Arm & Hammer 3320000008 User Manual
ARM & HAMMER® Liquid Laundry Detergent, XTRA® Liquid
Laundry Detergent
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision Date: 01/12/2015
Version: 1.0
01/12/2015
EN (English US) 1/10
Product Form: Mixture
Product Name: ARM & HAMMER® Liquid Laundry Detergent, XTRA® Liquid Laundry Detergent
Use of the Substance/Mixture: Laundry Detergent.
Name, Address, and Telephone of the Responsible Party
Company
Church & Dwight
500 Charles Ewing Blvd
Ewing Township, NJ 08628
T 1-800-524-1328
www.churchdwight.com
Emergency number
:
For Medical Emergency: 1-888-234-1828, For Chemical Emergency: 1-800-424-9300 (CHEMTREC)
Skin Irrit. 2
H315
Eye Irrit. 2A
H319
Aquatic Acute 2
H401
Aquatic Chronic 3
H412
Hazard Pictograms (GHS-US)
:
GHS07
Signal Word (GHS-US)
:
Warning
Hazard Statements (GHS-US)
:
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H401 - Toxic to aquatic life.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary Statements (GHS-US)
:
P264 - Wash hands, forearms, and other exposed areas thoroughly after handling.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection, face protection,
respiratory protection.
P302+P352 - If on skin: Wash with plenty of water.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - If exposed or concerned: Get medical advice/attention.
SECTION 1: IDENTIFICATION
Product Identifier
Intended Use of the Product
Emergency Telephone Number
SECTION 2: HAZARDS IDENTIFICATION
This product is labeled in accordance with regulations administered by the Consumer Product Safety Commission (CPSC). The use
pattern and exposure in the workplace are generally not consistent with those experienced by consumers. The requirements of the
Occupational Safety and Health Administration applicable to this SDS differ from the labeling requirements of the CPSC and, as a
result, this SDS may contain additional health hazard information not pertinent to consumer use and not found on the product label.
Classification of the Substance or Mixture
Classification (GHS-US)
Label Elements
GHS-US Labeling
ARM & HAMMER® Liquid Laundry Detergent, XTRA® Liquid Laundry
Detergent
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/12/2015
EN (English US)
2/10
P321 - Specific treatment (see section 4).
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P501 - Dispose of contents/container according to local, regional, national, territorial,
provincial, and international regulations.
Other Hazards Not Contributing to the Classification:
Other Hazards: Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. When heated to decomposition
may emit toxic and irritating fumes. May cause an allergic reaction in sensitive individuals.
Name
Product identifier
% (w/w)
Classification (GHS-US)
Poly(oxy-1,2-ethanediyl), .alpha.-sulfo.omega.-(dodecyloxy)-, sodium salt
(CAS No) 9004-82-4
1 – 5, 5 – 9.86
Acute Tox. 4 (Oral), H302
Skin Irrit. 2, H315
Eye Dam. 1, H318
Asp. Tox. 1, H304
Aquatic Acute 2, H401
Aquatic Chronic 2, H411
Alcohols, C12-15, ethoxylated
(CAS No) 68131-39-5
0.1 – 1, 1 – 5,
5 - 6.88
Acute Tox. 4 (Oral), H302
Eye Dam. 1, H318
Aquatic Acute 1, H400
Aquatic Chronic 3, H412
Sodium carbonate
(CAS No) 497-19-8
1.3 - 3.5
Eye Irrit. 2A, H319
Benzenesulfonic acid, alkyl derivatives
(CAS No) 42615-29-2
0.1 – 1 , 1 –
2.5
Acute Tox. 4 (Oral), H302
Acute Tox. 3 (Dermal), H311
Skin Corr. 1C, H314
Eye Dam. 1, H318
Aquatic Acute 2, H401
Benzenepropanal, 4-(1,1-dimethylethyl).alpha.-methyl-
(CAS No) 80-54-6
<0.1, 0.1 –
0.198
Acute Tox. 4 (Oral), H302
Skin Sens. 1B, H317
Repr. 2, H361
Aquatic Acute 2, H401
Aquatic Chronic 2, H411
Tinopal CBS
(CAS No) 27344-41-8
<0.1, 0.1 –
0.12
Acute Tox. 4 (Inhalation:dust,mist),
H332
Eye Irrit. 2A, H319
Aquatic Acute 2, H401
Other Hazards
Unknown Acute Toxicity (GHS-US)
No additional information available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Mixture
Multiple WHMIS ranges have been utilized due to varying composition.
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
Description of First Aid Measures
General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where
possible).
Inhalation: When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty
persists.
Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Wash contaminated clothing
before reuse. If skin irritation occurs: Get medical advice/attention.
ARM & HAMMER® Liquid Laundry Detergent, XTRA® Liquid Laundry
Detergent
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
01/12/2015
EN (English US)
3/10
General: Causes skin irritation. Causes eye irritation.
Inhalation: Prolonged exposure to liquid may cause a mild irritation.
Skin Contact: Causes skin irritation. May cause an allergic reaction in sensitive individuals.
Eye Contact: Causes eye irritation.
Ingestion: Ingestion is likely to be harmful or have adverse effects.
Chronic Symptoms: No additional information available.
Precautionary Measures Fire: Exercise caution when fighting any chemical fire.
Firefighting Instructions: Use water spray or fog for cooling exposed containers.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Hazardous Combustion Products: Carbon oxides (CO, CO2). Nitrogen oxides. Sulfur oxides. Toxic fumes and irritating fumes are
released.
Other information: Do not allow run-off from fire fighting to enter drains or water courses.
Reference to Other Sections
Refer to section 9 for flammability properties.
General Measures: Handle in accordance with good industrial hygiene and safety practice. Spilled material may present a slipping
hazard. Avoid prolonged contact with eyes, skin and clothing. Avoid breathing (vapors, mist, spray).
Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Ventilate area.
For Containment: Absorb and/or contain spill with inert material, then place in suitable container.
Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely. Absorb and/or contain spill with inert material,
then place in suitable container. Contact competent authorities after a spill.
Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire.
Unsuitable Extinguishing Media: For surrounding fire do not use a heavy water stream. Use of heavy stream of water may spread
fire.
Fire Hazard: NOT FLAMMABLE
Explosion Hazard: Product is not explosive.
Reactivity: Hazardous reactions will not occur under normal conditions.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Obtain medical attention if pain, blinking or redness persist.
Ingestion: Rinse mouth. Do NOT induce vomiting. Seek medical attention immediately.
Most Important Symptoms and Effects Both Acute and Delayed
Indication of Any Immediate Medical Attention and Special Treatment Needed
If exposed or concerned, get medical advice and attention.
SECTION 5: FIRE-FIGHTING MEASURES
Extinguishing Media
Special Hazards Arising From the Substance or Mixture
Advice for Firefighters
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
For Non-Emergency Personnel
For Emergency Personnel
Environmental Precautions
Prevent entry to sewers and public waters. Avoid release to the environment.
Methods and Material for Containment and Cleaning Up
Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection.
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