Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
revision 03.09.2020 (GB) Version 4.7
Robla Solo Mil-Laufreiniger
! SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Name of product
Robla Solo Mil-Laufreiniger
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended intended purpose(s)
Muzzle cleaner
1.3. Details of the supplier of the safety data sheet
Manufacturer
F.W.Klever
Hauptstraße 20, D-84168 Aham
Phone +49 (0) 8744 96 99 10, Fax + 49 (0) 8744 96 99 96
E-Mail info@ballistol.de
Internet www.ballistol.de
Advice
Qualitätssicherung
Phone +49 (0) 8744 96 99 30
E-mail (competent person):
info@ballistol.de
1.4. Emergency telephone number
Emergency advice
Dr.Zettler (Werktags von 8.00 Uhr bis 16.00 Uhr) oder
Giftnotrufzentrale 022819240
Phone +49 (0) 8744 96 99 30
! SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]
Hazard classes and Hazard
categories
Met. Corr. 1 H290
Skin Corr. 1B H314
Eye Dam. 1 H318
STOT SE 3 H335
Hazard statements for physical hazards
H290 May be corrosive to metals.
!
Hazard statements for health hazards
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.
2.2. Label elements
Hazard
Statements
Classification procedure
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Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
revision 03.09.2020 (GB) Version 4.7
Robla Solo Mil-Laufreiniger
Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS]
GHS05 GHS07
Signal word
Danger
Hazard statements for physical hazards
H290 May be corrosive to metals.
!
Hazard statements for health hazards
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
Precautionary Statements
General
P102 Keep out of reach of children.
!
Prevention
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
!
Response
P301 + P330 +
IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P331
P303 + P361 +
P353
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 +
P338
!
Storage
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P405 Store locked up.
Disposal
P501 Dispose of contents / container to recycling
Hazardous ingredients for labeling
Ammoniak
2.3. Other hazards
No information available.
! SECTION 3: Composition/ information on ingredients
3.1. Substances
not applicable
3.2. Mixtures
! Hazardous ingredients
CAS No EC No Name [%
weight]
1336-21-6 215-647-6 Ammoniak 25% 2,5 < 10 Skin Corr. 1B, H314 / Aquatic Acute 1, H400
Classification according to Regulation (EC)
No 1272/2008 [CLP/GHS]
/ Met. Corr. 1, H290 / STOT SE 1, H335
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Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
revision 03.09.2020 (GB) Version 4.7
Robla Solo Mil-Laufreiniger
SECTION 4: First aid measures
4.1. Description of first aid measures
In case of inhalation
Remove the casualty into fresh air and keep him immobile.
If intensive inhalation of fumes seek medical treatment immediately.
In case of skin contact
In case of contact with skin wash off immediately with plenty of water.
Consult a doctor if skin irritation persists.
In case of eye contact
In case of contact with eyes rinse with plenty of water carefully. In the event of persistent symptoms seek
medical treatment.
In case of ingestion
If swallowed seek medical advice immediately and show the doctor packing or label.
Rinse out mouth and give plenty of water to drink.
4.2. Most important symptoms and effects, both acute and delayed
No information available.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment (Advice to doctor)
After swallowing: Early endoscopy, to evaluate possibly occured alternation of the mucous membrane in
oesophagus and stomach. If necessary suction of remained substance.
SECTION 5: Firefighting measures
5.1. Extinguishing media
No information available.
5.2. Special hazards arising from the substance or mixture
No information available.
5.3. Advice for firefighters
Additional information
Product is incombustible
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Use personal protective clothing.
Avoid contact with substance
6.2. Environmental precautions
Do not discharge into surface waters/groundwater.
6.3. Methods and material for containment and cleaning up
Dilute with water.
Flush away residues with water.
Take up mechanically and send for disposal.
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6.4. Reference to other sections
No information available.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling
No special measures necessary if used correctly.
General protective measures
Avoid contact with eyes and skin
Hygiene measures
Clean skin thoroughly after working.
At work do not eat, drink, smoke or take drugs.
Remove soiled or soaked clothing immediately.
Advice on protection against fire and explosion
The product is not combustible.
No special measures necessary.
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
revision 03.09.2020 (GB) Version 4.7
Robla Solo Mil-Laufreiniger
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep in closed original container.
Advice on storage compatibility
Do not store together with food.
Further information on storage conditions
Keep container tightly closed, open and handle carefully.
Rechtsgrundlage TRGS 510
Storage group
7.3. Specific end use(s)
No information available.
8B
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
8.2. Exposure controls
Hand protection
Gloves (alkali-resistant)
The material of the gloves has to be impermeable and consistent for the substance. Observe glove manufactor´s
instructions concerning penetrability and breakthrough time.
Eye protection
With demand: protective glasses
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
liquid, emulsion
Colour
orange
Odour
similar to ammonia
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Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
revision 03.09.2020 (GB) Version 4.7
Robla Solo Mil-Laufreiniger
Odour threshold
not determined
Important health, safety and environmental information
Value Temperature at Method Remark
pH value
ca. 9 20 °C
Boiling temperature /
boiling range
Melting point /
Freezing point
Flash point
Vapourisation rate
Flammable (solid)
Flammability (gas)
Ignition temperature
No
information
available.
No
information
available.
No flash point
Measurement had
been done until
boiling temperature.
No
information
available.
No
information
available.
No
information
available.
No
information
available.
