Adverse symptoms may include the following: stomach pains
Adverse symptoms may include the following: pain or irritation redness blistering may occur
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Eye contact
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Adverse symptoms may include the following: pain watering redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides halogenated compounds metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
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None known.
Suitable extinguishing media
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Unsuitable extinguishing media
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Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:13/14
Betco pH7Q Dual
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
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Special protective actions for fire-fighters
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. W ash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
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No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.
Large spill
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Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
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Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
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If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
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Protective measures
Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
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Precautions for safe handling
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:14/14
Betco pH7Q Dual
ethanol
ACGIH TLV (United States, 3/2016).
STEL: 1000 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours. TWA: 1900 mg/m³ 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough time): butyl rubber
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Recommended: splash goggles
Eye/face protection
Respiratory protection
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Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
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Environmental exposure controls
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Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
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If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
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Control parameters
Individual protection measures
Occupational exposure limits
Skin protection
Other skin protection
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Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:15/14
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