Page 1
Graffiti Remover
Not available.
Gas.
Chemtrec (800) 424-9300 24 hour
SAFETY DATA SHEET
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:::
:
Supplier's details
:
Betco Corporation
400 Van Camp Road
Bowling Green, Ohio 43402
www.betco.com
888-462-3826
Graffiti Remover
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
Product code
:
015
Section 2. Hazards identification
FLAMMABLE AEROSOLS - Category 1
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Classification of the
substance or mixture
:
Signal word
:
Danger
Hazard statements
:
Extremely flammable aerosol. May be fatal if swallowed and enters airways. Causes
skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness.
Suspected of damaging the unborn child. May cause damage to organs through
prolonged or repeated exposure.
Hazard pictograms
:
Precautionary statements
Prevention
:
Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves: 1 - 4 hours (breakthrough time):
butyl rubber. Wear eye or face protection: Recommended: safety glasses. Wear
protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking. Do not spray on an open flame or other ignition source.
Use only outdoors or in a well-ventilated area. Do not breathe gas. Wash hands
thoroughly after handling. Pressurized container: Do not pierce or burn, even after use.
GHS label elements
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:61/16
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Graffiti Remover
Section 2. Hazards identification
Response
:
Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED:
Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON
SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it
before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage
:
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal
:
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:
None known.
Section 3. Composition/information on ingredients
toluene
20 - 40
108-88-3
acetone
2.5 - 10
67-64-1
butane
2.5 - 10
106-97-8
propane
2.5 - 10
74-98-6
2-butoxyethanol
2.5 - 10
111-76-2
2-(2-butoxyethoxy)ethanol
2.5 - 10
112-34-5
sodium hydroxide
0.1 - 1
1310-73-2
Ingredient name
CAS number
%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:
Not available.
Substance/mixture
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
As this product is a gas, refer to the inhalation section. Aspiration hazard if swallowed.
Can enter lungs and cause damage. Do not induce vomiting.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. To avoid the risk of static discharges and gas ignition, soak contaminated
clothing thoroughly with water before removing it. Continue to rinse for at least 10
minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly
before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
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:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:62/16
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Graffiti Remover
Section 4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician
:
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments
:
No specific treatment.
Inhalation
:
Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. As this product is a gas, refer to the inhalation section.
:
Ingestion
Skin contact
:
Causes skin irritation. Contact with rapidly expanding gas may cause burns or frostbite.
Causes serious eye irritation. Contact with rapidly expanding gas may cause burns or
frostbite.
:
Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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:
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Date of previous issue
:
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:63/16
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Contains gas under pressure. Extremely flammable aerosol. Runoff to sewer may
create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled
from a fire at high speed.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Shut off all ignition sources. No flares, smoking or flames in hazard area.
Avoid breathing gas. Provide adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Put on appropriate personal protective equipment.
Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil or air).
Large spill
:
Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Section 7. Handling and storage
Protective measures
Put on appropriate personal protective equipment (see Section 8). Contains gas under
pressure. Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe gas. Do not swallow. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use
away from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Empty containers retain product residue and can be hazardous. Do not puncture
or incinerate container.
:
Precautions for safe handling
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:64/16
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Graffiti Remover
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 49°C (120.2°F). Store in accordance with
local regulations. Store in a segregated and approved area. Store away from direct
sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see
Section 10). Store locked up. Eliminate all ignition sources. Keep container tightly
closed and sealed until ready for use. See Section 10 for incompatible materials before
handling or use.
:
:
toluene
OSHA PEL 1989 (United States, 3/1989).
TWA: 100 ppm 8 hours.
TWA: 375 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2016).
TWA: 100 ppm 10 hours.
TWA: 375 mg/m³ 10 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.
propane
OSHA PEL 1989 (United States, 3/1989).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2017). Oxygen
Depletion [Asphyxiant].
acetone
ACGIH TLV (United States, 3/2017).
TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 750 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
STEL: 1000 ppm 15 minutes.
STEL: 2400 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.
2-butoxyethanol
OSHA PEL 1989 (United States, 3/1989).
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Control parameters
Occupational exposure limits
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:
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Date of previous issue
:
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:65/16
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Graffiti Remover
Section 8. Exposure controls/personal protection
Absorbed through skin.
TWA: 25 ppm 8 hours.
TWA: 120 mg/m³ 8 hours.
NIOSH REL (United States, 10/2016).
Absorbed through skin.
TWA: 5 ppm 10 hours.
TWA: 24 mg/m³ 10 hours.
ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 6/2016).
Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 240 mg/m³ 8 hours.
2-(2-butoxyethoxy)ethanol
ACGIH TLV (United States, 3/2017).
