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Safety data sheet
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1. Product identifier
Ultrafuse TPU 85A
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use: 3D Printing
1.3. Details of the supplier of the safety data sheet
Company:
BASF 3D Printing Solutions B.V.
Eerste Bokslootweg 17
7821 AT Emmen, Netherlands
Telephone: +49 621 60-0
E-mail address: [email protected]
1.4. Emergency telephone number
International emergency number:
Telephone: +49 180 2273-112
SECTION 2: Hazards Identification
2.1. Classification of the substance or mixture
According to Regulation (EC) No 1272/2008 [CLP]
No need for classification according to GHS criteria for this product.
2.2. Label elements
Contact address:
BASF SE
67056 Ludwigshafen
GERMANY
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
Globally Harmonized System, EU (GHS)
The product does not require a hazard warning label in accordance with GHS criteria.
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2.3. Other hazards
According to Regulation (EC) No 1272/2008 [CLP]
No specific dangers known, if the regulations/notes for storage and handling are considered.
SECTION 3: Composition/Information on Ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Chemical nature
Polymer based on: polyurethane, stabilizing agents, additives
Hazardous ingredients (GHS)
according to Regulation (EC) No. 1272/2008
Does not contain any hazardous ingredients.
SECTION 4: First-Aid Measures
4.1. Description of first aid measures
Remove contaminated clothing.
If inhaled:
Remove the affected individual into fresh air and keep the person calm. Immediate medical attention
required.
On skin contact:
Burns caused by molten material require hospital treatment.
On contact with eyes:
In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. If
irritation develops, seek medical attention.
On ingestion:
Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical
attention.
Page 3
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
Page: 3/12
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: No significant reaction of the human body to the product known.
Hazards: No hazards anticipated.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
SECTION 5: Fire-Fighting Measures
5.1. Extinguishing media
Suitable extinguishing media:
water spray, foam, dry powder, carbon dioxide
Unsuitable extinguishing media for safety reasons:
water jet
5.2. Special hazards arising from the substance or mixture
Carbon dioxide, carbon monoxide, hydrogen cyanide, nitrogen oxides, isocyanate
The substances/groups of substances mentioned can be released in case of fire.
5.3. Advice for fire-fighters
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
SECTION 6: Accidental Release Measures
High risk of slipping due to leakage/spillage of product.
6.1. Personal precautions, protective equipment and emergency procedures
No special precautions necessary.
6.2. Environmental precautions
No special precautions necessary.
6.3. Methods and material for containment and cleaning up
For small amounts: Sweep/shovel up.
For large amounts: Sweep/shovel up.
6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
Page: 4/12
SECTION 7: Handling and Storage
7.1. Precautions for safe handling
Provide suitable exhaust ventilation at the drying process and in the area surrounding the melt outlet
of processing machines.
Protection against fire and explosion:
No special precautions necessary.
7.2. Conditions for safe storage, including any incompatibilities
Segregate from foods and animal feeds.
Suitable materials for containers: High density polyethylene (HDPE), Low density polyethylene
(LDPE), Paper/Fibreboard
Further information on storage conditions: Frost sensitive sensitive to heat Avoid deposition of dust.
Storage stability:
Protect against moisture.
7.3. Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.
SECTION 8: Exposure Controls/Personal Protection
8.1. Control parameters
Components with occupational exposure limits
The substances mentioned are contained only in traces in the product.
101-68-8: 4,4'-methylenediphenyl diisocyanate
PNEC
No PNEC value available.
DNEL
No DNEL value available.
8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Breathing protection if breathable aerosols/dust are formed.
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not applicable
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
Hand protection:
Chemical resistant protective gloves (EN 374)
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
General safety and hygiene measures
Wearing of closed work clothing is recommended. When using, do not eat, drink or smoke. Hands
and/or face should be washed before breaks and at the end of the shift. At the end of the shift the
skin should be cleaned and skin-care agents applied.
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SECTION 9: Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Form: filament
Colour: transparent to opaque
Odour: odourless
Odour threshold:
pH value:
not applicable
softening temperature: > 120 °C
boiling temperature:
The product is a non-volatile solid.
Flash point:
not applicable
Evaporation rate:
Value can be approximated from
Henry's Law Constant or vapor
pressure.
Flammability: not flammable (Directive 92/69/EEC, A.10)
Lower explosion limit:
For solids not relevant for
classification and labelling.
Upper explosion limit:
For solids not relevant for
classification and labelling.
Ignition temperature: > 400 °C
Vapour pressure:
not applicable
Relative density:
No data available.
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Corrosion to metals
: No corrosive effect on metal.
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
Relative vapour density (air):
not applicable
Solubility in water: insoluble
Partitioning coefficient n-octanol/water (log Kow):
not applicable
Thermal decomposition: No decomposition if stored and handled as prescribed/indicated.
