Analytical Industries GPR-3100 User Manual

Advanced Instruments Inc.
Owner’s Manual
GPR-3100 Oxygen Purity Analyzer
2855 Metropolitan Place, Pomona, CA 91767 USA Tel: 909-392-6900, Fax: 909-392-3665, e-mail: info@aii2.com, www.aii2.com
Table of Contents
Advanced Instruments Inc.
Introduction
Quality Control Certification
Safety
Features & Specifications
Operation
Maintenance
Spare Parts
Troubleshooting
Warranty
1 2 3 4 5 6
7 8 9
(MSDS) Material Safety Data Sheet
Reference Drawings
Rev 3/2004 i
10
As Required
T
1 Introduction
Advanced Instruments Inc.
Thank You For Your Business
Your new oxygen analyzer is a precision piece of equipment
designed to give you years of use in variety of industrial oxygen applications.
his analyzer is designed to measure the purity of oxygen gas containing innert gases such as nitrogen, helium or argon and/or other reactive gases such as hydrogen and gaseous hydrocarbon gases as minor contaminants.
In order to derive maximum performance from your new oxygen analyzer, please read and follow the guidelines provided in this Owner’s Manual.
The serial number of this analyzer may be found on the inside the analyzer. You should note the serial number in the space provided and retains this Owner’s Manual as a permanent record of your purchase, for future reference and for warranty considerations.
Serial Number: _______________________ Every effort has been made to select the most reliable state of
the art materials and components designed for superior performance and minimal cost of ownership. This analyzer was tested thoroughly by the manufacturer for best performance. However, modern electronic devices do require service from time to time. The warranty included herein plus a staff of trained professional technicians to quickly service your analyzer is your assurance that we stand behind every analyzer sold.
Advanced Instruments Inc. appreciates your business and pledge to make effort to maintain the highest possible quality standards with respect to product design, manufacturing and service.
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Advanced Instruments Inc.
2 Quality Control Certification
Date: Customer: Order No.: Pass Model
Sensor Accessories
Configuration
Test - Electronics
Test - Gas Phase
Final
Notes
GPR-3100 High Purity % O2 Analyzer GPR-11-120-OP Owner’s Manual CABL-1008 Power Cord Black 3 Conductor UL/CSA HRWR-1021 Wrench 5/16 Combination Ranges: 0-100%; suppressed 50-100%, 80-100%, 90-100% A-1146-E-50 PCB Assembly Micro-processor / Display A-1147-E-50 PCB Assembly Power Supply / Interconnection Software Rev: _______ Wetted parts: Stainless steel Power: Specify: ( x ) 100/120 VAC, ( ) 220/240 VAC Enclosure: ( ) Panel mount 10.8”W x 7.5”H
( ) Rack mount panel 19”W x 12”H ( x ) Wall mount 12”W x 12”H x 8”D
Factory default zero (without sensor) Factory default span @ 20 uA Alarm relays activate/deactivate to changes in O
concentration
2
Sensor failure alarm Power failure alarm Analog signal output 0-1V and 4-20mA Range ID voltage output Baseline drift < ± 1% FS 90-100% range over 24 hour period Noise level < ± 1.0% FS Span adjustment within 10-50% FS Temperature controller (CNTL-_______) set at 85°F Overall inspection for physical defects
1 of 1 analyzer due ASAP
GPR-3100 Rev 7/2004 2 1 of 1
Advanced Instruments Inc.
3 Safety
This section summarizes the essential generic precautions applicable to all analyzers. Additional precautions specific to individual analyzers are contained in the following sections of this manual. To operate the analyzer safely and obtain maximum performance follow the basic guidelines outlined in this Owner’s Manual.
Caution: This symbol is used throughout the Owner’s Manual to CAUTION and alert the user to recommended safety and/or operating guidelines.
Danger: This symbol is used throughout the Owner’s Manual to identify sources of immediate DANGER such as the presence of hazardous voltages.
Read Instructions: Before operating the analyzer read the instructions. Retain Instructions: The safety precautions and operating instructions found in the Owner’s Manual
should be retained for future reference.
Heed Warnings: Follow all warnings on the analyzer, accessories (if any) and in this Owner’s Manual. Follow Instructions: Observe all precautions and operating instructions. Failure to do so may result in
personal injury or damage to the analyzer.
