Arm & Hammer 3320000107 User Manual

Signal Word (GHS-US)

: Warning

Hazard Statements (GHS-US)

:

H315 - Causes skin irritation.

H412 - Harmful to aquatic life with long lasting effects.

Precautionary Statements (GHS-US)

: P264 - Wash hands, forearms, and other exposed areas thoroughly after handling.

Skin Irrit. 2

H315

Eye Irrit. 2A

H319

Aquatic Acute 2

H401

Aquatic Chronic 3

H412

Arm & Hammer® Liquid Laundry Detergent plus Oxiclean

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECT

ION 1: IDENTIFICATION

Product Identifier

Product Form: Mixture
Product Name: Arm & Hammer® Liquid Laundry Detergent plus Oxiclean

Intended Use of the Product

Use of the Substance/Mixture: Laundry Detergent.

Name, Address, and Telephone of the Responsible Party

Company

Church & Dwight
500 Charles Ewing Blvd
Ewing Township, NJ 08628
T 1-800-524-1328

www.churchdwight.com

Emergency Telephone Number

Emergency number : For Medical Emergency: 1-888-234-1828, For Chemical Emergency: 1-800-424-9300 (CHEMTREC)

SECTION 2: HAZARDS

This

product is labeled in accordance with regulations administered by the Consumer Product Safety Commission (CPSC). The use
pattern and exposure in the workplace are generally not consistent with those experienced by consumers. The requirements of the
Occupational Safety and Health Administration applicable to this SDS differ from the labeling requirements of the CPSC and, as a
result, this SDS may contain additional health hazard information not pertinent to consumer use and not found on the product label.

IDENTIFICATION

Classification of the Substance or Mixture

Classification (GHS-US)

Revision Date: 01/12/2015 Version: 1.0

Label Elements

GHS-US Labeling
Hazard Pictograms (GHS-US) :

01/12/2015 EN (English US) 1/10

GHS07

H319 - Causes serious eye irritation.
H401 - Toxic to aquatic life.

P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection, face protection,
respiratory protection.
P302+P352 - If on skin: Wash with plenty of water.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - If exposed or concerned: Get medical advice/attention.

Arm & Hammer® Liquid Laundry Detergent plus Oxiclean

01/12/2015

EN (English US)

2/10

Name

Product identifier

% (w/w)

Classification (GHS-US)

Poly(oxy-1,2-ethanediyl),

.alpha.-sulfo-

(CAS No) 9004-82-4

1 – 5, 5 – 9.86

Acute Tox. 4 (Oral), H302

Aquatic Chronic 2, H411

Alcohols, C12-15, ethoxylated

(CAS No) 68131-39-5

0.1 – 1, 1 – 5,

Acute Tox. 4 (Oral), H302

Aquatic Chronic 3, H412

Sodium carbonate

(CAS No) 497-19-8

1.3 - 3.5

Eye Irrit. 2A, H319

Benzenesulfonic acid, alkyl derivatives

(CAS No) 42615-29-2

0.1 – 1 , 1 –

Acute Tox. 4 (Oral), H302

Aquatic Acute 2, H401

Benzenepropanal, 4-(1,1-dimethylethyl)-

(CAS No) 80-54-6

<0.1, 0.1 –

Acute Tox. 4 (Oral), H302

Aquatic Chronic 2, H411

Tinopal CBS

(CAS No) 27344-41-8

<0.1, 0.1 –

Acute Tox. 4 (Inhalation:dust,mist),

Aquatic Acute 2, H401

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

P321 - Specific treatment (see section 4).
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P501 - Dispose of contents/container according to local, regional, national, territorial,
provincial, and international regulations.

Other Hazards

Other Hazards Not Contributing to the Classification:
Other Hazards: Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. When heated to decomposition

may emit toxic and irritating fumes. May cause an allergic reaction in sensitive individuals.

Unknown Acute Toxicity (GHS-US)

No additional information available

SECT

ION 3:

COMPOSITIO

N/INFORMATION ON INGREDIENTS

Mixture

.omega.-(dodecyloxy)-, sodium salt

Skin Irrit. 2, H315
Eye Dam. 1, H318
Asp. Tox. 1, H304
Aquatic Acute 2, H401

5 - 6.88

2.5

.alpha.-methyl-

Multiple WHMIS ranges have been utilized due to varying composition.
Full text of H-phrases: see section 16

SECT

ION 4: FIRST AI

Description of First Aid Measures

General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where

possible).
Inhalation: When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty

persists.
Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Wash contaminated clothing
before reuse. If skin irritation occurs: Get medical advice/attention.

Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Obtain medical attention if pain, blinking or redness persist.

D M

EASURES

0.198

0.12

Eye Dam. 1, H318
Aquatic Acute 1, H400

Acute Tox. 3 (Dermal), H311
Skin Corr. 1C, H314
Eye Dam. 1, H318

Skin Sens. 1B, H317
Repr. 2, H361
Aquatic Acute 2, H401

H332
Eye Irrit. 2A, H319

Arm & Hammer® Liquid Laundry Detergent plus Oxiclean

01/12/2015

EN (English US)

3/10

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Ingestion: Rinse mouth. Do NOT induce vomiting. Seek medical attention immediately.

Most Important Symptoms and Effects Both Acute and Delayed

General: Causes skin irritation. Causes eye irritation.
Inhalation: Prolonged exposure to liquid may cause a mild irritation.
Skin Contact: Causes skin irritation. May cause an allergic reaction in sensitive individuals.
Eye Contact: Causes eye irritation.
Ingestion: Ingestion is likely to be harmful or have adverse effects.
Chronic Symptoms: No additional information available.

Indication of Any Immediate Medical Attention and Special Treatment Needed

If exposed or concerned, get medical advice and attention.

SECT

ION 5: FIRE-FIGHTIN

Extinguishing Media

Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Unsuitable Extinguishing Media: For surrounding fire do not use a heavy water stream. Use of heavy stream of water may spread

fire.

Special Hazards Arising From the Substance or Mixture

Fire Hazard: NOT FLAMMABLE
Explosion Hazard: Product is not explosive.
Reactivity: Hazardous reactions will not occur under normal conditions.

Advice for Firefighters

Precautionary Measures Fire: Exercise caution when fighting any chemical fire.
Firefighting Instructions: Use water spray or fog for cooling exposed containers.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Hazardous Combustion Products: Carbon oxides (CO, CO

released.

Other information: Do not allow run-off from fire fighting to enter drains or water courses.

Reference to Other Sections

Refer to section 9 for flammability properties.

SECT

ION 6: ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures

General Measures: Handle in accordance with good industrial hygiene and safety practice. Spilled material may present a slipping

hazard. Avoid prolonged contact with eyes, skin and clothing. Avoid breathing (vapors, mist, spray).

For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
For Emergency Personnel
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Ventilate area.

Environmental Precautions

Prevent entry to sewers and public waters. Avoid release to the environment.

G M

EASURES

). Nitrogen oxides. Sulfur oxides. Toxic fumes and irritating fumes are

2

Methods and Material for Containment and Cleaning Up

For Containment: Absorb and/or contain spill with inert material, then place in suitable container.
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Absorb and/or contain spill with inert material,

then place in suitable container. Contact competent authorities after a spill.

Reference to Other Sections

See heading 8, Exposure Controls and Personal Protection.

SECT

ION 7: HANDLING AND STORAGE

Precautions for Safe Handling

Additional Hazards When Processed: When heated to decomposition, material may emit toxic and irritating fumes.