BBJ Environmental B2201992 User Manual

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SAFETY DATA SHEET
Freshduct Odor Eliminator
Concentrate
BBJ Environmental Solutions
"The standard of care for indoor air"
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
1.1 Product identifier
Product Name: Freshduct Odor Eliminator (Concentrate) Product Codes(s):
EPA Registration No.: Synonyms:
REACH Registration Number:
substances in this product have been pre-registered according to Article 2 REACH Regulation (EC) No 1907/2006.
433-24; 445-01; 455-01
Not applicable
None known
Some materials in this product have been registered according to Regulation (EC) 1907/2006. The remaining
1.2 Relevant identified uses of the substance or mixture and uses advised against
General Use: Uses advised against:
Odor control for HVAC systems and air ducts
No uses advised against
1.3 Details of the supplier and of the safety data sheet
Manufacturer/Distributor
BBJ Environmental Solutions 6321 Pelican Creek Circle Riverview, FL 33578 USA
+1-813-622-8550; Toll free: +1-800-889-2251
1.4 Emergency telephone number: Chemtrec (24 hours) +1-800-424-9300
SECTION 2 - HAZARDS IDENTIFICATION
2.1 Classification of substance or mixture
Classification (REGULATION (EC) No 1272/2008)
Eye Irritant - Category 2B [H320]
2.2 Label Elements
Labeling (REGULATION (EC) No 1272/2008)
Hazard Symbols Signal Word: Hazard Statement(s): Precautionary Statements:
[Prevention] [Response]
None allocated Warning
H320 - Causes eye irritation
P264 - Wash hands thoroughly after handling. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical attention.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
Not applicable
3.2 Mixtures
Chemical characterization (preparation)
Proprietary mixture consisting of low toxicity ingredients. The identities of the components in this product are a trade secret (29 CFR 1910.1200(i))
and are available to the attending physician or paramedical personnel in case of emergency.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified
SECTION 4 - FIRST AID MEASURES
4.1 Description of first aid measures
Inhalation:
difficult or irregular, administer oxygen; if respiratory arrest occurs, start artificial respiration by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. If symptoms persist, seek medical attention immediately.
Eyes: Immediately flush eyes with large amounts of water for 15 minutes. Remove contact lenses, if present and easy to do, after the first 5 .
minutes and continue rinsing, occasionally lifting upper and lower lids. If irritation persists obtain medical attention, preferably from an ophthalmologist.
Skin:
clothing and shoes thoroughly before reuse. If irritation persists, seek prompt medical attention.
Ingestion:
medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Freshduct Odor Eliminator (Concentrate)
If product vapor or mist causes respiratory irritation or distress, move the exposed person to fresh air immediately. If breathing is
Flush skin with large amounts of water while removing contaminated clothing. Wash affected area with soap and water. Wash contaminated
Rinse mouth with water. If conscious and alert drink 2 - 4 cupfuls of milk or water. Do not induce vomiting unless directed to do so by
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4.2 Most important symptoms and effects, both acute and delayed
Potential health symptoms and effects
May cause transient eye irritation. May cause chemical conjunctivitis.
Eyes:
May cause mild skin irritation.
Skin: Inhalation: Ingestion: Chronic:
Inhalation of mist or spray may cause irritation of the respiratory system.
May cause gastrointestinal upset with nausea, vomiting and diarrhea.
No information available.
SECTION 5 - FIRE FIGHTING MEASURES
5.1 Extinguishable media
Suitable methods of extinction: Unsuitable methods of extinction:
5.2 Special hazards arising from the substance or mixture
Solutions containing glycol ethers in water can form flammable vapors with air if heated sufficiently. Closed containers may explode due to the build-up of pressure when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention.
5.3 Advice for firefighters
Full protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. If possible, firefighters should control run-off water to prevent environmental contamination.
Use extinguishing media appropriate for surrounding fire.
None known
SECTION 6 - ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Wear appropriate protective clothing designated in Section 8. Ventilate the area.
6.2 Environmental precautions
Avoid dispersal of spilled material or run-off and prevent contact with soil and entry into drains, sewers or waterways.
6.3 Methods and materials for containment and cleaning up
Cover drains and contain spill. Cover with a large quantity of inert absorbent. Shovel or sweep up product and into place into an approved container for proper disposal. Observe possible material restrictions (section 7.2 and 10.5). Clean contaminated area with soap and water.
6.4 Reference to other sections
For indications about waste treatment, see section 13.
SECTION 7 - HANDLING AND STORAGE
7.1 Precautions for safe handling
Observe label precautions. Wear all appropriate protective equipment specified in Section 8. Keep containers closed when not in use.