Inlet Pressure: Recommended 5-30 psi, 100 psi maximum. Outlet Pressure: The sample gas vent pressure should be atmospheric. Oxygen Sensor: DO NOT open the sensor. The sensor contains a corrosive liquid electrolyte that could
be harmful if touched or ingested, refer to the Material Safety Data Sheet contained in the Owner’s Manual appendix. Avoid contact with any liquid or crystal type powder in or around the sensor or sensor housing, as either could be a form of electrolyte. Leaking sensors should be disposed of in accordance with local regulations.
Mounting: The analyzer is approved for indoor use only. It may be used outdoors with optional enclosures. Mount as recommended by the manufacturer.
Power: Supply power to the analyzer only as rated by the specification in Section 4 nd/or markings on the analyzer enclosure. The wiring/cords that connect the analyzer to the power source should be installed in accordance with recognized electrical standards and so they are not pinched particularly near the power source and the point where they attach to the analyzer. Never yank a power cord to remove it from an outlet or from the analyzer.
Operating Temperature: The maximum operating temperature is 45º C. Heat: Situate and store the analyzer away from sources of heat. Liquid and Object Entry: The analyzer should not be immersed in any liquid. Care should be taken so
that liquids are not spilled into and objects do not fall into the inside of the analyzer. Handling: Do not use force when using the switches and knobs. Before moving your analyzer be sure
to disconnect the wiring/power cord and any cables connected to the output terminals located on the analyzer.
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Advanced Instruments Inc.
3 Safety
Serviceability: Except for replacing the oxygen sensor, there are no parts inside the analyzer for the operator to service.
Only trained personnel with the authorization of their supervisor should conduct maintenance. Oxygen Sensor: DO NOT open the sensor. The sensor contains a corrosive liquid electrolyte that could
be harmful if touched or ingested, refer to the Material Safety Data Sheet contained in the Owner’s Manual appendix. Avoid contact with any liquid or crystal type powder in or around the sensor or sensor housing, as either could be a form of electrolyte. Leaking sensors should be disposed of in accordance with local regulations.
Troubleshooting: Consult the guidelines in Section 8 for advice on the common operating errors before concluding that your analyzer is faulty.
Do not attempt to service the analyzer beyond those means described in this Owner’s Manual. Do not attempt to make repairs by yourself as this will void the warranty as per Section 9 and may result in electrical shock, injury or damage. All other servicing should be referred to qualified service personnel.
Cleaning: The analyzer should be cleaned only as recommended by the manufacturer. Wipe off dust and dirt from the outside of the unit with a soft damp cloth then dry immediately. Do not use solvents or chemicals.
Nonuse Periods: Isolate ppb and ppm oxygen sensors as described in this manual and disconnect the power when the analyzer is left unused for a long period of time.
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Advanced Instruments Inc.
Gas analysis solutions through advanced analyzer and sensor technology
Technical Specifications
Accuracy: < 1% of FS range at constant conditions; inherent accu-
racy of 0.1% following calibration with 95-100% oxygen
Analysis: 0-100% full scale range; 50-100%, 80-100%, 90-100 sup-
Application: Continuous monitoring of high purity oxygen levels up to
Approvals: CE Area Classification: General purpose Alarms: 2 adjustable form C relay contacts non-latching; “weak
Calibration:
Compensation: Barometric pressure and temperature; temperature con-
Connections: Compression tube fittings 1/8” inlet; 1/4” vent Controls: Water resistant keypad; menu driven range selection,
Data Acquisition: Selectable data point intervals Display:
Enclosure: Painted aluminum 7.5” x 10.8” x 12.25” panel mount Flow Sensitivity: None between 1-3 SCFH, 2 SCFH recommended
Linearity: > .995 over all ranges Pressure: Inlet - regulate to 5-30 psig; vent - atmospheric
Power: Specify 100/120 or 220/240 VAC Response Time: 90% of final FS reading < 13 seconds Sample System: Flow control, flow indicator, special integral sample
Sensitivity: 0.1% oxygen Sensor Model: GPR-11-120-OP - requires no maintenance
Sensor Life: 24 months in 100% oxygen at 25ºC and 1 atm Signal Output: 4-20mA isolated and 0-1V Temp. Range: 5º to 45ºC Warranty: 12 months analyzer; 12 months sensor Wetted Parts: 316 stainless steel