TWA: 10 ppm 8 hours. Form: Inhalable
fraction and vapor
Hand protection
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated. 1 - 4 hours (breakthrough
time): butyl rubber
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Recommended: safety glasses
Eye/face protection
:
:
Body protection
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures
:
Individual protection measures
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:66/16
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Graffiti Remover
Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use. Respirator selection must be based on known or anticipated exposure
levels, the hazards of the product and the safe working limits of the selected respirator.
Respiratory protection
:
Personal protective
equipment (Pictograms)
:
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Gas. [Compressed gas.]
Not available.
0.827
Not available.
Not available.
Partially soluble in the following materials: cold water and hot water.
Aromatic.
Odor
pH
Tan.
Color
Evaporation rate
Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: <-18°C (<-0.4°F)
Not available.
Not available.
Viscosity
Not available.
Not available.
Odor threshold
Partition coefficient: noctanol/water
:
:::
:
:
:::
:
:
:
:
:
:
Appearance
Boiling point
:
Not available.
Flammability (solid, gas)
:
Extremely flammable in the presence of the following materials or conditions: open
flames, sparks and static discharge.
Lower and upper explosive
(flammable) limits
:
Not available.
Decomposition temperature
:
Not available.
Type of aerosol
:
Spray
Heat of combustion
:
27.74 kJ/g
Aerosol product
Solubility in water
:
Not available.
Flow time (ISO 2431)
:
Not available.
Section 10. Stability and reactivity
Conditions to avoid
Avoid all possible sources of ignition (spark or flame).
The product is stable.
Chemical stability
:
:
Possibility of hazardous
reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:67/16
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Graffiti Remover
Section 10. Stability and reactivity
Hazardous decomposition
products
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
No specific data.
:
Incompatible materials
:
Section 11. Toxicological information
Acute toxicity
toluene
LC50 Inhalation Vapor
Rat
49 g/m³
4 hours
LD50 Oral
Rat
636 mg/kg
-
acetone
LD50 Oral
Rat
5800 mg/kg
-
2-butoxyethanol
LC50 Inhalation Gas.
Rat
450 ppm
4 hours
LD50 Dermal
Rabbit
220 mg/kg
-
LD50 Oral
Rat
250 mg/kg
-
2-(2-butoxyethoxy)ethanol
LD50 Dermal
Rabbit
2700 mg/kg
-
LD50 Oral
Rat
4500 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Mutagenicity
Not available.
Irritation/Corrosion
toluene
Eyes - Mild irritant
Rabbit
-
0.5 minutes
100
milligrams
-
Eyes - Mild irritant
Rabbit
-
870
Micrograms
-
Eyes - Severe irritant
Rabbit
-
24 hours 2
milligrams
-
Skin - Mild irritant
Pig
-
24 hours 250
microliters
-
Skin - Mild irritant
Rabbit
-
435
milligrams
-
Skin - Moderate irritant
Rabbit
-
24 hours 20
milligrams
-
Skin - Moderate irritant
Rabbit
-
500
milligrams
-
acetone
Eyes - Mild irritant
Human
-
186300 parts
per million
-
Eyes - Mild irritant
Rabbit
-
10 microliters
-
Eyes - Moderate irritant
Rabbit
-
24 hours 20
milligrams
-
Eyes - Severe irritant
Rabbit
-
20 milligrams
-
Skin - Mild irritant
Rabbit
-
24 hours 500
milligrams
-
Skin - Mild irritant
Rabbit
-
395
milligrams
-
2-butoxyethanol
Eyes - Moderate irritant
Rabbit
-
24 hours 100
milligrams
-
Eyes - Severe irritant
Rabbit
-
100
milligrams
-
Skin - Mild irritant
Rabbit
-
500
milligrams
-
2-(2-butoxyethoxy)ethanol
Eyes - Moderate irritant
Rabbit
-
24 hours 20
milligrams
-
Eyes - Severe irritant
Rabbit
-
20 milligrams
-
Product/ingredient name
Result
Score
Exposure
Observation
Sensitization
Not available.
Species
Information on toxicological effects
Date of issue/Date of revision
:
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Date of previous issue
:
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:68/16
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Graffiti Remover
Section 11. Toxicological information
Carcinogenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Information on the likely
routes of exposure
Inhalation
:
Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. As this product is a gas, refer to the inhalation section.
:
Ingestion
Skin contact
:
Causes skin irritation. Contact with rapidly expanding gas may cause burns or frostbite.
Causes serious eye irritation. Contact with rapidly expanding gas may cause burns or
frostbite.
:
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Graffiti Remover
Category 3
Not applicable.
