Arm & Hammer 3320000108 User Manual

ARM & HAMMERTM Powder Laundry Detergent plus
OxicleanTM

Safety Data Sheet

According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations

Revision Date: 09/08/2015

Date of issue: 05/14/2015 Version: 2.0

09/08/2015

EN (English US) 1/8

Product Form: Mixture

Product Name: ARM & HAMMERTM Powder Laundry Detergent plus OxicleanTM

Synonyms: Detergent

Laundry Detergent.

Name, Address, and Telephone of the Responsible Party

Company

Church & Dwight
500 Charles Ewing Blvd
Ewing Township, NJ 08628
T 1-800-524-1328

www.churchdwight.com

Emergency Number

:

For Medical Emergency: 1-888-234-1828, For Chemical Emergency: 1-800-424-9300 (CHEMTREC)

Eye Irrit. 2A

H319

Aquatic Acute 2

H401

Hazard Pictograms (GHS-US)

:

GHS07

Signal Word (GHS-US)

:

Warning

Hazard Statements (GHS-US)

:

H319 - Causes serious eye irritation.
H401 - Toxic to aquatic life.

Precautionary Statements (GHS-US)

:

P264 - Wash hands, forearms, and other exposed areas thoroughly after handling.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, and eye protection.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P501 - Dispose of contents/container in accordance with local, regional, national,
territorial, provincial, and international regulations.

SECTION 1: IDENTIFICATION

Product Identifier

Intended Use of the Product

Emergency Telephone Number

SECTION 2: HAZARDS IDENTIFICATION

This product is labeled in accordance with regulations administered by the Consumer Product Safety Commission (CPSC). The use
pattern and exposure in the workplace are generally not consistent with those experienced by consumers. The requirements of the
Occupational Safety and Health Administration applicable to this SDS differ from the labeling requirements of the CPSC and, as a
result, this SDS may contain additional health hazard information not pertinent to consumer use and not found on the product label.

Classification of the Substance or Mixture

GHS-US classification

Full text of H-phrases: see section 16

Label Elements

GHS-US Labeling

Other Hazards Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. . May cause an allergic reaction

in sensitive individuals.

ARM & HAMMERTM Powder Laundry Detergent plus OxicleanTM

Safety Data Sheet

According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations

09/08/2015

EN (English US)

2/8

Name

Product Identifier

% (w/w)

GHS-US classification

Disodium carbonate

(CAS No) 497-19-8

60 - 100

Eye Irrit. 2A, H319

Poly(oxy-1,2-ethanediyl), .alpha.-sulfo-.omega.­hydroxy-, C10-16-alkyl ethers, sodium salts

(CAS No) 68585-34-2

3 - 7

Skin Irrit. 2, H315
Eye Irrit. 2B, H320

Alcohols, C12-16, ethoxylated

(CAS No) 68551-12-2

1 - 5

Skin Irrit. 2, H315
Eye Dam. 1, H318
Aquatic Acute 1, H400

Tinopal CBS

(CAS No) 27344-41-8

0.45

Acute Tox. 4 (Inhalation:dust,mist), H332
Eye Irrit. 2A, H319
Aquatic Acute 2, H401

Subtilisins (proteolytic enzymes)

(CAS No) 9014-01-1

< 0.1

Acute Tox. 4 (Oral), H302
Skin Irrit. 2, H315
Eye Dam. 1, H318
Resp. Sens. 1, H334
STOT SE 3, H335
Aquatic Acute 1, H400
Aquatic Chronic 2, H411

General: Causes serious eye irritation. Prolonged contact with large amounts of dust may cause mechanical irritation.

Inhalation: May cause respiratory irritation. May cause pulmonary edema.

Skin Contact: May cause skin irritation. May cause an allergic reaction in sensitive individuals.

Eye Contact: Symptoms may include: Redness, pain, swelling, itching, burning, tearing, and blurred vision.

Ingestion: Ingestion is likely to be harmful or have adverse effects.

Chronic Symptoms: None expected under normal conditions of use.

If exposed or concerned, get medical advice and attention.

Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.

Unsuitable Extinguishing Media: For surrounding fire. Use of heavy stream of water may spread fire.

Fire Hazard: Not flammable.

Explosion Hazard: Product is not explosive.