Optional Equipment
Bezel for 19” rack mounting, wall mount NEMA4 and 4X enclosure Sample conditioning accessories - contac t factory
pressed ranges
100% oxygen in inert, helium, hydrogen and mixed gases
sensor” indicator; power failure; system failure Certified gas of O
oxygen for optimum accuracy; otherwise, O approximate 80% of full scale range
trolled heated sample system and sensor housing
calibration, alarm and system functions
Graphical LCD 5 x 2.75; resolution .01%; displays real time ambient temperature and pressure
temperature equalization system
balance N2 approximating 95-100%
2
content should
2
GPR-3100 Oxygen Purity Analyzer
Breakthrough Sensor Technology 24 month life at 100% Oxygen Levels Accuracy < 1% FS Range Sensitivity < 0.1% Oxygen No maintenance Inherent Accuracy 0.1% Following Calibration With 100% Oxygen 4 Standard Analysis Ranges including 3 Suppressed Ranges 50/80/90-100% Auto Zero, Span Calibration Temperature Controlled Sample System Pressure Compensated Remote Communication Link Certified ISO 9001 QA System
‘the only electrochemical
sensor based analyzer
capable of analyzing
> 99.5% pure oxygen
continuously 24/7
for 24 months‘
2855 Metropolitan Place, Pomona, CA 91767 USA Tel: 909-392-6900, Fax: 909-392-3665, www.aii1.com, e-mail: info@aii1.com Rev 5/05
Advanced Instruments Inc.
5 Operation
Principle of Operation
The GPR-3100 oxygen analyzer incorporates an advanced galvanic fuel cell type sensor capable of measuring 100% oxygen on a suppressed range of 90-100% on a continuous basis It is the only electrochemical sensor based analyzer capable of this measurement.
Background
The production of pure oxygen has been confined to the production of medical grade oxygen (99.0%, typically specified at 99.5% or greater purity). However, the demand for oxygen is expanding rapidly due largely to recent developments in chemical processes requiring elevated concentrations of oxygen (85­95%) that boost yields and reduce emissions without significant cost increases and to a lesser extent the growth of transfilling oxygen (92%) cylinders for home care use. The oxygen supplied can be be generated cryogenically or by pressure (PSA) or vacuum (VSA) swing adsorption methods.
Historically producers and users have relied on analyzers based on paramagnetic method for measuring oxygen purity. These sensor offer highly accurate results especially at the suppressed ranges of 90-100% oxygen. However, they are very sensitive to changes in the flow rate of sample gas, the presence of minute particulates and moisture, temperature variations and vibration. Consequently, paramagnetic analyzers are expensive and require frequent almost daily calibration.
Analyzers based on galvanic sensor concept have always generated an interest for oxygen purity measurements because they are specific to oxygen, versatile, low maintenance and inexpensive. However, short sensor life (3-4 months at best) and the gradual drop (drift) in the signal output of the micro-fuel cell with time has precluded their use.
Major Advancement in Galvanic Fuel Cell Sensor Technology
In competing with paramagnetic devices the focus was primarily on advancing the galvanic sensor technology but also included temperature controlling the sample gas and automatically compensating the signal output of the sensor for barometric pressure variations to assure a stable ‘drift free’ oxygen measurement.
An advanced galvanic sensor has been developed that provides two years of sensor life and is capable of operating properly on a continuous basis in 100% oxygen concentrations. This proprietary design addresses the challenges of:
Providing a sufficient amount of anode material to support the reduction of oxygen over several years. Maintaining at all times a sufficient concentration of hydroxyl ions to support the reduction of oxygen at
and near the sensing cathode. Preventing the build-up of PbO at and near the sensing cathode (that eventually starts precipitating and
covers the sensing cathode) that can cause the signal output of the sensor to drop (drift) with time. Through proprietary means the production rate of the reaction product is controlled without sacrificing
either the fast less than 13 second response time or any of the features (described above) of the micro­fuel cell analyzer. The resulting on-line and portable analyzers are approximately half the cost of their paramagnetic counterparts.
The performance of the sensor was validated over 14 months of testing and exhibited excellent stability in 100% oxygen. The sample flow rate was set at 0.1 lpm (and insensitive to changes of up to 1.0 lpm) with the sample vented to the atmosphere via ¼” diameter tube to minimize the backpressure.
