BASF ULTRAFUSE BASFU 0108 Datasheet

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Safety data sheet
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BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 14.11.2019 Version: 6.0 Product: Ultrafuse ABS
Date of print 17.11.2019

1. Identification

Product identifier
Ultrafuse ABS
Recommended use: 3D Printing, for industrial use only
Details of the supplier of the safety data sheet
Company: BASF 3D Printing Solutions B.V. Eerste Bokslootweg 17 7821 AT Emmen, Netherlands
Telephone: + 31 591 820 389 E-mail address: sales@basf-3dps.com
Emergency telephone number
National Poisoning Information Centre: +31 30 – 2748888 Information only for professionals in case of acute intoxication International emergency number: Telephone: +49 180 2273-112

2. Hazards Identification

Classification of the substance or mixture
According to UN GHS criteria No need for classification according to GHS criteria for this product.
Label elements
Globally Harmonized System (GHS)
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BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 14.11.2019 Version: 6.0 Product: Ultrafuse ABS
Date of print 17.11.2019
The product does not require a hazard warning label in accordance with GHS criteria.
Other hazards
According to UN GHS criteria If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.

3. Composition/Information on Ingredients

Substances
Not applicable
Mixtures
Chemical nature Polymer Hazardous ingredients (GHS)
According to UN GHS criteria No particular hazards known.

4. First-Aid Measures

Description of first aid measures
Remove contaminated clothing. If inhaled:
Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. If symptoms persist, seek medical advice.
On skin contact: Wash thoroughly with soap and water. Burns caused by molten material require hospital treatment. If irritation develops, seek medical attention.
On contact with eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. If irritation develops, seek medical attention.
On ingestion: Rinse mouth and then drink 200-300 ml of water. Do not induce vomiting. Seek medical attention.
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BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 14.11.2019 Version: 6.0 Product: Ultrafuse ABS
Date of print 17.11.2019
Most important symptoms and effects, both acute and delayed
Symptoms: (Further) symptoms and / or effects are not known so far Hazards: No hazard is expected under intended use and appropriate handling.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

5. Fire-Fighting Measures

Extinguishing media
Suitable extinguishing media: water spray, foam, dry powder
Special hazards arising from the substance or mixture
fumes/smoke, carbon oxides, nitrogen oxides
Advice for fire-fighters
Special protective equipment: Wear a self-contained breathing apparatus.
Further information: Dusty conditions may ignite explosively in the presence of an ignition source causing flash fire.

6. Accidental Release Measures

Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Avoid the formation and build-up of dust - danger of dust explosion. Dust in sufficient concentration can result in an explosive mixture in air. Handle to minimize dusting and eliminate open flame and other sources of ignition.
Personal precautions, protective equipment and emergency procedures
No special precautions necessary.
Environmental precautions
Do not allow to enter soil, waterways or waste water channels.
Methods and material for containment and cleaning up
For small amounts: Sweep/shovel up. For large amounts: Sweep/shovel up. Vacuum up spilled product. Reclaim for processing if possible. Ensure adequate ventilation. Avoid raising dust. After decontamination, spill area can be washed with water.
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BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 14.11.2019 Version: 6.0 Product: Ultrafuse ABS
Date of print 17.11.2019

7. Handling and Storage

Precautions for safe handling
Avoid inhalation of dusts/mists/vapours. Ensure adequate ventilation. Provide suitable exhaust ventilation at drying process and in the surrounding of processing machines. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. Avoid the formation and deposition of dust.
Protection against fire and explosion: Avoid dust formation. Dust in sufficient concentration can result in an explosive mixture in air. Handle to minimize dusting and eliminate open flame and other sources of ignition. Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed. Avoid extreme heat. Avoid all sources of ignition: heat, sparks, open flame.
Storage stability: Avoid prolonged storage.

8. Exposure Controls/Personal Protection

Control parameters
Components with occupational exposure limits
100-42-5: Styrene
107-13-1: Acrylonitrile
Exposure controls
Personal protective equipment Respiratory protection:
Breathing protection if breathable aerosols/dust are formed. Wear respiratory protection if ventilation is inadequate. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection: Wear chemical resistant protective gloves.
Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection: Standard work clothes and shoes.
General safety and hygiene measures Wear protective clothing to prevent contact during mechanical processing and/or hot melt conditions. After use of gloves apply skin-cleaning agents and skin cosmetics.
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BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 14.11.2019 Version: 6.0 Product: Ultrafuse ABS
Date of print 17.11.2019

9. Physical and Chemical Properties

Information on basic physical and chemical properties
Form: filament
Colour: various, depending on the colourant
Odour: odourless
Odour threshold:
not applicable, odour not perceivable
pH value:
not determined
Melting point:
not determined
Boiling point:
not applicable
Flash point:
not applicable
Evaporation rate:
The product is a non-volatile solid.
Flammability: not flammable
Lower explosion limit:
For solids not relevant for classification and labelling.
Upper explosion limit:
For solids not relevant for classification and labelling.
Ignition temperature:
not determined
Vapour pressure:
not applicable
Relative density: 1,05 - 1,07
(25 °C)
Relative vapour density (air):
not applicable
Solubility in water: negligible
Partitioning coefficient n-octanol/water (log Kow):
not applicable for mixtures
Self ignition: not self-igniting Thermal decomposition: > 300 °C
Viscosity, dynamic:
not applicable, the product is a solid
Viscosity, kinematic:
not applicable, the product is a solid
Fire promoting properties: not fire-propagating
Other information
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BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 14.11.2019 Version: 6.0 Product: Ultrafuse ABS
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Self heating ability: It is not a substance capable of
spontaneous heating.
Radioactivity: not radioactive for transport purposes