Narcotic effects
toluene
Category 3
Not applicable.
Narcotic effects
propane
Category 3
Not applicable.
Respiratory tract
irritation
acetone
Category 3
Not applicable.
Narcotic effects
Name
Category
Name
Category
Graffiti Remover
Category 2
Not determined
Not determined
toluene
Category 2
Not determined
Not determined
Aspiration hazard
Name
Result
Graffiti Remover
ASPIRATION HAZARD - Category 1
toluene
ASPIRATION HAZARD - Category 1
2-butoxyethanol
ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:
Routes of entry anticipated: Dermal, Inhalation.
Potential acute health effects
Classification
toluene
-3-
2-butoxyethanol
-3-
Product/ingredient name
NTP
IARC
OSHA
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:
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:
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Graffiti Remover
Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
Suspected of damaging the unborn child.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate
effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
Section 12. Ecological information
Toxicity
Date of issue/Date of revision
:
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Date of previous issue
:
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:610/16
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Graffiti Remover
Section 12. Ecological information
LogP
ow
BCF
Potential
Bioaccumulative potential
Other adverse effects
:
No known significant effects or critical hazards.
Product/ingredient name
toluene
2.7390low
propane
1.09-low
acetone
-0.23
-
low
2-butoxyethanol
0.81-low
2-(2-butoxyethoxy)ethanol
1-low
toluene
Acute EC50 12500 µg/l Fresh water
Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 11600 µg/l Fresh water
Crustaceans - Gammarus
pseudolimnaeus - Adult
48 hours
Acute EC50 6000 µg/l Fresh water
Daphnia - Daphnia magna Juvenile (Fledgling, Hatchling,
Weanling)
48 hours
Acute LC50 5500 µg/l Fresh water
Fish - Oncorhynchus kisutch - Fry
96 hours
Chronic NOEC 1000 µg/l Fresh water
Daphnia - Daphnia magna
21 days
acetone
Acute EC50 20.565 mg/l Marine water
Algae - Ulva pertusa
96 hours
Acute LC50 6000000 µg/l Fresh water
Crustaceans - Gammarus pulex
48 hours
Acute LC50 10000 µg/l Fresh water
Daphnia - Daphnia magna
48 hours
Acute LC50 5600 ppm Fresh water
Fish - Poecilia reticulata
96 hours
Chronic NOEC 4.95 mg/l Marine water
Algae - Ulva pertusa
96 hours
Chronic NOEC 0.016 ml/L Fresh water
Crustaceans - Daphniidae
21 days
Chronic NOEC 0.1 ml/L Fresh water
Daphnia - Daphnia magna Neonate
21 days
Chronic NOEC 5 µg/l Marine water
Fish - Gasterosteus aculeatus Larvae
42 days
2-butoxyethanol
Acute EC50 >1000 mg/l Fresh water
Daphnia - Daphnia magna
48 hours
Acute LC50 800000 µg/l Marine water
Crustaceans - Crangon crangon
48 hours
Acute LC50 1250000 µg/l Marine water
Fish - Menidia beryllina
96 hours
2-(2-butoxyethoxy)ethanol
Acute LC50 1300000 µg/l Fresh water
Fish - Lepomis macrochirus
96 hours
Product/ingredient name
Species
Result
Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:
Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Empty pressure vessels should be returned to the supplier. Waste packaging should be
recycled. Incineration or landfill should only be considered when recycling is not
feasible. This material and its container must be disposed of in a safe way. Empty
containers or liners may retain some product residues. Do not puncture or incinerate
container.
:
Disposal methods
United States - RCRA Toxic hazardous waste "U" List
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:611/16
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Section 13. Disposal considerations
Toluene; Benzene, methyl-
108-88-3
Listed
U220
Acetone (I); 2-Propanone (I)
67-64-1
Listed
U002
Ingredient
CAS #
Status
Reference
number
Section 14. Transport information
Aerosols
2.1
-
Aerosols
2.1
-
Not available.
Not available.
2.1
-
1950
1950
Reportable quantity
3333.3 lbs / 1513.3 kg. Package sizes shipped in quantities less
than the product reportable quantity are not subject to the RQ (reportable quantity)
transportation requirements.
Limited quantity
Yes.
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
The environmentally hazardous substance mark may appear if required by other
transportation regulations.
DOT
Classification
IMDG
IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.
Yes.
Yes. The
environmentally
hazardous
substance
mark is not
required.
Transport within user’s premises:
always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
Not available.
:
TDG
Classification
1950
Aerosols
2.1
-
Yes.
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.13-2.17 (Class 2), 2.7 (Marine pollutant mark).
