Arm & Hammer CDC 33200-35255 User Manual

Scrub FreeTM Bathroom Cleaner Plus OxicleanTM Soap Scum
Fighters

Safety Data Sheet

According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations

Revision Date: 04/09/2015

Date of issue: 04/09/2015

Supersedes Date: 02/26/2010

Version: 1.0

04/09/2015

EN (English US) 1/9

Product Form: Mixture

Product Name: Scrub FreeTM Bathroom Cleaner Plus OxicleanTM Soap Scum Fighters

Bathroom cleaner.

Name, Address, and Telephone of the Responsible Party

Company

Church & Dwight
500 Charles Ewing Blvd
Ewing Township, NJ 08628
T 1-800-524-1328

www.churchdwight.com

Emergency Number

:

For Medical Emergency: 1-888-234-1828, For Chemical Emergency: 1-800-424-9300 (CHEMTREC)

Skin Corr. 1A

H314

Eye Dam. 1

H318

Aquatic Acute 3

H402

Hazard Pictograms (GHS-US)

:

GHS05

Signal Word (GHS-US)

:

Danger

Hazard Statements (GHS-US)

:

H314 - Causes severe skin burns and eye damage.
H318 - Causes serious eye damage.
H402 - Harmful to aquatic life.

Precautionary Statements (GHS-US)

:

P260 - Do not breathe vapors, mist, or spray.
P264 - Wash hands, forearms, and other exposed areas thoroughly after handling.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, and eye protection.
P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353+P363 - IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse.
P304+P340 - IF INHALED: Remove person to fresh air and keep at rest in a position
comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove

SECTION 1: IDENTIFICATION

Product Identifier

Intended Use of the Product

Emergency Telephone Number

SECTION 2: HAZARDS IDENTIFICATION

This product is labeled in accordance with regulations administered by the Consumer Product Safety Commission (CPSC). The use
pattern and exposure in the workplace are generally not consistent with those experienced by consumers. The requirements of the
Occupational Safety and Health Administration applicable to this SDS differ from the labeling requirements of the CPSC and, as a
result, this SDS may contain additional health hazard information not pertinent to consumer use and not found on the product label.

Classification of the Substance or Mixture

Classification (GHS-US)

Full text of H-phrases: see section 16

Label Elements

GHS-US Labeling

Scrub FreeTM Bathroom Cleaner Plus OxicleanTM Soap Scum Fighters

Safety Data Sheet

According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations

04/09/2015

EN (English US)

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contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a poison center or doctor.
P405 - Store locked up.
P501 - Dispose of contents/container in accordance with local, regional, national,
territorial, provincial, and international regulations.

Name

Product Identifier

% (w/w)

Classification (GHS-US)

Water

(CAS No) 7732-18-5

60 - 100

Not classified

Sulfamic acid

(CAS No) 5329-14-6

1 - 5

Acute Tox. 4 (Oral), H302
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Aquatic Acute 3, H402
Aquatic Chronic 3, H412

1-Dodecanamine, N,N-dimethyl-, N-oxide

(CAS No) 1643-20-5

1 - 5

Skin Irrit. 2, H315
Eye Dam. 1, H318
Aquatic Acute 1, H400

Alcohols, C6-12, ethoxylated

(CAS No) 68439-45-2

0.1 - 1

Acute Tox. 4 (Oral), H302
Eye Dam. 1, H318

Fragrance

(CAS No) Not available

0.1 - 1

Not classified

General: Causes severe skin burns and eye damage.

Inhalation: Contact may cause immediate severe irritation progressing quickly to chemical burns.

Skin Contact: Corrosive. Causes burns. Symptoms may include: Redness, pain, swelling, itching, burning, dryness, and dermatitis.

Eye Contact: Causes serious eye damage. Symptoms may include: Redness, pain, swelling, itching, burning, tearing, and blurred

vision. Causes permanent damage to the cornea, iris, or conjunctiva.

Ingestion: Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract f the
linings of the mouth, throat, and gastrointestinal tract.

Chronic Symptoms: None known.

If you feel unwell, seek medical advice (show the label where possible).

Other Hazards

May be corrosive to respiratory tract. Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions.

Unknown Acute Toxicity (GHS-US) Not available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Mixture

The specific chemical identity and/or exact percentage of composition have been withheld as a trade secret [29 CFR 1910.1200].
A range of concentration as prescribed by the Controlled Products Regulations has been used where necessary, due to varying
composition.
Full text of H-phrases: see section 16

SECTION 4: FIRST AID MEASURES

Description of First Aid Measures

General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where

possible).
Inhalation: When symptoms occur: go into open air and ventilate suspected area. Remove person to fresh air and keep comfortable

for breathing. Immediately call a POISON CENTER or doctor/physician.
Skin Contact: Immediately flush skin with plenty of water for at least 60 minutes. Remove contaminated clothing and shoes. Get
immediate medical advice/attention. Wash contaminated clothing before reuse.

Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for
at least 60 minutes. Immediately call a POISON CENTER or doctor/physician.

Ingestion: Rinse mouth. Do not induce vomiting. Immediately call a POISON CENTER or doctor/physician.

Most Important Symptoms and Effects Both Acute and Delayed

Indication of Any Immediate Medical Attention and Special Treatment Needed

Scrub FreeTM Bathroom Cleaner Plus OxicleanTM Soap Scum Fighters

Safety Data Sheet

According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations

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Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be
present.

Firefighting Instructions: Use water spray or fog for cooling exposed containers.

Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.

Hazardous Combustion Products: Carbon oxides (CO, CO2). Nitrogen oxides.

Reference to Other Sections

Refer to section 9 for flammability properties.

General Measures: Do not get in eyes, on skin, or on clothing. Do not breathe vapor, mist or spray.

Protective Equipment: Use appropriate personal protection equipment (PPE).

Emergency Procedures: Evacuate unnecessary personnel.

Protective Equipment: Equip cleanup crew with proper protection.

Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods,

protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit.

For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.

Methods for Cleaning Up: Cautiously neutralize spilled liquid. Absorb spillage to prevent material damage. Collect absorbed material

and place into a sealed, labeled container for proper disposal. Clean up spills immediately and dispose of waste safely.

See heading 8, Exposure Controls and Personal Protection. For further information refer to section 13.

Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas
with mild soap and water before eating, drinking, or smoking and again when leaving work. Do not eat, drink or smoke when using
this product.

Technical Measures: Ensure all national/local regulations are observed.

Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Store in original container.

Incompatible Materials: Strong acids. Strong bases. May react with active metals, oxidizing agents, cyanide, or sulfide salts to

produce hydrogen, oxides of nitrogen, hydrogen cyanide, or hydrogen sulfide gases.

Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.

Unsuitable Extinguishing Media: Use of heavy stream of water may spread fire.

Fire Hazard: Not flammable.

Explosion Hazard: Product is not explosive.

Reactivity: Hazardous reactions will not occur under normal conditions.

SECTION 5: FIRE-FIGHTING MEASURES

Extinguishing Media

Special Hazards Arising From the Substance or Mixture

Advice for Firefighters

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures

For Non-Emergency Personnel

For Emergency Personnel

Environmental Precautions

Prevent entry to sewers and public waters. Contact competent authorities after a spill.

Methods and Material for Containment and Cleaning Up

Reference to Other Sections

SECTION 7: HANDLING AND STORAGE

Precautions for Safe Handling

Conditions for Safe Storage, Including Any Incompatibilities

Specific End Use(s)

Bathroom cleaner.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier,
importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or
the Mexican government