Reactivity: Hazardous reactions will not occur under normal conditions.

Unknown Acute Toxicity (GHS-US) Not available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Mixture

A range of concentration as prescribed by the Controlled Products Regulations has been used where necessary, due to varying
composition.
The specific chemical identity and/or exact percentage of composition have been withheld as a trade secret [29 CFR 1910.1200].
Full text of H-phrases: see section 16

SECTION 4: FIRST AID MEASURES

Description of First Aid Measures

General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice.
Inhalation: When symptoms occur: go into open air and ventilate suspected area. Remove to fresh air and keep at rest in a position

comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell.
Skin Contact: Brush off loose particles from skin. Rinse immediately with plenty of water (for at least 15 minutes). Obtain medical
attention if irritation develops or persists. Wash contaminated clothing before reuse.
Eye Contact: Do not rub. Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do so.
Continue rinsing. Obtain medical attention if irritation persists.
Ingestion: Seek medical attention if a large amount is swallowed. Rinse mouth. Do NOT induce vomiting. If vomiting occurs have
person lean forward.

Most Important Symptoms and Effects Both Acute and Delayed

Indication of Any Immediate Medical Attention and Special Treatment Needed

SECTION 5: FIRE-FIGHTING MEASURES

Extinguishing Media

Special Hazards Arising From the Substance or Mixture

ARM & HAMMERTM Powder Laundry Detergent plus OxicleanTM

Safety Data Sheet

According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations

09/08/2015

EN (English US)

3/8

Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be
present.

Firefighting Instructions: Use water spray or fog for cooling exposed containers.

Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Wear

self-contained breathing apparatus when entering area unless atmosphere is proved to be safe.

Hazardous Combustion Products: Carbon oxides (CO, CO2). Sulfur oxides. Sodium oxides.

Reference to Other Sections

Refer to section 9 for flammability properties.

General Measures: Do not breathe dust or fumes. Avoid skin and eye contact.

Protective Equipment: Use appropriate personal protection equipment (PPE).

Emergency Procedures: Evacuate unnecessary personnel.

Protective Equipment: Equip cleanup crew with proper protection.

Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods,

protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit.

For Containment: Contain and collect as any solid.

Methods for Cleaning Up: Avoid generation of dust during clean-up of spills. Keep in suitable, closed containers for disposal. Contact

competent authorities after a spill. Clean up spills immediately and dispose of waste safely.

See heading 8, Exposure Controls and Personal Protection. For further information refer to section 13.

Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas
with mild soap and water before eating, drinking, or smoking and again when leaving work.

Technical Measures: Ensure all national/local regulations are observed.

Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container tightly closed. Store away from incompatible

materials.

Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Heavy metals.

Subtilisins (proteolytic enzymes) (9014-01-1)

USA ACGIH

ACGIH Ceiling (mg/m³)

0.00006 mg/m³

USA NIOSH

NIOSH REL (STEL) (mg/m³)

0.00006 mg/m³

Alberta

OEL Ceiling (mg/m³)

0.00006 mg/m³

British Columbia

OEL Ceiling (mg/m³)

0.00006 mg/m³

Manitoba

OEL Ceiling (mg/m³)

0.00006 mg/m³

New Brunswick

OEL Ceiling (mg/m³)

0.00006 mg/m³ (proteolytic enzymes)

Newfoundland & Labrador

OEL Ceiling (mg/m³)

0.00006 mg/m³

Nova Scotia

OEL Ceiling (mg/m³)

0.00006 mg/m³

Nunavut

OEL Ceiling (mg/m³)

0.00006 mg/m³ (Proteolytic enzymes)

Northwest Territories

OEL Ceiling (mg/m³)

0.00006 mg/m³

Advice for Firefighters

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures

For Non-Emergency Personnel

For Emergency Personnel

Environmental Precautions Avoid release to the environment. Contact competent authorities after a spill.
Methods and Material for Containment and Cleaning Up

Reference to Other Sections

SECTION 7: HANDLING AND STORAGE

Precautions for Safe Handling

Conditions for Safe Storage, Including Any Incompatibilities

Specific End Use(s) Laundry Detergent.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier,
importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), OSHA (PEL), Canadian provincial governments, or
the Mexican government