Betco 3550400 User Manual

Page 1
Betco pH7Q Dual
Not available. Liquid.
Chemtrec (800) 424-9300 24 hour
SAFETY DATA SHEET
Other means of identification
Product type
Emergency telephone number (with hours of operation)
Section 1. Identification
:
: :
:
Supplier's details
:
Betco Corporation LTD 400 Van Camp Road Bowling Green, OH 43402 www.betco.com 888-462-3826
Betco pH7Q Dual
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
Section 2. Hazards identification
ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (dermal) - Category 4 SKIN CORROSION - Category 1B SERIOUS EYE DAMAGE - Category 1
Classification of the substance or mixture
:
Signal word
:
Danger
Hazard statements
:
Causes severe skin burns and eye damage. (Previous statements per OSHA). CORROSIVE. Causes irreversible eye damage and skin burns. Harmful if swallowed or absorbed through the skin. (Previous statements per EPA).
Hazard pictograms
:
Precautionary statements
Prevention
:
Wear protective gloves: > 8 hours (breakthrough time): butyl rubber. Wear eye or face protection: Recommended: splash goggles. Wear protective clothing. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Response
:
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or physician. IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician.
GHS label elements
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of nonpesticide chemicals. Please read complete product label.
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:11/14
Page 2
Betco pH7Q Dual
Section 2. Hazards identification
Storage
:
Store locked up.
Disposal
:
Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
:
None known.
Section 3. Composition/information on ingredients
didecyldimethylammonium chloride
≥5 - <10
7173-51-5
Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl, chlorides
≥5 - <10
68424-85-1
tetrasodium ethylene diamine tetraacetate
≥3 - <5
64-02-8
ethanol
≥1 - <3
64-17-5
Alcohols, C9-11, ethoxylated
≥1 - <3
68439-46-3
Terpenes and Terpenoids, sweet orange-oil
≥0.3 - <1
68647-72-3
Ingredient name
CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Other means of identification
:
Not available.
CAS number
:
Not applicable.
Substance/mixture
Product code
:
355
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in
Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.
Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Description of necessary first aid measures
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:12/14
Page 3
Betco pH7Q Dual
Section 4. First aid measures
recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician
:
In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
:
No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards. (Per OSHA). Harmful if swallowed. (Per EPA).
:
Ingestion
Skin contact
:
Causes severe burns. (Per OSHA). Corrosive. Causes skin burns. Harmful if absorbed through the skin. (Per EPA).
Causes serious eye damage. (Per OSHA) Corrosive. Causes irreversible eye damage. (Per EPA).
:
Eye contact Over-exposure signs/symptoms
Skin contact
Ingestion Inhalation
No specific data.
Adverse symptoms may include the following: stomach pains
Adverse symptoms may include the following: pain or irritation redness blistering may occur
: :
:
Eye contact
:
Adverse symptoms may include the following: pain watering redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides halogenated compounds metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:13/14
Page 4
Betco pH7Q Dual
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. W ash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
:
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.
Large spill
:
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
:
:
Protective measures
Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:14/14
Page 5
Betco pH7Q Dual
ethanol
ACGIH TLV (United States, 3/2016).
STEL: 1000 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours. TWA: 1900 mg/m³ 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 1000 ppm 8 hours. TWA: 1900 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough time): butyl rubber
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Recommended: splash goggles
Eye/face protection
Respiratory protection
:
:
:
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Environmental exposure controls
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
:
If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
:
Control parameters
Individual protection measures
Occupational exposure limits
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:15/14
Page 6
Betco pH7Q Dual
Section 8. Exposure controls/personal protection
Personal protective equipment (Pictograms)
:
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.0053
Not available.
Not available.
Easily soluble in the following materials: cold water.
Lemon-like.
Odor
pH
Orange.
Color
Evaporation rate
Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: >100°C (>212°F) [Product does not sustain combustion.]
Not available. 6 to 8
Viscosity
Not available.
Not available.