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5 Operation
With the sensor and sample gas lines temperature controlled and the signal output of the sensor compensated for ambient pressure variations it was possible to measure oxygen in the suppressed range of 90-100% with less than + periodically and found to be within + scale over the fourteen month test period suggesting the interval between calibrations could be extended to several months.
To demonstrate the stability of the new analyzer, 99.5% oxygen was introduced (typically the threshhold for gas manufacturers) for 30 days and the output plotted as shown at the right. The resolution of the analyzer’s 4-1/2 digit display is 0.01%.
The maximum variation in the signal output is
0.1% oxygen over a 24 hour period and is
+ primarily to the variation in ambient temperature.
1% of full scale (+0.1% oxygen) accuracy. The calibration was checked
1% of full
100.00
99.00
98.00
97.00
% Oxy gen
96.00
95.00
94.00
93.00
92.00
91.00
90.00 2 5 8 11141720232629
30 Day Stability in
99.5% Oxyg en
90-100% Suppressed Range
Day s
Advanced Sensor Technology Overview:
The sensor function on the same principle and are specific for oxygen. They measure the partial pressure of oxygen from low ppm to 100% levels in inert gases, gaseous hydrocarbons, helium, hydrogen, mixed gases, acid gas streams and ambient air.
Oxygen, the fuel for this electrochemical transducer, diffusing into the sensor reacts chemically at the sensing electrode to produce an electrical current output proportional to the oxygen concentration in the gas phase. The sensor’s signal output is linear over all ranges and remains virtually constant over its useful life. The sensor requires no maintenance and is easily and safely replaced at the end of its useful life.
Proprietary advancements in design and chemistry add significant advantages to an extremely versatile oxygen sensing technology. Sensors for low ppm analysis recover from air to ppm levels in minutes, exhibit longer life and reliable quality.
The expected life of our new generation of percentage range sensors now range to five and ten years with faster response times and greater stability. Another significant development involves expanding the operating temperature range for percentage range sensors from -30°C to 50°C.
Electronics:
The signal generated by the sensor is processed by state of the art low power micro-processor based digital circuitry. The first stage amplifies the signal. The second stage eliminates the low frequency noise. The third stage employs a high frequency filter and compensates for signal output variations caused by ambient temperature changes. The result is a very stable signal.
Additional features of the micro-processor based electronics include manual or auto ranging, optional integral sample, span and zero inlet valves for auto-zero and auto-calibration at user specified intervals, data acquisition and temperature tracking all which can be controlled remotely. Analog outputs, 0-1V and an isolated 4-20mA, and an USB communication link are provided along with field selectable alarms with dry relay contacts, power and range identification. An unique algorithm predicts and display a message indicating a ‘weak sensor’ suggesting the sensor be replaced in the near future.
GPR-3100 Rev 2/05 2
Advanced Instruments Inc.
5 Operation
Sample System:
The GPR-3100 is supplied with stainless steel flow housing, fittings and tubing along with an integral flow meter to provide optimum percentage range oxygen measurements. As a rule of thumb, the sample must be properly presented to the sensor to ensure an accurate measurement. For optimum accuracy the overall performance is enhanced by an temperature controlled heater system that controls the temperature around the sensor to eliminate drift and daily calibration requirements associated with competitive analyzers.
Advanced Instruments Inc. offers a full line of sample handling, conditioning and expertise to meet your application requirements. Contact us at 909-392-6900 or e-mail us at aii2@earthlink.net
Controlling Pressure & Flow
All electrochemical oxygen sensors respond to partial pressure changes in oxygen. The inlet pressure must always be higher than the pressure at the outlet vent which is normally at atmospheric pressure. Despite the fact the oxygen reading is compensated for variations in barometric pressure (at the vent), it is extremely critical for suppressed range measurements of 90-100% that backpressure be kept to an absolute minimum. For this reason the analyzer is equipped with 1/8” inlet connections and ¼” vent connections.
Flow Through Configuration:
The sensor is exposed to sample gas that must flow or be drawn through metal or plastic tubing, see Application Pressure below, to the analyzer, through the analyzer’s internal sample system that includes an o-ring sealed stainless steel sensor housing and finally is normally vented to atmosphere.