> 230 °C
Thermal decomposition above the indicated temperature is possible.
Prolonged thermal loading can result in products of degradation being
given off.
Viscosity, dynamic:
not applicable
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating
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9.2. Other information
Self heating ability: It is not a substance capable of
spontaneous heating.
Bulk density: 500 - 700 kg/m3
(20 °C)
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.
SECTION 10: Stability and Reactivity
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions
No hazardous reactions when stored and handled according to instructions.
10.4. Conditions to avoid
No conditions to avoid anticipated.
10.5. Incompatible materials
Substances to avoid:
No substances known that should be avoided.
10.6. Hazardous decomposition products
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
Hazardous decomposition products:
Gaseous products of degradation can be given off if the product is greatly overheated.
Possible thermal decomposition products:
carbon monoxide, Carbon dioxide, hydrogen cyanide
isocyanates, nitrogen oxides
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SECTION 11: Toxicological Information
11.1. Information on toxicological effects
Acute toxicity
Assessment of acute toxicity:
Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation. Virtually nontoxic after a
single ingestion.
Experimental/calculated data:
LD50 rat (oral): > 5,000 mg/kg
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.
Irritation
Assessment of irritating effects:
Not irritating to the eyes. Not irritating to the skin. The product has not been tested. The statement
has been derived from substances/products of a similar structure or composition.
Respiratory/Skin sensitization
Assessment of sensitization:
The chemical structure does not suggest a sensitizing effect.
Germ cell mutagenicity
Assessment of mutagenicity:
The chemical structure does not suggest a specific alert for such an effect.
Carcinogenicity
Assessment of carcinogenicity:
The chemical structure does not suggest a specific alert for such an effect.
Reproductive toxicity
Assessment of reproduction toxicity:
The chemical structure does not suggest a specific alert for such an effect.
Developmental toxicity
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
Assessment of teratogenicity:
The chemical structure does not suggest a specific alert for such an effect.
Specific target organ toxicity (single exposure)
Assessment of STOT single:
Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:
Repeated dermal uptake of the substance did not cause substance-related effects. Repeated
inhalative uptake of the substance did not cause substance-related effects. Repeated oral uptake of
the substance did not cause substance-related effects.
Aspiration hazard
No aspiration hazard expected.
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SECTION 12: Ecological Information
12.1. Toxicity
Assessment of aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms.
12.2. Persistence and degradability
Assessment biodegradation and elimination (H2O):
Poorly biodegradable.
Elimination information:
Poorly biodegradable.
12.3. Bioaccumulative potential
Assessment bioaccumulation potential:
Does not significantly accumulate in organisms.
12.4. Mobility in soil
Assessment transport between environmental compartments:
Adsorption in soil: Due to the product characteristics the test is impossible.
12.5. Results of PBT and vPvB assessment
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): The product does not contain a substance
fulfilling the PBT (persistent/bioaccumulative/toxic) criteria.
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12.6. Other adverse effects
The product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on
substances that deplete the ozone layer.
12.7. Additional information
Adsorbable organically-bound halogen (AOX):
This product contains no organically-bound halogen.
SECTION 13: Disposal Considerations
13.1. Waste treatment methods
Observe national and local legal requirements.
Waste key:
07 02 13 waste plastic
Contaminated packaging:
Completely emptied packagings can be given for recycling.
SECTION 14: Transport Information
Land transport
ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for
user
RID
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
None known
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
Environmental hazards: Not applicable
Special precautions for
user
Inland waterway transport
ADN
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for
user:
Transport in inland waterway vessel
Not evaluated
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for
user
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for
user
None known
None known
None known
None known
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Page 11
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
Page: 11/12
14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.
14.2. UN proper shipping name
See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.
14.3. Transport hazard class(es)
See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.
14.4. Packing group
See corresponding entries for “Packing group” for the respective regulations in the tables above.
14.5. Environmental hazards
See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.
14.6. Special precautions for user
See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
SECTION 15: Regulatory Information
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Prohibitions, Restrictions and Authorizations
If it is intended to use materials for the manufacture of consumer goods (e. g. products which will
come into contact with foodstuffs or with the skin, toys) or medical products, national and
international regulations have to be observed. Where no regulations exist, consumer goods or
medical products must at least comply with European legislation. We recommend contacting our
Sales and our Product Safety departments.
15.2. Chemical Safety Assessment
Product is not classified as hazardous.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 08.11.2018 Version: 1.1
Product: Ultrafuse TPU 85A
(ID no. 933777/SDS_GEN_EU/EN)
Date of print 27.09.2019
Page: 12/12
SECTION 16: Other Information
Any other intended applications should be discussed with the manufacturer. Corresponding
occupational protection measurements must be followed.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.
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