Odor threshold
Partition coefficient: n­octanol/water
:::
:::::
:::
::::Appearance
Boiling point
:
Not available.
Flammability (solid, gas)
:
Not available.
Lower and upper explosive (flammable) limits
:
Not available.
Decomposition temperature
:
Not available.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid
No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.
Chemical stability
No specific data.
:
:
:
Incompatible materials
:
Possibility of hazardous reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:16/14
Page 7
Betco pH7Q Dual
Section 11. Toxicological information
Acute toxicity
didecyldimethylammonium chloride
LD50 Oral
Rat
84 mg/kg
-
Quaternary ammonium compounds, benzyl­C12-16-alkyldimethyl, chlorides
LD50 Oral
Rat
426 mg/kg
-
tetrasodium ethylene diamine tetraacetate
LD50 Oral
Rat
10 g/kg
-
ethanol
LC50 Inhalation Vapor
Rat
124700 mg/m³
4 hours
LD50 Oral
Rat
7 g/kg
-
Alcohols, C9-11, ethoxylated
LD50 Dermal
Rabbit
2 g/kg
-
LD50 Oral
Rat
1378 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
didecyldimethylammonium chloride
Skin - Severe irritant
Rabbit
-
500 milligrams
-
Quaternary ammonium compounds, benzyl­C12-16-alkyldimethyl, chlorides
Skin - Severe irritant
Rabbit
-
25 milligrams
-
tetrasodium ethylene diamine tetraacetate
Eyes - Moderate irritant
Rabbit
-
24 hours 100 milligrams
-
Skin - Moderate irritant
Rabbit
-
24 hours 500 milligrams
-
ethanol
Eyes - Mild irritant
Rabbit
-
24 hours 500 milligrams
-
Eyes - Moderate irritant
Rabbit
-
0.066666667 minutes 100 milligrams
-
Eyes - Moderate irritant
Rabbit
-
100 microliters
-
Eyes - Severe irritant
Rabbit
-
500 milligrams
-
Skin - Mild irritant
Rabbit
-
400 milligrams
-
Skin - Moderate irritant
Rabbit
-
24 hours 20 milligrams
-
Product/ingredient name
Result
Score
Exposure
Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
ethanol
-1-
Product/ingredient name
NTP
IARC
OSHA
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:17/14
Page 8
Betco pH7Q Dual
Section 11. Toxicological information
Not available.
Information on the likely routes of exposure
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards. (Per OSHA). Harmful if swallowed. (Per EPA).
:
Ingestion
Skin contact
:
Causes severe burns. (Per OSHA). Corrosive. Causes skin burns. Harmful if absorbed through the skin. (Per EPA).
Causes serious eye damage. (Per OSHA) Corrosive. Causes irreversible eye damage. (Per EPA).
:
Eye contact
No known significant effects or critical hazards.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion Inhalation
No specific data.
Adverse symptoms may include the following: stomach pains
Adverse symptoms may include the following: pain or irritation redness blistering may occur
: :
:
Eye contact
:
Adverse symptoms may include the following: pain watering redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Numerical measures of toxicity
Acute toxicity estimates
Aspiration hazard
Not available.
:
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential acute health effects
Potential immediate effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:18/14
Page 9
Betco pH7Q Dual
Section 11. Toxicological information
Not available.