10. Stability and Reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal.
Chemical stability
Stable under normal conditions.
Possibility of hazardous reactions
The product is stable if stored and handled as prescribed/indicated.
Conditions to avoid
Temperature: > 300 °C Prolonged exposure to elevated temperatures may result in exothermic decomposition accompanied by a pressure build-up in sealed containers. Avoid all sources of ignition: heat, sparks, open flame.
Incompatible materials
Substances to avoid: oxidizing agents
Hazardous decomposition products
Hazardous decomposition products: Acrylonitrile, Styrene monomers, gases/vapours, oxides, hydrocarbons

11. Toxicological Information

Information on toxicological effects
Acute toxicity Assessment of acute toxicity:
Contact with molten product may cause thermal burns. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation. Virtually nontoxic after a single ingestion. The product has not been tested. The statement has been derived from the properties of the individual components.
Irritation
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BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 14.11.2019 Version: 6.0 Product: Ultrafuse ABS
Date of print 17.11.2019
Assessment of irritating effects: May cause slight irritation to the skin. May cause slight irritation to the eyes. May cause slight irritation to the respiratory tract.
Respiratory/Skin sensitization Assessment of sensitization:
A sensitizing effect on particularly sensitive individuals cannot be excluded. Germ cell mutagenicity Assessment of mutagenicity:
Not classified, due to lack of data. Carcinogenicity Assessment of carcinogenicity:
Not classified, due to lack of data. Reproductive toxicity Assessment of reproduction toxicity:
Not classified, due to lack of data. Developmental toxicity Assessment of teratogenicity:
Not classified, due to lack of data. Specific target organ toxicity (single exposure) Assessment of STOT single:
Based on available Data, the classification criteria are not met.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity:
The information available on the product provides no indication of toxicity on target organs after repeated exposure.
Aspiration hazard No aspiration hazard expected.
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BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 14.11.2019 Version: 6.0 Product: Ultrafuse ABS
Date of print 17.11.2019

12. Ecological Information

Toxicity
Assessment of aquatic toxicity: The product has not been tested. The statement has been derived from the structure of the product. There is a high probability that the product is not acutely harmful to aquatic organisms.
Persistence and degradability
Assessment biodegradation and elimination (H2O): Experience shows this product to be inert and non-degradable.
Bioaccumulative potential
Bioaccumulation potential: The product will not be readily bioavailable due to its consistency and insolubility in water.
Mobility in soil
Assessment transport between environmental compartments: Adsorption in soil: Adsorption to solid soil phase is possible.
Results of PBT and vPvB assessment
The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative).
Other adverse effects
No data available.
Additional information
Other ecotoxicological advice:
The product has been assessed on the basis of the components’ available data. To some extent
data gaps exist for individual components.

13. Disposal Considerations

Waste treatment methods
Must be disposed of or incinerated in accordance with local regulations. A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to
dependence on the usage.
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BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 14.11.2019 Version: 6.0 Product: Ultrafuse ABS
Date of print 17.11.2019
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging: Packs that cannot be cleaned should be disposed of in the same manner as the contents. Uncontaminated packaging can be re-used.

14. Transport Information

Land transport
ADR
Not classified as a dangerous good under transport regulations
UN number:
Not applicable
UN proper shipping name:
Not applicable
Transport hazard class(es):
Not applicable
Packing group:
Not applicable
Environmental hazards:
Not applicable
Special precautions for user
None known
RID
Not classified as a dangerous good under transport regulations
UN number:
Not applicable
UN proper shipping name:
Not applicable
Transport hazard class(es):
Not applicable
Packing group:
Not applicable
Environmental hazards:
Not applicable
Special precautions for user
None known
Inland waterway transport
ADN
Not classified as a dangerous good under transport regulations
UN number:
Not applicable
UN proper shipping name:
Not applicable
Transport hazard class(es):
Not applicable
Packing group:
Not applicable
Environmental hazards:
Not applicable
Special precautions for user:
None known
Transport in inland waterway vessel Not evaluated
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BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 14.11.2019 Version: 6.0 Product: Ultrafuse ABS
Date of print 17.11.2019
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
UN number:
Not applicable
UN proper shipping name:
Not applicable
Transport hazard class(es):
Not applicable
Packing group:
Not applicable
Environmental hazards:
Not applicable
Special precautions for user
None known
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number:
Not applicable
UN proper shipping name:
Not applicable
Transport hazard class(es):
Not applicable
Packing group:
Not applicable
Environmental hazards:
Not applicable
Special precautions for user
None known
Transport in bulk according to Annex II of MARPOL and the IBC Code
Regulation:
Not evaluated
Shipment approved:
Not evaluated
Pollution name:
Not evaluated
Pollution category:
Not evaluated
Ship Type:
Not evaluated

15. Regulatory Information

Safety, health and environmental regulations/legislation specific for the substance or mixture
Not applicable

16. Other Information

The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a
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BASF Safety data sheet according to UN GHS 4th rev. Date / Revised: 14.11.2019 Version: 6.0 Product: Ultrafuse ABS
Date of print 17.11.2019
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.
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