Self ignition
temperature
Lower explosion limit
Upper explosion limit
Vapour pressure
Relative density
Bulk density
Vapour density
No
information
available.
No
information
available.
No
information
available.
No
information
available.
0,954 g/cm3 20 °C 1013 hPa
not applicable
No
information
available.
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Solubility in water
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
revision 03.09.2020 (GB) Version 4.7
Robla Solo Mil-Laufreiniger
Value Temperature at Method Remark
multimiscible
Solubility/other
Partition coefficient noctanol/water (log P
O/W)
Decomposition
temperature
Viscosity
Viscosity
Solvent separation test
Solvent content
No
information
available.
No
information
available.
No
information
available.
No
information
available.
No
information
available.
No
information
available.
No
information
available.
Water content
Solids content
No
information
available.
No
information
available.
Oxidising properties
No information available.
Explosive properties
No information available.
9.2. Other information
No information available.
SECTION 10: Stability and reactivity
10.1. Reactivity
No information available.
10.2. Chemical stability
No information available.
10.3. Possibility of hazardous reactions
Acid, concentrated
Oxidising agent, strong
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10.4. Conditions to avoid
heating up
No hazardous reactions known.
10.5. Incompatible materials
No information available.
10.6. Hazardous decomposition products
No hazardous decomposition products known.
Additional information
Product is stable under normal storage conditions
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity/Irritation/Sensitization
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
revision 03.09.2020 (GB) Version 4.7
Robla Solo Mil-Laufreiniger
Value/Validation Species Method Remark
LD50 acute oral
LC50 acute
inhalation
Skin irritation
Eye irritation
Skin sensitization
1070 mg/kg rat Result applies to conc. Ammonia
solution.
1,4 mg/l (4 h) rat Result applies to conc. Ammonia
solution.
strong irritant rabbit Information apply to conc. ammonia
strong irritant rabbit eye Information apply to conc. ammonia
non-sensitizing Guinea pig Information apply to conc. ammonia
Toxicity test (Additional information)
No experimental indication of genotoxicity in vitro ( Ames-test negative ).
No experimental indication of genotoxicity in vivo (micronucleus test negative ).
Additional information
The product has not been tested. The information is derived from the properties of the individual components.
SECTION 12: Ecological information
12.1. Toxicity
Ecotoxicological effects
Value Species Method Validation
Fish
LC50 0,23 - 0,33 mg/l (96 h) Oncorhynchus mykiss Information are based on
results of similar products
Daphnia
EC50 53,5 mg/l (48 h) Daphnia magna Based on actual testing result
12.2. Persistence and degradability
No information available.
12.3. Bioaccumulative potential
data or a comparable product
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Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
revision 03.09.2020 (GB) Version 4.7
Robla Solo Mil-Laufreiniger
No information available.
12.4. Mobility in soil
No information available.
12.5. Results of PBT and vPvB assessment
No information available.
12.6. Other adverse effects
Behaviour in sewage plant
When low concentrations are discharged correctly into adapted biological sewage treatment plants, interference with the
degradation activity of activated sludge is not likely.
The product is an alkaline solution. Neutralization is normally necessary before waste water is discharged into sewage treatment
plants.
General regulation
The breakdown properties of the product have not been tested. The information on these is given on the basis of details in the
literature.
The behaviour of the product in sewage treatment plants has not been tested. The information on this is given on the basis of details
in the literature.
The ecotoxic effect of the product has not been tested. The information on this is given on the basis of details in the literature.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste code No. Name of waste
06 02 05* other bases
Wastes marked with an asterisk are considered to be hazardous waste pursuant to Directive 2008/98/EC on
hazardous waste.
Recommendations for the product
Neutralize with hydrochloric acid or sulphuric acid.
Dilution with water.
Recommendations for packaging
Uncontaminated packaging may be taken for recycling.
Barrel: return by DSD ( Dualistic System Germany )
Recommended cleansing agent
Water
General information
Waste removal corresponding to official directives
! SECTION 14: Transport information
ADR/RID IMDG IATA-DGR
14.1. UN number
14.2. UN proper shipping
name
- - -
- - -
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Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
revision 03.09.2020 (GB) Version 4.7
Robla Solo Mil-Laufreiniger
ADR/RID IMDG IATA-DGR
14.3. Transport hazard
class(es)
14.4. Packing group
14.5. Environmental
hazards
14.6. Special precautions for user
No information available.
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No information available.
Land and inland navigation transport ADR/RID
No dangerous goods as defined by these transport regulations
Marine transport IMDG
No dangerous goods as defined by these transport regulations
Air transport ICAO/IATA-DGR
No dangerous goods as defined by these transport regulations.
- - -
- - -
- - -
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
Water hazard class
15.2. Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.
2 AwSV vom 18.04.2017
clearly water-carrying
SECTION 16: Other information
Recommended uses and restrictions
National and local regulations concerning chemicals shall be observed.
The information in this data sheet has been established to our best knowledge and was up-to-date at time of
revision. It does not represent a guarantee for the properties of the product described in terms of the legal
warranty regulations.
Keep out of the reach of children.
Further information
The information contained herein is based on the state of our knowledge. It characterizes the product with
regard to the appropriate safety precautions. It does not represent a guarantee of the properties of the product.
Indication of changes: "!" = Data changed compared with the previous version.
Indication of changes: "!" = Data changed compared with the previous version. Previous version: 4.6
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
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