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Material Safety Data Sheet
PROPYLENE GLYCOL
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION:
Allan Chemical Corporation
235 Margaret King Ave.
Ringwood, NJ 07456
Tel.: 973-962-4014 Fax: 973-962-6820
E-Mail: allanchem@alla nchem.com
EMERGENCY TELEPHONE: CHEM-TEL: 800-255-3924
Effective Date: 11/10/12
Product: Propylene Glycol
2. COMPOSITION/INFORMATION ON INGREDIENTS:
Propylene Glycol – C.A.S. # 000057-55-6
Chemical Formula: C3H8O2
Synonyms: 1,2-propanediol; 1,2-dihdroxypropane; methyl glycol
Formula CAS No.: 57-55-6 Molecular Weight: 76.09
3. HAZARDOUS IDENTIFICATION
Colorless liquid. Odorless. Toxic fumes are released in fire situations.
Potential health effects - see Section 11 for toxicological data.
Eye: may cause slight transient (temporary) eye irritation. Corneal injury is
unlikely. Mists may cause eye irritation.
Skin: Prolonged contact is essentially nonirritating to skin. A single prolonged
exposure is not likely to result in material being absorbed through skin in
harmful amounts. Repeated exposures may cause flaking and softening of skin.
May be absorbed in potentially harmful amounts when applied in large quantities
to severe burns (second or third degree) over large areas of the body as part of
cream or other topical application. Absorption under such circumstances can
elevate serum osmolality and may result in osmotic shock.
Inhalation: At room temperature, vapors are minimal due to physical properties
Mists may cause irritation of upper respiratory tract.
Systemic: (other target organ) Effects: Repeated excessive ingestion may cause
central nervous system effects.
Cancer Information: Did not cause cancer in long-term animal studies.
Teratology (Birth Defects): Birth defects are unlikely. Exposures having no
:
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adverse effects on the mother, should have no effect on the fetus.
Reproductive Effects: In animal studies, it has been shown not to interfere with
Reproduction.
4. FIRST AID:
Eye: Flush eyes with plenty of water
Skin: Wash off in flowing water or shower
Ingestion: No adverse effects anticipated by this route of exposure incidental to
proper industrial handling.
Note To Physician: No specific antidote. Supportive care. Treatment based
on judgment of the physician in response to reactions of the patient.
5. FIRE FIGHTING MEASURES:
Flammable Properties
Flash Point: 218˚F, 102˚C
Method Used: PMCC
Auto-ignition Temperature: not determined
Flammability Limits
LFL: 2.6%
UFL: 12.5%
Hazardous Combustion Products: During a fire, smoke may contain the
original material in addition to unidentified toxic and/or irritating compounds.
Hazardous combustion products may include and are not limited to: aldehydes,
carbon monoxide.
Other Flammability Information: Violent steam generation or eruption may occur
upon application of direct water stream to hot liquids. Spills of these organic
liquids on hot fibrous insulations may lead to lowering of the auto-ignition
temperatures possibly resulting in spontaneous combustion.
Extinguishing Media: Water fog or fine spray. Carbon dioxide. Dry chemical.
Foam. Alcohol resistant foams (ATC type) are preferred if available. General-
purpose synthetic foams (including AFFF) or protein foams may function, but much
less effectively. Do not use direct water stream. Will spread fire.
Media To Be Avoided: Do not use direct water stream.
Fire Fighting Instructions: Keep people away. Isolate fire area and deny
unnecessary entry. Burning liquids may be moved by flushing with water to
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protect personnel and minimize property damage. Burning liquids may be
extinguished by dilution with water. Do not use direct water stream. May spread
fire.
Protective Equipment For Fire Fighters: Wear positive-pressure self-contained
breathing apparatus (SCBA) and protective fire fighting clothing (Includes fire
fighting helmet, coat, pants, boots and gloves). If protective equipment is not
available or not used, fight fire from a protected location or safe distance.
6. ACCIDENTAL RELEASE MEASURES:
(See Section 15 for Regulatory Information)
Protect People: Isolate Area.
Protect The Environment: Contain liquid to prevent contamination of soil, surface
water or ground water.
Cleanup: For small spills, clean up with absorbent material. Collect material in
suitable and properly labeled open containers. For large spills, dike and pump into
suitable and properly labeled containers.
7. Handling & Storage
Handling: Product handled hot may require additional ventilation or local exhaust.
Storage: Keep containers tightly closed when not in use. Store in stainless steel,
aluminum, plasite 3066 lined containers or 316 stainless steel.
8. Exposure Controls/Personal Protection
Engineering Controls: Provide general and/or local exhaust ventilation to control
airborne levels below the exposure guidelines.
Personal Protective Equipment:
Eye/Face Protection: Use safety glasses. Safety glasses should be sufficient for
most operations; howev er, for misty operations w ea r chemical goggles.
Skin Protection: Use gloves impervious to this material.
Respiratory Protection: Atmospheric levels should be maintained below the
exposure guideline. When respiratory protection is required for certain operations,
use an approved air-purifying respirator. In misty atmospheres, use an approved
mist respirator.
Exposure Guideline (s): Propylene glycol: AIHA WEEL is 50 ppm total, 10 mg/m3
aerosol only.
