3M B2184896, B2184850 User Manual

3M™ Abrasive Products, 747D PG Wheels 08/29/16

__________________________________________________________________________________________

Page 1 of 10

Safety Data Sheet

Copyright,2016,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group:

28-1670-0

Version Number:

1.06

Issue Date:

08/29/16

Supercedes Date:

08/26/16

SECTION 1: Identification

1.1. Product identifier

3M™ Abrasive Products, 747D PG Wheels

1.2. Recommended use and restrictions on use

Recommended use

Abrasive Product

1.3. Supplier’s details
MANUFACTURER:

3M

DIVISION:

Abrasive Systems Division

ADDRESS:

3M Center, St. Paul, MN 55144-1000, USA

Telephone:

1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or [phone] (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classification

Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.

2.2. Label elements

Signal word

Not applicable.

Symbols

Not applicable.

Pictograms

Not applicable.

2.3. Hazards not otherwise classified

None.

26% of the mixture consists of ingredients of unknown acute oral toxicity.

3M™ Abrasive Products, 747D PG Wheels 08/29/16

__________________________________________________________________________________________

Page 2 of 10

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt

Ceramic Aluminum Oxide / Aluminum Oxide Mineral
Blend (non-fibrous)

1344-28-1 10 - 35

Filler 13983-17-0 2 - 15
Filler 1332-58-7 0.2 - 1.5
Filler 1317-65-3 0.1 - 1.5
Inorganic Fluoride 14075-53-7 2 - 10
Inorganic Fluoride 15096-52-3 1 - 10
Titanium Dioxide 13463-67-7 0.1 - 1.5
Pigment 1332-37-2 0.1 - 1.5
Cured Resin Mixture 5 - 30
Cloth Backing None 3 - 25
Steel Shank Mixture 20 - 50

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:

Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:

Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye Contact:

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If Swallowed:

No need for first aid is anticipated.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media

In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Fluoride During Combustion

3M™ Abrasive Products, 747D PG Wheels 08/29/16

__________________________________________________________________________________________

Page 3 of 10

5.3. Special protective actions for fire-fighters

When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective
clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants,
bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Observe precautions from other sections.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Not applicable.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Do not breathe thermal decomposition products. For industrial or professional use only. Avoid breathing of dust created by
sanding, grinding or machining. Damaged product can break apart during use and cause serious injury to face or eyes. Check
product for damage such as cracks or nicks prior to use. Replace if damaged. Always wear eye and face protection when
working at sanding or grinding operations or when near such operations. Avoid release to the environment. Combustible
dust may form by action of this product on another material (substrate). Dust generated from the substrate during use of this
product may be explosive if in sufficient concentration with an ignition source. Dust deposits should not be allowed to
accumulate on surfaces because of the potential for secondary explosions.

7.2. Conditions for safe storage including any incompatibilities

No special storage requirements.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.

Ingredient C.A.S. No. Agency Limit type Additional Comments

Filler 1317-65-3 OSHA TWA(as total dust):15

mg/m3;TWA(respirable
fraction):5 mg/m3

Filler 1332-58-7 ACGIH TWA(respirable fraction):2

mg/m3

A4: Not class. as human
carcin

KAOLIN, TOTAL DUST 1332-58-7 OSHA TWA(as total dust):15

mg/m3;TWA(respirable

fraction):5 mg/m3
Ceramic Aluminum Oxide /
Aluminum Oxide Mineral Blend
(non-fibrous)

1344-28-1 OSHA TWA(as total dust):15

mg/m3;TWA(respirable

fraction):5 mg/m3
Aluminum, insoluble compounds 1344-28-1 ACGIH TWA(respirable fraction):1

mg/m3

A4: Not class. as human

carcin
Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3
Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human

