1
Z
38.0.4
*
1 Identi cation
·
Product identi
·
Product name:
·
Product status:
·
Product
· Relevant
·
Application
·
Details
· Manufacturer/Supplier:
Perstorp Specialty
SE-284 80 Perstorp, Sweden
Tel. +46 435
Fax +46 435 38100
www.perstorp.com
Bare Ground
PO Box 3477
Framingham, MA 01705
888-800-8356
·
·
Emergency telephone
*
2
Hazard(s)
·
Classi
This chemical is
CFR
The
·
Label elements
·
Hazard pictograms Not applicable
·
S
upplementary
·
Hazards
·
Unknown acute tox
·
Classi
· NFPA ratings (scale 0
·
HMIS-ratings (scale 0
HEALT
FIRE
REACTIVITY
·
Other hazards
· Results
·
PBT: No.
identi
identi
ed uses
of the substance
of the supplier
38000
identi cation
ation of the substance
1910.1200).
product
not
cation system:
1 0
H
of
is
not
hazard
otherwise
Health
Fire
Reactivity = 0
1
Health
1
Fire
Reactivity = 0
0
PBT and vPvB assessment
Safety Data Sheet
acc.
to
OSHA HCS
Version: 2
Sodium Formate Deicer
of the substance
/ the mixture
of the safety data sheet
Chemicals A
B
number: 1 866 519 4752 (Contract No. :
or mixture
not
considered hazardous
classi ed according
information Not applicable
classi ed (HNOC)
icity: 1%
- 4)
= 1
= 1
- 4)
= 1
= 1
or
mixture and
Deicing
by th e
2012 OSHA Hazard Communication Standard (29
to the
Globally Harmonized System (GHS).
May be harmful
uses advised against
agent
334101)
if swallowed.
Reviewe
Page
1/8
d on 01/27/2016
(Contd.
on
page
2)
USA
Page 2
Safety Data
Sheet
acc. to OSHA HCS
Version: 2
01/27/2016
Reviewed on 01/27/2016
·
Chemical components:
141-53-7
sodium formate
> 98%
Product name:
·
vPvB: No.
3
38.0.4
Composition/information
·
Chemical characterization: Mixtures Yes.
4 First-aid measures
·
Description of first aid measures
·
After inhalation: First aid measures not required, but get fresh air for personal comfort.
·
After skin contact:
First aid measures not required, but wash exposed skin with soap and water for hygienic reasons.
·
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
Rinse mouth with water.
If a large quantity has been ingested or you feel unwell, get medical advice/attention.
·
Most important symptoms and effects, both acute and delayed
No further relevant information available.
·
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
·
Extinguishing media
·
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
·
For safety reasons unsuitable extinguishing agents: Water with full jet
·
Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
·
Advice for firefighters
·
Protective equipment:
Fire-fighters should wear appropriate protectiv e equipment and selfcontained breathing apparatus
(SCBA) with a full face-piece operated in positive pressure mode.
6 Accidental release measures
·
Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
If dusty conditions wear respiratory protective device with dust filter, gloves and protective clothing for
hygienic reasons.
·
Environmental precautions: Do not allow to enter sewers/ surface or ground water.
·
Methods and material for containment and cleaning up:
Pick up mechanically.
Cover to prevent dust formation.
Clean the affected area carefully; suitable cleaners are:
Sodium Formate Deicer
on ingredients
(Contd. of page 1)
(Contd. on page 3)
USA
Page 3
Safety Data
Sheet
acc. to OSHA HCS
Version: 2
01/27/2016
Reviewed on 01/27/2016
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
·
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Product name:
Sodium Formate Deicer
water
·
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
·
Precautions for safe handling
Wear personal protective equipment according to section 8 if risk of exposure.
Ensure good ventilation/exhaustion at the workplace.
·
Information about protection against explosions and fires: Not applicable
·
Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Store in cool, dry place in tightly closed receptacles.
·
Further information about storage conditions: This product is hygroscopic.
·
Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
·
Control parameters
·
Components with limit values that require monitoring at the workplace:
PARTICULATES NOT OTHERWISE REGULATED TOTAL DUST;
OSHA Z-1 PEL is: 15 mg/m3.
