Betco 01523-00 User Manual

Graffiti Remover
Not available. Gas.
Chemtrec (800) 424-9300 24 hour
SAFETY DATA SHEET
Other means of identification
Product type
Emergency telephone number (with hours of operation)
Section 1. Identification
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Supplier's details
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Betco Corporation 400 Van Camp Road Bowling Green, Ohio 43402 www.betco.com 888-462-3826
Graffiti Remover
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
Product code
:
015
Section 2. Hazards identification
FLAMMABLE AEROSOLS - Category 1 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) ­Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1
Classification of the substance or mixture
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Signal word
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Danger
Hazard statements
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Extremely flammable aerosol. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure.
Hazard pictograms
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Precautionary statements
Prevention
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Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves: 1 - 4 hours (breakthrough time): butyl rubber. Wear eye or face protection: Recommended: safety glasses. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe gas. Wash hands thoroughly after handling. Pressurized container: Do not pierce or burn, even after use.
GHS label elements
OSHA/HCS status
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This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:61/16
Graffiti Remover
Section 2. Hazards identification
Response
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Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage
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Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place.
Disposal
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Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified
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None known.
Section 3. Composition/information on ingredients
toluene
20 - 40
108-88-3
acetone
2.5 - 10
67-64-1
butane
2.5 - 10
106-97-8
propane
2.5 - 10
74-98-6
2-butoxyethanol
2.5 - 10
111-76-2
2-(2-butoxyethoxy)ethanol
2.5 - 10
112-34-5
sodium hydroxide
0.1 - 1
1310-73-2
Ingredient name
CAS number %
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Other means of identification
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Not available.
Substance/mixture
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Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
As this product is a gas, refer to the inhalation section. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
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Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:62/16
Graffiti Remover
Section 4. First aid measures
Protection of first-aiders
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No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician
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Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Specific treatments
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No specific treatment.
Inhalation
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Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. As this product is a gas, refer to the inhalation section.
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Ingestion Skin contact
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Causes skin irritation. Contact with rapidly expanding gas may cause burns or frostbite.
Causes serious eye irritation. Contact with rapidly expanding gas may cause burns or frostbite.
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Eye contact Over-exposure signs/symptoms
Skin contact Ingestion
Inhalation
Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations
Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations
Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations
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Eye contact
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Adverse symptoms may include the following: pain or irritation watering redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
None known.
Suitable extinguishing media
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Unsuitable extinguishing media
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Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:63/16
Graffiti Remover
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials: carbon dioxide carbon monoxide
Contains gas under pressure. Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
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Special protective actions for fire-fighters
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
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No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill
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Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment.
Small spill
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Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders
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If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".
Section 7. Handling and storage
Protective measures
Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure ­obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe gas. Do not swallow. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not puncture or incinerate container.
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Precautions for safe handling
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:64/16
Graffiti Remover
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage, including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Do not store above the following temperature: 49°C (120.2°F). Store in accordance with local regulations. Store in a segregated and approved area. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Store locked up. Eliminate all ignition sources. Keep container tightly closed and sealed until ready for use. See Section 10 for incompatible materials before handling or use.
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toluene
OSHA PEL 1989 (United States, 3/1989).
TWA: 100 ppm 8 hours. TWA: 375 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m³ 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2016).
TWA: 100 ppm 10 hours. TWA: 375 mg/m³ 10 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours. propane
OSHA PEL 1989 (United States, 3/1989).
TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2017). Oxygen Depletion [Asphyxiant].
acetone
ACGIH TLV (United States, 3/2017).
TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 750 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. STEL: 1000 ppm 15 minutes. STEL: 2400 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 250 ppm 10 hours. TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 1000 ppm 8 hours. TWA: 2400 mg/m³ 8 hours.
2-butoxyethanol
OSHA PEL 1989 (United States, 3/1989).
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Control parameters
Occupational exposure limits
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:65/16
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