Flow rates of 1-5 SCFH cause no appreciable change in the oxygen reading. However, flow rates above 5 SCFH generate backpressure and erroneous oxygen readings because the diameter of the integral tubing cannot evacuate the sample gas at the higher flow rate. A flow indicator with an integral metering valve upstream of the sensor is recommended as a means of controlling the flow rate of the sample gas. A flow rate of 2 SCFH or 1liter per minute is recommended for optimum performance.
Assure that the vent line is connected to a ¼” or larger tube and is vented to atmosphere, with the magnification associated with the use of suppressed ranges even the slightest amount of backpressure will adversely affect the oxygen reading.
Caution: Do not place your finger over the vent (it pressurizes the sensor) to test the flow indicator when gas is flowing to the sensor. Removing your finger (the restriction) generates a vacuum on the sensor and may damage the sensor (voiding the sensor warranty).
Application Pressure - Positive:
A flow indicator with an integral metering valve positioned upstream of the sensor is provided for controlling the sample flow rate between 1-5 SCFH. If necessary, a pressure regulator (with a metallic diaphragm is recommended to prevent high oxygen readings resulting from the use of diaphragms of more permeable materials) upstream of the flow control valve should be used to regulate the pressure.
Application Pressure - Atmospheric or Slightly Negative:
For accurate percentage range measurements, a sample pump is should be positioned downstream of the sample inlet to draw the sample from the process through the analyzer’s sample system and by the sensor. A flow indicator with an integral metering valve positioned downstream of the sensor is necessary to obtain the recommended flow rate between 1-5 SCFH. If pump loading is a consideration, a second
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Advanced Instruments Inc.
5 Operation
throttle valve on the pump’s inlet side may be necessary to provide a bypass path so the sample flow rate is within the above parameters.
An eductor jet pump is an alternative to a pump that is used in classified areas since it has no moving parts or to eliminate the maintenance associated with mechanical pumps. The eductor must be positioned downstream of the sample outlet. The eductor has three (3) orifices and requires a source of compressed gas which enters through the top and exits at the bottom while drawing a mild vacuum (and sample gas) through the side orifice. A flow indicator with an integral metering valve positioned downstream of the sensor is recommended for controlling the sample flow rate between 1-5 SCFH.
To avoid erroneous oxygen readings and damaging the sensor:
¾ Assure there are no restrictions in the sample line that could create and draw a vacuum exceeding
14” of water column on the sensor.
¾ Avoid excessive flow rates above 5 SCFH which generate backpressure on the sensor. ¾ Avoid sudden changes in pressure that can severely damage the sensor – assure a flow control valve
is positioned upstream of the analyzer’s inlet.
¾ Assure no particulates, liquids or condensation collect on the sensor that could block the diffusion of
oxygen into the sensor.
¾ Do not place your finger over the vent (it pressurizes the sensor) to test the flow indicator when gas
is flowing to the sensor. Removing your finger (the restriction) generates a vacuum on the sensor and may damage the sensor (voiding the sensor warranty).
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Advanced Instruments Inc.
5 Operation
Calibration and Accuracy
Single Point Calibration: As previously described the galvanic oxygen sensor generates an electrical current sensor exhibiting an absolute zero, e.g. the sensor does not generate a current output in the absence of oxygen. Given these linearity and absolute zero properties, single point calibration is possible.
Pressure: Because sensors are sensitive to the partial pressure of oxygen in the sample gas their output is a function of the number of molecules of oxygen 'per unit volume'. Readouts in percent are permissible only when the total pressure of the sample gas being analyzed remains constant. The pressure of the sample gas and that of the calibration gas(es) must be the same (reality < 1-2 psi).
Temperature: The rate oxygen molecules diffuse into the sensor is controlled by a Teflon membrane otherwise known as an 'oxygen diffusion limiting barrier' and all diffusion processes are temperature sensitive, the fact the sensor's electrical output will vary with temperature is normal. This variation is relatively constant 2.5% per ºC. A temperature compensation circuit employing a thermistor offsets this effect with an accuracy of +5% or better and generates an output function that is independent of temperature. There is no error if the calibration and sampling are performed at the same temperature or if the measurement is made immediately after calibration. Lastly, small temperature variations of 10-15º produce < +1% error.