PARTICULATES NOT OTHERWISE REGULATED RESPIRABLE FRACTION;
OSHA Z-1 PEL is: 5 mg/m3.
·
Additional information:
(Contd. of page 2)
·
Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
·
Breathing equipment:
Wear respiratory device with dust filter (minimum N95) in case of insufficient ventilation.
·
Protection of hands:
Protective gloves
S
38.0.4
·
Material of gloves
Chloroprene rubber, CR
Nitrile rubber, NBR
(Contd. on page 4)
USA
Page 4
Safety Data
Sheet
acc. to OSHA HCS
Version: 2
01/27/2016
Reviewed on 01/27/2016
·
Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form: Granulate
Color: White
·
Odor: Odorless
·
Change in condition
Melting point/Melting range: 253-255 °C
(487-491 °F)
Boiling point/Boiling range: Decomposes.
·
Flash point: Not applicable.
·
Flammability (solid, gaseous): The product is not flammable.
·
Danger of explosion: Not explosive.
·
Explosion limits: Not applicable
·
Oxidizing properties Not oxidizing.
·
Vapor pressure: Not applicable.
·
Density: 850-950 g/l
·
Solubility in / Miscibility with
Water: Easily soluble.
·
Segregation coefficient (n-octanol/water): See section 12.
·
Viscosity:
Dynamic: Not applicable.
·
Other information No further relevant information available.
Product name:
Sodium Formate Deicer
(Contd. of page 3)
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
·
Penetration time of glove material
The exact breakthrough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
·
Eye protection:
R
Safety glasses
·
Body protection: Normal work clothes for the chemical industry (long legs and sleeves).
·
Limitation and supervision of exposure into the environment Not required.
·
Risk management measures Not applicable
*
9 Physical and chemical properties
38.0.4
10 Stability and reactivity
·
Reactivity
There exists no specific test data for this product. For further information, see the subsequent
subsections of this chapter.
·
Chemical stability The product is stable at normal conditions.
(Contd. on page 5)
USA
Page 5
Safety Data
Sheet
acc. to OSHA HCS
Version: 2
01/27/2016
Reviewed on 01/27/2016
·
LD/LC50 values:
141-53-7 sodium formate
Oral
Dermal
Inhalative
LD50
LD50
LC0(4h)
3000 mg/kg (rat)
>2000 mg/kg (rat) (OECD 402)
>0.67 mg/m³ (rat) (EPA OTS 798.1150)
141-53-7 sodium formate
Oral
NOAEL/104 weeks
2000* mg/kg bw/day (rat) (OECD 453)
141-53-7 sodium formate
Oral
NOAEL Development
NOAEL Fertility
1000 mg/kg bw/day (rat) (OECD 414)
1000 mg/kg bw/day (rat) (OECD 416)
Product name:
Sodium Formate Deicer
·
Possibility of hazardous reactions No dangerous reactions known.
·
Conditions to avoid None known.
·
Incompatible materials: None known.
·
Hazardous decomposition products: No dangerous decomposition products known.
11 Toxicological information
·
Information on toxicological effects
·
Acute to xicity:
(Contd. of page 4)
·
Remark: The maximal attainable dust concentration of 0.67 mg/l produced no signs of toxicity.
·
Primary irritant effect:
·
on the skin: No irritating effect.
·
on the eye: No irritating effect.
·
Sensitization No skin sensitization. (OECD 406)*
·
Carcinogenicity:
Animal studies have not shown any carcinogenic potential. *
·
Mutagenicity:
The product is not considered to be mutagenic.
In vitro:
Not mutagenic in Bacterial Reverse Mutation Assay. (OECD 471)
Not mutagenic in mammalian cells. (OECD 476)*
The product is not clastogenic. Mammalian Chromosomal Aberration Test (OECD 473).*
In vivo:
Did not induce mutations in the Drosophila SLRL test in vivo. (OECD 477)
·
Reproductive toxicity:
No impairment of fertility has been observed.
No embryotoxic or teratogenic effects have been observed.