Section 12. Ecological information
LogP
ow
BCF
Potential
Bioaccumulative potential
Product/ingredient name
tetrasodium ethylene diamine tetraacetate
5.01
1.8
low
ethanol
-0.35
-
low
Toxicity
didecyldimethylammonium chloride
Acute EC50 110 µg/l Fresh water
Algae - Chlorella pyrenoidosa ­Exponential growth phase
72 hours
Acute EC50 14.22 ppb Fresh water
Algae - Pseudokirchneriella subcapitata
96 hours
Acute EC50 18 ppb Fresh water
Daphnia - Daphnia magna
48 hours
Acute LC50 39 µg/l Marine water
Crustaceans - Americamysis bahia - Juvenile (Fledgling, Hatchling, Weanling)
48 hours
Acute LC50 0.01 µg/l Fresh water
Fish - Acipenser transmontanus ­Larvae
96 hours
Chronic NOEC 25 µg/l Fresh water
Algae - Pseudokirchneriella subcapitata - Exponential growth phase
72 hours
Chronic NOEC 125 µg/l Fresh water
Daphnia - Daphnia magna
21 days
Quaternary ammonium compounds, benzyl­C12-16-alkyldimethyl, chlorides
Acute EC50 670 µg/l Fresh water
Algae - Chlorella pyrenoidosa ­Exponential growth phase
96 hours
Acute EC50 5.9 ppb Fresh water
Daphnia - Daphnia magna
48 hours
Acute LC50 64 ppb Fresh water
Fish - Oncorhynchus mykiss
96 hours
Chronic NOEC 4.15 ppb Marine water
Daphnia - Daphnia magna
21 days
Chronic NOEC 32.2 ppb
Fish - Pimephales promelas
34 days
tetrasodium ethylene diamine tetraacetate
Acute LC50 486000 µg/l Fresh water
Fish - Lepomis macrochirus
96 hours
ethanol
Acute EC50 17.921 mg/l Marine water
Algae - Ulva pertusa
96 hours
Acute EC50 2000 µg/l Fresh water
Daphnia - Daphnia magna
48 hours
Acute LC50 25500 µg/l Marine water
Crustaceans - Artemia franciscana - Larvae
48 hours
Acute LC50 42000 µg/l Fresh water
Fish - Oncorhynchus mykiss
4 days
Chronic NOEC 4.995 mg/l Marine water
Algae - Ulva pertusa
96 hours
Chronic NOEC 100 ul/L Fresh water
Daphnia - Daphnia magna ­Neonate
21 days
Chronic NOEC 0.375 ul/L Fresh water
Fish - Gambusia holbrooki ­Larvae
12 weeks
Alcohols, C9-11, ethoxylated
Acute EC50 5.36 mg/l Fresh water
Crustaceans - Ceriodaphnia dubia - Neonate
48 hours
Acute EC50 2686 µg/l Fresh water
Daphnia - Daphnia magna ­Neonate
48 hours
Acute LC50 8500 µg/l Fresh water
Fish - Pimephales promelas
96 hours
Product/ingredient name
Species
Result
Exposure
Persistence and degradability
Mobility in soil
Not available.
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:19/14
Page 10
Betco pH7Q Dual
Section 12. Ecological information
Other adverse effects
:
No known significant effects or critical hazards.
Soil/water partition coefficient (KOC)
:
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:
Disposal methods
Section 14. Transport information
Disinfectants, Liquid, Corrosive, N.O. S. (Quaternary Ammonium Compound)
8
III
Disinfectant, Liquid, Corrosive, N.O. S. (Quaternary Ammonium Compound), Marine Pollutant
(didecyldimethylammonium
chloride, Quaternary ammonium compounds, benzyl-
C12-16-alkyldimethyl,
chlorides)
8
III
Disinfectants, Liquid, Corrosive, N.O. S. (Quaternary Ammonium Compound)
1903 8
III
1903
1903
DOT
Classification
IMDG
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Environmental hazards
No.
Yes.
No.
TDG
Classification
1903
Disinfectant, Liquid, Corrosive, N.O. S. (Quaternary Ammonium Compound), Marine Pollutant
(didecyldimethylammonium
chloride, Quaternary ammonium compounds, benzyl-
C12-16-alkyldimethyl,
chlorides)
8
III
Yes.
ADR/RID
1903
Disinfectant, Liquid, Corrosive, N.O. S. (Quaternary Ammonium Compound), Marine Pollutant
(didecyldimethylammonium
chloride, Quaternary ammonium compounds, benzyl-
C12-16-alkyldimethyl,
chlorides)
8
III
Yes.
