SAFETY DATA SHEET
Issuing Date 11-Jan-2017
Revision Date 26-Jan-2017
Revision Number 3
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The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name
calcium chloride pellets Winter CaCL
UPC: 636676382548
Other means of identification
Synonyms
None
Recommended use of the chemical and restrictions on use
Recommended Use
Ice Control
Uses advised against
No information available
Details of the supplier of the safety data sheet
Supplier Name
E. Brookmyer, Inc. d/b/a Bare Ground Systems
Supplier Address
PO Box 3477
Framingham
MA
01705
US
Supplier Phone Number
Phone:9784399862
Fax:9784399868
Supplier Email
EBrookmyer@gmail.com
Emergency telephone number
Company Emergency Phone
Number
6178773101
2. HAZARDS IDENTIFICATION
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Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Acute toxicity - Oral
Category 4
Serious eye damage/eye irritation
Category 2A
GHS Label elements, including precautionary statements
Emergency Overview
Signal word
Warning
Hazard Statements
Harmful if swallowed
Causes serious eye irritation
.
Appearance White
Physical state Pellets Solid
Odor None
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Wear eye/face protection
Precautionary Statements - Response
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Precautionary Statements - Storage
None
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
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Not applicable
Unknown Toxicity
0 % of the mixture consists of ingredient(s) of unknown toxicity
Other information
No information available
Interactions with Other Chemicals
No information available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical name
CAS No
Weight-%
Trade Secret
Calcium chloride
10043-52-4
60 - 100
*
*The exact percentage (concentration) of composition has been withheld as a trade secret
4. FIRST AID MEASURES
First aid measures
General Advice
Show this safety data sheet to the doctor in attendance.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open
while rinsing. Do not rub affected area. Get medical attention if irritation develops and
persists.
Skin contact
Wash with soap and water.
Inhalation
Remove to fresh air.
Ingestion
Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an
unconscious person. Do NOT induce vomiting. Call a physician.
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Effects
Burning sensation.
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Treat symptomatically.
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the chemical
No information available.
Uniform Fire Code
Irritant: Solid
Explosion Data
Sensitivity to Mechanical Impact
None.
Sensitivity to Static Discharge
None.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Other Information
Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental precautions
See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up
Methods for containment
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Pick up and transfer to properly labeled containers.
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7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product.
Conditions for safe storage, including any incompatibilities
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach
of children.
Incompatible Products
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies
Appropriate engineering controls
Engineering Measures
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin and body protection
Wear protective gloves and protective clothing.
Respiratory protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or
smoke when using this product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical state
Pellets, Solid
Appearance
White
Odor
None
Color
No information available
Odor Threshold
Not applicable
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Property
Values
Remarks Method
pH
No data available
None known
Melting / freezing point
No data available
None known
Boiling point / boiling range
No data available
None known
Flash Point
No data available
None known
Evaporation Rate
No data available
None known
Flammability (solid, gas)
No data available
None known
Flammability Limit in Air
Upper flammability limit
No data available
Lower flammability limit
No data available
Vapor pressure
No data available
None known
Vapor density
No data available
None known
Specific Gravity
No data available
None known
Water Solubility
Soluble in water
None known
Solubility in other solvents
No data available
None known
Partition coefficient: n-octanol/water
N/A
None known
Autoignition temperature
No data available
None known
Decomposition temperature
No data available
None known
Kinematic viscosity
No data available
None known
Dynamic viscosity
0 None known
Explosive properties
No data available
Oxidizing properties
No data available
Other Information
Softening Point
No data available
VOC Content (%)
No data available
Particle Size
No data available
Particle Size Distribution
10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
None known based on information supplied.
Incompatible materials
None known based on information supplied.
Hazardous Decomposition Products
None known based on information supplied.
11. TOXICOLOGICAL INFORMATION
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Information on likely routes of exposure
Product Information
.
Inhalation
Specific test data for the substance or mixture is not available. May cause irritation of
respiratory tract.
Eye contact
Specific test data for the substance or mixture is not available. Causes serious eye
irritation. (based on components). May cause redness, itching, and pain.
Skin contact
Specific test data for the substance or mixture is not available. May cause irritation.
Prolonged contact may cause redness and irritation.
Ingestion
Specific test data for the substance or mixture is not available. Ingestion may cause
irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhea. Harmful if swallowed. (based on components).
Component Information
Chemical name
Oral LD50
Dermal LD50
Inhalation LC50
Calcium chloride
10043-52-4
= 1000 mg/kg ( Rat )
> 5000 mg/kg ( Rabbit )
-
Information on toxicological effects
Symptoms
May cause redness and tearing of the eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
No information available.
Mutagenic Effects
No information available.
Carcinogenicity
Contains no ingredient listed as a carcinogen.
Reproductive toxicity
No information available.
STOT - single exposure
No information available.
STOT - repeated exposure
No information available.
Chronic Toxicity
No known effect based on information supplied.
Target Organ Effects
Eyes. Blood.
Aspiration Hazard
No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
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ATEmix (oral)
1,038.00 mg/kg
ATEmix (inhalation-dust/mist)
37.50 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicity
The environmental impact of this product has not been fully investigated.
Chemical name
Toxicity to Algae
Toxicity to Fish
Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
Calcium chloride
10043-52-4
96h LC50: = 10650 mg/L
(Lepomis macrochirus)
48h LC50: = 2400 mg/L
Persistence and Degradability
No information available.
Bioaccumulation
No information available
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal methods
This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.
Contaminated Packaging
Dispose of contents/containers in accordance with local regulations.
California Hazardous Waste Codes
141
14. TRANSPORT INFORMATION
DOT
NOT REGULATED
Proper Shipping Name
NON REGULATED
Hazard Class
N/A
TDG
Not regulated
MEX
Not regulated
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ICAO
Not regulated
IATA
Not regulated
Proper Shipping Name
NON REGULATED
Hazard Class
N/A
IMDG/IMO
Not regulated
Hazard Class
N/A
RID
Not regulated
ADR
Not regulated
ADN
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA
Not determined
DSL
Not determined
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard
Yes
Chronic Health Hazard
No
Fire Hazard
No
Sudden release of pressure hazard
No
Reactive Hazard
No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
This product does not contain any substances regulated by state right-to-know regulations.
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International Regulations
Canada
WHMIS Hazard Class
Not determined
16. OTHER INFORMATION
NFPA
Health Hazards 2
Flammability 0
Instability 0
Physical and
Chemical Hazards -
HMIS
Health Hazards 2
Flammability 0
Physical Hazard 0
Personal Protection
X
Prepared By
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Issuing Date
11-Jan-2017
Revision Date
26-Jan-2017
Revision Note
No information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
End of Safety Data Sheet
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