·
Remark: * read-across from supporting substance (structural analogue)
12 Ecological
·
Toxicity
·
Aquatic toxicity:
information
Low toxicity to aquatic organisms.
141-53-7 sodium formate
EC50/48h > 1000 mg/l (Daphnia magna) (EPA-660/3-75-009)
EC50/72h > 1000* mg/l (Pseudokirchnerella subcapitata)
LC50/96h > 1000 mg/l (Oncorhynchus mykiss) (EPA OTS 797.1400)
38.0.4
(Contd. on page 6)
USA
Page 6
Safety Data
Sheet
acc. to OSHA HCS
Version: 2
01/27/2016
Reviewed on 01/27/2016
·
UN Number
·
DOT, ADR, ADN, IMDG, IATA -
·
Proper shipping name (Technical Name)
·
DOT, ADN, IMDG, IATA -
·
ADR -
·
Transport hazard class(es)
·
DOT, ADR, ADN, IMDG, IATA
·
Class -
·
Packing group
·
DOT, ADR, IMDG, IATA -
·
Environmental hazards: Not applicable.
·
Special precautions for user Not applicable.
·
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Product name:
Sodium Formate Deicer
·
Persistence and degradability
The product is readily biodegradable.
141-53-7 sodium formate
BOD28 86 % (bacteria) (OECD 306)
·
Bioaccumulative potential
Does not accumulate in organisms
141-53-7 sodium formate
log Pow <-1.8 (-) (OECD 107)
·
Mobility in soil
The product is not expected to adsorb to a high degree to suspended solids and sediment based upon
the log Pow.
·
Results of PBT and vPvB assessment
·
PBT: No.
·
vPvB: No.
·
Other adverse effects No further relevant information available.
·
Remark: * read-across from supporting substance (structural analogue)
13 Disposal considerations
·
Waste treatment methods The product is not classified as hazardous waste.
·
Recommendation: Disposal must be made according to official regulations.
·
Uncleaned packagings:
Thoroughly emptied and clean packagings may be recycled.
Contaminated packaging materials must be disposed of in the same manner as the product.
·
Recommendation: Disposal must be made according to official regulations.
14 Transport information
(Contd. of page 5)
38.0.4
(Contd. on page 7)
USA
Page 7
Safety Data
Sheet
acc. to OSHA HCS
Version: 2
01/27/2016
Reviewed on 01/27/2016
·
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
·
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
·
EPA (Environmental Protection Agency)
Not listed.
·
IARC (International Agency for Research on Cancer)
Not listed.
·
NTP (National Toxicology Program)
Not listed.
·
Australian Inventory of Chemical Substances (AICS)
All ingredients are listed.
·
Canadian Domestic Substance List (DSL)
All ingredients are listed.
·
Canadian Non Domestic Substance List (NDSL)
Not listed.
·
Chinese Chemical Inventory of Existing Chemical Substances (CIECS)
All ingredients are listed.
·
European EINECS/ELINCS Listing
All ingredients are listed.
·
Korea Existing Chemical Inventory (KECI)
All ingredients are listed.
·
Philippines Inventory of Chemicals and Chemical Substances (PICCS)
All ingredients are listed.
·
TSCA listing
All ingredients are listed.
·
Chemicals known to cause cancer:
Not listed.
·
Chemicals known to cause reproductive toxicity for females:
Not listed.
·
Chemicals known to cause reproductive toxicity for males:
Not listed.
Product name:
Sodium Formate Deicer
·
Transport/Additional information: Not dangerous according to the above specifications.
*
15 Regulatory information
·
Sara
·
Carcinogenic categories
(Contd. of page 6)
·
Inventory status:
·
Other regulations, limitations and prohibitive regulations Not applicable
·
State of California, Proposition 65:
38.0.4
(Contd. on page 8)
USA
Page 8
Safety Data
Sheet
acc. to OSHA HCS
Version: 2
01/27/2016
Reviewed on 01/27/2016
Product name:
·
Chemicals known to cause developmental toxicity:
Not listed.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
·
·
* Data compared to the previous version altered.
38.0.4
Sodium Formate Deicer
(Contd. of page 7)
USA
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