Advice on protection against fire and explosion
Keep away from heat, sparks and flame. Solutions containing glycol ethers in water can form flammable vapors with air if heated sufficiently.
7.2 Conditions for safe storage, including any incompatibilities
Store in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10.5), food and drink. Transfer only to approved containers having correct labeling. Protect container against physical damage. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Containers of this material may be hazardous when empty as they contain product residues. Use appropriate containment to avoid environmental contamination. Ventilate closed areas. Do not take internally. Keep out of reach of children.
7.3 Specific end uses
Apart from the uses mentioned in section 1.2, no other specific uses are stipulated.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Contains no substances with exposure limits
8.2 Exposure controls
Engineering Measures:
equipment. Use adequate ventilation. Local exhaust is preferable. Refer to See Section 7.1.
Individual protection measures:
selected specifically for the workplace, depending on concentrations and quantities of hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the representative supplier.
Hygiene measures:
clothing. Preventive skin protection is recommended. Wash hands thoroughly after use, before eating, drinking or using the lavatory.
Eye/face protection:
or European Standard EN 166.
Hand Protection:
chemicals and oil. Breakthrough time of selected gloves must be greater than the intended use period.
Other protective equipment:
Technical measures and appropriate working operations should be given priority over the use of personal protective
Wear protective clothing to prevent repeated or prolonged contact with product. Protective clothing needs to be
Facilities storing or using this material should be equipped with an eyewash station and safety shower. Change contaminated
Wear protective goggles or safety glasses with unperforated side shields during use. Refer to 29 CFR 1910.133, ANSI Z87.1
Wear gloves recommended by glove supplier for protection against materials in section 3. Gloves should be impermeable to
Protective clothing. Protective boots, if the situation requires.
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Respiratory Protection:
assessment shows air-purifying respirators are appropriate use a full-faced respirator with multi-purpose combination (US) or type ABEK
(EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Environmental exposure controls:
None required with normal use. Always use an approved respirator when vapor/aerosols are generated. Where risk
Do not empty into drains.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance Clear, colorless liquid Odor Scented (Clean Linen) Odor Threshold Not determined Molecular Weight Not applicable Chemical Formula Not applicable pH Freezing/Melting Point Initial Boiling Point Evaporation Rate Not determined Flammability (solid, gas) Not applicable Flash Point Not determined Autoignition Temperature Not determined Decomposition Temperature Not determined Lower Explosive Limit (LEL) Not determined Upper Explosive Limit (UEL) Not determined Vapor Pressure Vapor Density Not determined Specific Gravity Viscosity Not determined Solubility in Water Complete Partition Coefficient: n-octanol/water Not determined Volatiles by Volume @ 70º F >80%
9.2 Other data
No data available
4.75 - 4.85 @ 20 °C (68 °F)
-2 °C (28 °F)
110 °C (230 °F)
Not determined
1.005
SECTION 10 - STABILITY AND REACTIVITY
10.1 Reactivity
No special reactivity has been reported. Hazardous polymerization will not occur.
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
None known
10.4 Conditions to avoid
Extreme temperatures. Contact with incompatible materials.
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Thermal decomposition products may include carbon oxides, aldehydes, ketones, organic acids.
SECTION 11 - TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute Oral Toxicity
LD50 - Rat: >5,000 mg/kg
Acute inhalation toxicity
LC50 - Rat: >202.18 mg/l
Acute dermal toxicity
No data available
Skin irritation
May cause slight skin irritation.
Eye irritation
May cause transient eye irritation and conjunctivitis.
Sensitization
No data available
Genotoxicity in vitro
No data available
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Mutagenicity
No data available
Specific organ toxicity - single exposure
No data available
Specific organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
11.2 Further information
This material is not listed as a carcinogen by IARC, ACGIH, NTP or OSHA. No data is available regarding the mutagenicity and/or teratogenicity of this material in humans, nor is there available data that indicates that it causes adverse developmental and/or fertility effects in humans.
Handle in accordance with good industrial hygiene and safety practice.
SECTION 12 - ECOLOGICAL INFORMATION
12.1 Toxicity
Material is expected to have low toxicity to aquatic organisms.
12.2 Persistence and degradability
Material is expected to be biodegradable.
12.3 Bioaccumulation potential
Not expected to bioaccumulate
12.4 Mobility
Mobility in the soil is expected to be high.
12.5 Results of PBT and vPvB assessment
No data available
12.6 Other adverse effects
Additional ecological information
No data available
SECTION 13 - DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product Methods of disposal:
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Hazardous waste:
The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some
The classification of this product may meet the criteria for a hazardous waste.