Accuracy:
of errors: 1) those producing 'percent of reading errors', illustrated by Graph A below, such as + temperature compensation to make span adjustments and 2) those producing 'percent of full scale errors', illustrated by Graph B, such as +1-2% linearity errors in readout devices, which are really minimal due to today's technology and the fact that other errors are 'spanned out' during calibration.
GPR-3100 Rev 2/05 5
In light of the above parameters, the overall accuracy of an analyzer is affected by two types
5%
circuit, tolerances of range resistors and the 'play' in the potentiometer used
Advanced Instruments Inc.
5 Operation
Graph C illustrates these 'worse case' specifications that are typically used to develop an analyzer's overall accuracy statement of +2% of full scale at constant temperature or +5% over the operating temperature range. QC testing is typically <+0.5% prior to shipment.
Example: As illustrated by Graph A any error, play in the multi-turn span pot or the temperature compensation circuit, during a span adjustment at 20.9% (air) of full scale range would be multiplied by a factor of 4.78 (100/20.9) if used for measurements of 95-100% oxygen concentrations. Conversely, an error during a span adjustment at 100% of full scale range is reduced proportionately for measurements of lower oxygen concentrations.
Recommendation: The analyzer may be calibrated by using a certified span gas of 80-90% value of the range of analysis. For example, for analysis on 90-100% range, use 98-99% oxygen as the span gas and for analysis on 80-90% oxygen, use 96-98% oxygen as the span gas.
Note: The accuracy of the analyzer is given as the % of full-scale. Therefore, the calibration of the analyzer must be done on the range of analysis or one range above the range of analysis. The analysis of the sample gas must be carried out on the range that provides the required accuracy.
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5 Operation
Installation
The GPR-3100 Oxygen Analyzer consists of an electronic module, sensor housing and sample system housed in a 10.8”W x 7.5”H x 12.25”D enclosure suitable for panel mounting or 19” rack mounting with the optional panel. A 12”W x 12”H x 8”D wall mount configuration is also available.
An integral temperature controlled heating system maintains the temperature of the sensor at a pre-set temperature and assures the stability not found in competitive analyzers. The analyzer has been tested and calibrated by the manufacturer prior to shipment.
Installation Considerations: The GPR-3100 is fully operational from the shipping container with the oxygen sensor installed and
calibrated at the factory prior to shipment. Once installed, we recommend the user allow the analyzer to stabilize for 30 minutes and then recalibrate the device as instructed below.
¾ Mounting the analyzer and optional components such as coalescing or particulate filters and pumps. ¾ Assemble the necessary hardware for mounting the analyzer and optional components, 1/8” stainless
steel tubing for interconnecting the analyzer and optional components.
¾ Review the application conditions to ensure the sample is suitable for analysis. ¾ Temperature: The sample must be sufficiently cooled before it enters the analyzer and any optional
components. A coiled 10 foot length of ¼” stainless steel tubing is sufficient for cooling sample gases as high as 1,800ºF to ambient.
¾ Pressure & Flow: As described above. ¾ Moisture & Particulates: Prevent water and/or particulates from entering the sample system. They
can clog the tubing and damage the optional components such as pumps, scrubbers or sensors. Installation of a suitable coalescing or particulate filter is required to remove condensation, moisture and/or particulates from the sample gas to prevent erroneous analysis readings and damage to the sensor or optional components. Consult the factory for recommendations concerning the proper selection and installation of components.
¾ Contaminants: A gas scrubber and flow indicator with integral metering valve are required upstream
of the analyzer to remove interfering gases such as oxides of sulfur and nitrogen or hydrogen sulfide that can produce false readings and reduce the expected life of the sensor. Installation of a suitable scrubber is required to remove the contaminant from the sample gas to prevent erroneous analysis readings and damage to the sensor or optional components. Consult the factory for recommendations concerning the proper selection and installation of components.
¾ Gas connections: Inlet gas lines require 1/8” diameter metal tubing whereas ¼” diameter tubing is
required for the vent. Span gas and required accessories are the responsibility of the user.
¾ Power connection: To meet hazardous area classification and weatherproofing requirements install
the interconnection wiring in rigid conduit.
¾ Output connections. To assure proper grounding, connect the 4-20mA signal output to the external
power source before attempting calibration adjustments.
¾ Establishing power to the electronics. ¾ Setting the alarm values (if applicable). ¾ Zeroing the analyzer (required only for very low percentage range measurements). ¾ Calibrating the analyzer.
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