The marine pollutant mark is not required when transported by road or rail.
Explosive Limit and Limited Quantity Index
1
ADR/RID
1950
Aerosols
2
-
Yes.
Tunnel code
D
Mexico
Classification
1950
Aerosols
2.1
-
Yes. The
environmentally
hazardous
substance
mark is not
required.
DOT Classification
TDG Classification
ADR/RID
IMDG
IATA
:
:
:::
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:612/16
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Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: PROPANE; TOLUENE; METHYLBENZENE;
ACETONE; 2-BUTOXYETHANOL; BUTYL CELLOSOLVE; BUTANE
Clean Water Act (CWA) 307
: toluene
Clean Water Act (CWA) 311
: toluene; sodium hydroxide
Clean Air Act (CAA) 112 regulated flammable substances
: propane; butane
Massachusetts
:
:
SARA 313
Product name
CAS number
%
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
toluene
108-88-3
≥25 - ≤50
2-butoxyethanol
111-76-2
≤10
2-(2-butoxyethoxy)ethanol
112-34-5
≤10
toluene
108-88-3
≥25 - ≤50
2-butoxyethanol
111-76-2
≤10
2-(2-butoxyethoxy)ethanol
112-34-5
≤10
Form R - Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Listed
Clean Air Act Section 602
Class I Substances
:
Not listed
Clean Air Act Section 602
Class II Substances
:
Not listed
DEA List I Chemicals
(Precursor Chemicals)
:
Not listed
DEA List II Chemicals
(Essential Chemicals)
:
Listed
New York
:
The following components are listed: Toluene; Acetone; 2-Propanone
New Jersey
:
The following components are listed: PROPANE; TOLUENE; BENZENE, METHYL-;
ACETONE; 2-PROPANONE; 2-BUTOXY ETHANOL; BUTYL CELLOSOLVE; BUTANE;
GLYCOL ETHERS
State regulations
TSCA 8(a) CDR Exempt/Partial exemption
: Not determined
SARA 302/304
SARA 304 RQ
:
Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification
:
Fire hazard
Sudden release of pressure
Immediate (acute) health hazard
Delayed (chronic) health hazard
toluene
≥25 - ≤50
Yes.
No.
No.
Yes.
Yes.
propane
≥10 - ≤25
Yes.
Yes.
No.
Yes.
No.
acetone
≤10
Yes.
No.
No.
Yes.
No.
2-butoxyethanol
≤10
Yes.
No.
No.
Yes.
No.
2-(2-butoxyethoxy)ethanol
≤10
No.
No.
No.
Yes.
No.
Name
%
Fire
hazard
Sudden
release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:613/16
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Section 15. Regulatory information
WARNING
: This product can expose you to Toluene, which is known to the State of California to cause birth defects or
other reproductive harm. For more information go to www.P65Warnings.ca.gov.
Toluene
No.
Yes.-Yes.
Ingredient name
Cancer
Reproductive
No significant risk
level
Maximum
acceptable dosage
level
California Prop. 65
Pennsylvania
:
The following components are listed: PROPANE; BENZENE, METHYL-;
2-PROPANONE; ETHANOL, 2-BUTOXY-; BUTANE; 9-OCTADECENOIC ACID (Z)-
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia
:
Not determined.
Canada
:
Not determined.
China
:
Not determined.
Europe
:
Not determined.
Japan
:
Japan inventory (ENCS)
: Not determined.
Japan inventory (ISHL)
: Not determined.
Republic of Korea
:
Not determined.
Malaysia
:
Not determined.
New Zealand
:
Not determined.
Philippines
:
Not determined.
Taiwan
:
Not determined.
Turkey
:
Not determined.
United States
:
Not determined.
Thailand
:
Not determined.
Viet Nam
:
Not determined.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
4
3
*
Health
Flammability
Physical hazards
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:614/16
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Section 16. Other information
4/30/2018
History
Date of printing
Date of issue/Date of
revision
Version
Notice to reader
Date of previous issue
:::
:
Indicates information that has changed from previously issued version.
References
:
Not available.
Key to abbreviations
:
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
4/30/2018
4/27/2018
6
043
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification
Justification
FLAMMABLE AEROSOLS - Category 1
Expert judgment
SKIN IRRITATION - Category 2
Expert judgment
EYE IRRITATION - Category 2A
Expert judgment
TOXIC TO REPRODUCTION (Unborn child) - Category 2
Expert judgment
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) Category 3
Expert judgment
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Expert judgment
ASPIRATION HAZARD - Category 1
Expert judgment
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:615/16
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Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue/Date of revision
:
4/30/2018
Date of previous issue
:
4/27/2018
Version
:616/16
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