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9. Physical And Chemical Properties:
Appearance: colorless liquid
Odor: odorless
Vapor Pressure: 0.08 mmHg @ 20˚C, 68˚F
Vapor Density: 2.62
Boiling Point: 370˚F, 188˚C
Solubility In Water: Complete
Specific Gravity: 1.038 20/20˚c. 68˚F
10. Stability & Reactivity
Chemical Stability : Stable
Conditions To Avoid: Product and decompose at elevated temperatures.
Incompatibility With Other Materials: Avoid contact with oxidizing materials.
Hazardous Decomposition Products: When available oxygen is limited, as in a
fire or when heated to very high temperatures by hot wire or plate, carbon
monoxide and other hazardous compounds such as aldehydes might be generated.
Hazardous Polmerization: Will not occur.
11. Toxicological Information
(See section 3 for potential health effects.) For detailed toxicological data, write
or call the address or non-emergency member shown in section 1.
Skin: The LD50 for skin absorption in rabbits is >10,000 mg/kg.
Ingestion: The vitro mutagenicity studies were negative. Animal mutagenicity
studies were negative.
12. Ecological Information:
(For detailed ecological data, write or call the address or non-emergency number
shown in section 1.)
Environmental Fate
Movement & Partitioning: Based largely or completely on information for similar
materials, i.e. propylene glycol. Bioconcentration potential is low (BCF less than
100 or log Pow less than 3). Log Octanol/water partition coefficient (log Pow) is
–0.92. Henry’s Law Constant (H) is 1,2E-8 atm.m3/mole.
Degradation & Persistence: Based largely or completely on information for similar
material (s), i.e. propylene glycol. Biodegration under aerobic static laboratory
conditions is high (BOD2O or BOD28/ThOD greater than 40%). Biodegradation is
expected to be achievable in a secondary wastewater treatment plant. 5-Day
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biochemical demand (BOD5 is 1.16 p/p. 20-Day biochemical oxygen demand
(BOD20 is 1.45 p/p. Theoretical oxygen demand (thOD) is calculated to be 1.68
p/p. Inhibitory concentration (IC50) in OECD Activated Sludge Respiration
Inhibition /Test (OECD Test 209) is greater than 1 gm/L. Degradation is expected
in atmospheric environment within minutes to hours.
Ecotoxicity: Based largely or completely in information for similar material (S), I.E.
propylene glycol. Material is practically non-toxic to aquatic organisms on an acute
basis. (LC50 greater than 100 mg/L in most sensitive species.)
Acute LC50 for fathead minnow (Pimephales promelas) is 46500-54900 mg/L.
Acute LC50 for guppy (Poecilia reticulate) is greater than 1000 mg/L.
Acute LC50 for water flea (Daphnia magna) is 4850-34400 mg\L.
Acute LC50 for rainbow trout (Oncorhynchus mykiss) is 44 mL/L (about 44000
mg/L.
13. Disposal Considerations
(See section 15 for Regulatory Information.)
Disposal: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY
BODY OF WATER. All disposal methods must be in compliance with all Federal,
State/Provincial and local laws and regulations. Regulations may vary in different
locations. Waste characterizations and compliance laws are the responsibility
solely of the waste generator. ALLAN CHEMICAL CORPORATION HAS NO
CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES
OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION
PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBE D IN MSDS SECTION 2
(Composition/Information On Ingredients)
FOR USED & UNCONTAMINATED PRODUCT, the preferred options include sending
to a licensed, permitted: recycler, reclaimer, incinerator, and wastewater
treatment system.
14. Transport Infor m a tion
DEPARTMENT OF TRANSPORTATION: This product is not regulated by D.O.T. when
shipped by land.
CANADIAN TDG INFORMATION: For TDG regulatory information, if required,
consult transportation regulations and product shipping papers.
15. Regulatory Information
(Not meant to be all-inclusive—selected regulations represented)
Effective Date: November 2003
NOTICE: The information herein is presented in good faith and believed to be
accurate as of the effective date shown above. However, no warranty, express or
implied is given. Regulatory requirements are subject to change and may differ
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from one location to another; it is the buyer’s responsibility to ensure that its
activities comply with federal, state or provincial and local laws. The following
specific information is made for the purpose of complying with numerous federal,
state or provincial and local laws and regulations. See other sections for health
and safety information.
U.S. Regulations:
SARA 313 Information: To the best of our knowledge, this product contains no
chemical subject to SARA Title III Section 313 supplier notification requirements.
SARA HAZARD CATEGORY: This product has been reviewed according to the EPA
“’Hazard Categories” promulgated under Sections 311 and 312222 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is
considered, under applicable definitions, to meet the following categories:
Not to have met any hazard category
TOXIC SUBSTANCES CONTROL ACT (TSCA):
All ingredients are on the TSCA inventory or are not required to be listed on the
TSCA inventory.
STATE RIGHT-TO-KNOW: The following product components are cited on certain
lists as mentioned. Non-listed components may be shown in the composition
section off the MSDS.
CHEMICAL NAME: CAS NUMBER LIST
1,2-PROPANDIOL 000057-55-6 PA1
PA1=Pennsylvania Hazardous Substance (present at greater than or equal to 1.0%
CANADIAN REGULATIONS
WHMIS INFORMATION: The Canadian Workplace Hazardous Materials Information
System (WHMIS) Classification for this p ro du ct:
This product is not a “Controlled Product” under WHMIS.
16. OTHER INFORMATION
MSDS STATUS: Revised Section 13, Disposal
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