Mexico
Classification
1903
Disinfectants, Liquid, Corrosive, N.O. S. (Quaternary Ammonium Compound)
8
III
No.
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:110/14
Page 11
Betco pH7Q Dual
Section 14. Transport information
Limited quantity
Yes.
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
The
environmentally
hazardous substance mark may appear if required by other transportation regulations.
Additional information
Special precautions for user
Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport within user’s premises:
always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
:
Not available.
:
Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2. 40-2.42 (Class
8), 2.7 (Marine pollutant mark).
The marine pollutant mark is not required when transported by road or rail.
The
environmentally
hazardous substance mark is not required when transported in sizes of ≤5 L or ≤5 kg.
-
Section 15. Regulatory information
U.S. Federal regulations
TSCA 4(a) proposed test rules
: Quaternary ammonium compounds, benzyl-
C12-16-alkyldimethyl, chlorides
Clean Water Act (CWA) 311
: sodium hydroxide
:
Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs)
:
Not listed
Clean Air Act Section 602 Class I Substances
:
Not listed
Clean Air Act Section 602 Class II Substances
:
Not listed
DEA List I Chemicals (Precursor Chemicals)
:
Not listed
DEA List II Chemicals (Essential Chemicals)
:
Not listed
TSCA 8(a) CDR Exempt/Partial exemption
: Not determined
Not determined.
SARA 302/304
SARA 304 RQ
:
Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification
:
Immediate (acute) health hazard
Composition/information on ingredients
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:111/14
Page 12
Betco pH7Q Dual
Section 15. Regulatory information
The following components are listed: ETHYL ALCOHOL; DENATURED ALCOHOL
Massachusetts
:
New York
:
None of the components are listed.
New Jersey
:
The following components are listed: ETHYL ALCOHOL; ALCOHOL
Pennsylvania
:
The following components are listed: DENATURED ALCOHOL; ETHANOL
State regulations
didecyldimethylammonium chloride
≥5 - <10
No.
No.
No.
Yes.
No.
Quaternary ammonium compounds, benzyl­C12-16-alkyldimethyl, chlorides
≥5 - <10
No.
No.
No.
Yes.
No.
tetrasodium ethylene diamine tetraacetate
≥3 - <5
No.
No.
No.
Yes.
No.
ethanol
≥1 - <3
Yes.
No.
No.
Yes.
No.
Alcohols, C9-11, ethoxylated
≥1 - <3
No.
No.
No.
Yes.
No.
Terpenes and Terpenoids, sweet orange-oil
≥0.3 - <1
Yes.
No.
No.
Yes.
No.
Name
%
Fire hazard
Sudden release of pressure
Reactive
Immediate (acute) health hazard
Delayed (chronic) health hazard
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Inform Consent (PIC)
Not listed.
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventory
Australia
:
Not determined.
Canada
:
Not determined.
China
:
Not determined.
Europe
:
Not determined.
Japan
:
Japan inventory (ENCS)
: Not determined.
Japan inventory (ISHL)
: Not determined.
Republic of Korea
:
Not determined.
Malaysia
:
Not determined.
New Zealand
:
Not determined.
Philippines
:
Not determined.
Taiwan
:
Not determined.
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:112/14
Page 13
Betco pH7Q Dual
Section 16. Other information
3/8/2017
History
Date of printing
Date of issue/Date of revision
Version
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References
:
Not available.
Key to abbreviations
:
ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations
3/8/2017
7/31/2015
1
Hazardous Material Information System (U.S.A.)
2
1
0
012
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification
Justification
Acute Tox. 4, H302
Expert judgment
Acute Tox. 4, H312
Expert judgment
Skin Corr. 1B, H314
Expert judgment
Eye Dam. 1, H318
Expert judgment
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:113/14
Page 14
Betco pH7Q Dual
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of issue/Date of revision
:
3/8/2017
Date of previous issue
:
7/31/2015
Version
:114/14
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