SECTION 14 - TRANSPORT INFORMATION
Note:
Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United Nations TDG and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials and methods of shipping.
This material is not regulated for transport. Marine Pollutant:
This product is a not a marine pollutant.
SECTION 15 - REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for substance or mixture
U. S. Federal Regulations OSHA Hazard Communication Standard: OSHA Process Safety Management Standard: EPA Risk Management Planning Standard:
TSCA Status:
Superfund Amendments and Reauthorization Act (SARA)
SARA Section 311/312 Hazard Categories: SARA 313 Information:
the Emergency Planning and Community Right-to Know Act of 1986.
SARA 302/304 Extremely Hazardous Substance
No components of the product exceed the threshold (de minimis) reporting levels established by of these sections of Title III of SARA.
SARA 302/304 Emergency Planning & Notification:
No components of the product exceed the threshold (de minimis) reporting levels established by of these sections of Title III of SARA.
Comprehensive Response Compensation and Liability Act (CERCLA):
All components of this product are listed on the Toxic Substance Control Act (TSCA) Inventory.
None of the chemicals in this product exceed the threshold (de minimis) reporting levels established by Section 313 of
This material is classified as hazardous in accordance with OSHA 29 CRF 1910.1200.
Components of this product are not regulated under OSHA PSM Standard 29 CFR 1910.119.
Components of this product are not regulated under EPA RMP Standard (RMP) 40 CFR Part 68.
Acute Health Hazard
Contains no chemicals regulated under CERCLA.
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Clean Air Act (CAA)
This product does not contain any chemicals that are listed as Hazardous Air Pollutants (HAPs) designated in CAA Section 112 (b). This product does not contain any Class 1 Ozone depletors. This product does not contain any Class 2 Ozone depletors.
Clean Water Act (CWA)
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
U.S. State Regulations California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986:
This product contains no chemical(s) known to the state of California to cause cancer or other reproductive harm.
Other U.S. State Inventories
None of the substances in this product are listed on any State Hazardous Substance Inventories, Right-to-Know lists and/or Air Quality/Air Pollutants lists.
Canada
WHMIS Hazard Symbol and Classification:
Canadian Controlled Products Regulations (CPR):
None allocated
This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations, and the MSDS contains all the information required by the Controlled Products Regulations.
Canadian Ingredient Disclosure List (IDL): Canadian National Pollutant Release Inventory (NPRI):
Citric Acid (CAS #77-92-9) is listed on the IDL.
None of the ingredients in this product are listed on the NPRI.
European Economic Community
Labeling (67/548/EEC to 1999/45/EC):
Risk Phrases: Safety Phrases:
R36 - Irritating to eyes. S2 - Keep out of the reach of children.
None allocated
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK, Germany (Water danger/protection):
1
Global Chemical Inventory Lists
Country Canada:
Canada: Europe: United States: Australia: New Zealand:
China: Japan: Korea: Philippines:
Inventory Name
Domestic Substance List (DSL). Non-Domestic Substance List (NDSL). Inventory of New and Existing Chemicals (EINECS) Toxic Substance Control Act (TSCA)
Australian Inventory of Chemical Substances (AICS) New Zealand Inventory of Chemicals (NZIoC) Inventory of Existing Chemical Substances in China (IECSC) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) Philippines Inventory of Chemicals and Chemical Substances (PICCS)
Inventory Listing*
Yes
No Yes Yes Yes Yes Yes Yes Yes Yes
*"Yes" indicates that all components of this product are in compliance with the inventory requirements administered by the governing country. *"No" indicates that one or more components of this product are not on the inventory and are not exempt from listing.
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out.
SECTION 16 - OTHER INFORMATION
Hazardous Material Information System (HMIS)
Health Flammability
Physical Hazard
Personal Protection
BBJ Environmental Solutions assumes no legal responsibility or liability form the described product's use. All chemicals possess unknown potential hazards. The information herein should be used only to supplement the end user's existing knowledge. Read directions for proper use. This SDS was written for the product as packaged. Product may turn yellow, orange or brown if pH becomes alkaline; however, this should not affect the product's effectiveness. If frozen, crystals may remain in the container after thawing. Shake until dissolved before using. Cleaning Contractors shall comply with all applicable OSHA regulations.
Preparation Date: 31 October 2013
Freshduct Odor Eliminator (Concentrate)
1 1 0 C
S and NFPA Hazard Rating Legend
HMI
* = Chronic Health Hazard 0 = INSIGN IFICANT
1 = S LIGHT
2 = MODERATE 3 = HIGH
= EXTREME
4
National Fire Protection Association (NFPA)
Flammability
1
Health
1
Special
0
Instability
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