3M™ Abrasive Products, 747D PG Wheels 08/29/16

__________________________________________________________________________________________

Page 4 of 10

carcin
FLUORIDES 15096-52-3 OSHA TWA(as dust):2.5

mg/m3;TWA(as F):2.5 mg/m3

FLUORIDES 15096-52-3 ACGIH TWA(as F):2.5 mg/m3 A4: Not class. as human

carcin
Aluminum, insoluble compounds 15096-52-3 ACGIH TWA(respirable fraction):1

mg/m3

A4: Not class. as human

carcin

ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

For those situations where the material might be exposed to extreme overheating due to misuse or equipment failure, use with
appropriate local exhaust ventilation sufficient to maintain levels of thermal decomposition products below their exposure
guidelines. Provide appropriate local exhaust ventilation for sanding, grinding or machining. Use general dilution ventilation
and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control
dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide local exhaust at
process emission sources to control exposure near the source and to prevent the escape of dust into the work area. Ensure that
dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to
prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).

8.2.2. Personal protective equipment (PPE)

Eye/face protection

To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding
operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an
exposure assessment. The following eye/face protection(s) are recommended:
Safety Glasses with side shields

Skin/hand protection

Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or
sanding.

Respiratory protection

Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when
determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure.
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
General Physical Form:

Solid

Odor, Color, Grade:

Solid Abrasive Product

3M™ Abrasive Products, 747D PG Wheels 08/29/16

__________________________________________________________________________________________

Page 5 of 10

Odor threshold

Not Applicable

pH

Not Applicable

Melting point

Not Applicable

Boiling Point

Not Applicable

Flash Point

Not Applicable

Evaporation rate

Not Applicable

Flammability (solid, gas)

Not Classified

Flammable Limits(LEL)

Not Applicable

Flammable Limits(UEL)

Not Applicable

Vapor Pressure

Not Applicable

Vapor Density

Not Applicable

Specific Gravity

Not Applicable

Solubility In Water

Not Applicable

Solubility- non-water

Not Applicable

Partition coefficient: n-octanol/ water

Not Applicable

Autoignition temperature

Not Applicable

Decomposition temperature

Not Applicable

Viscosity

Not Applicable

SECTION 10: Stability and reactivity

10.1. Reactivity

This material is considered to be non reactive under normal use conditions.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

None known.

10.5. Incompatible materials

None known.

10.6. Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition
product.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

3M™ Abrasive Products, 747D PG Wheels 08/29/16

__________________________________________________________________________________________

Page 6 of 10

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:

Dust from grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Skin Contact:

Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.

Eye Contact:

Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.

Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling,

pain, tearing, and blurred or hazy vision.

Ingestion:

No known health effects.

Carcinogenicity:

Ingredient CAS No. Class Description Regulation

Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer

Additional Information:

This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material
being abraded must also be considered.

This product contains titanium dioxide. Cancer of the lungs has been observed in rats that inhaled high levels of titanium
dioxide. No exposure to inhaled titanium dioxide is expected during the normal handling and use of this product. Titanium
dioxide was not detected when air sampling was conducted during simulated use of similar products containing titanium
dioxide. Therefore, the health effects associated with titanium dioxide are not expected during the normal use of this product.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
Ceramic Aluminum Oxide / Aluminum Oxide Mineral Blend

(non-fibrous)

Dermal LD50 estimated to be > 5,000 mg/kg

Ceramic Aluminum Oxide / Aluminum Oxide Mineral Blend
(non-fibrous)

Inhalation­Dust/Mist
(4 hours)

Rat LC50 > 2.3 mg/l

Ceramic Aluminum Oxide / Aluminum Oxide Mineral Blend
(non-fibrous)

Ingestion Rat LD50 > 5,000 mg/kg

Filler Dermal LD50 estimated to be > 5,000 mg/kg
Filler Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Inorganic Fluoride Dermal LD50 estimated to be > 5,000 mg/kg
Inorganic Fluoride Inhalation-

Dust/Mist
(4 hours)

Rat LC50 > 5.3 mg/l

Inorganic Fluoride Ingestion Rat LD50 5,854 mg/kg
Inorganic Fluoride Dermal Rabbit LD50 > 2,100 mg/kg
Inorganic Fluoride Inhalation- Rat LC50 4.5 mg/l

3M™ Abrasive Products, 747D PG Wheels 08/29/16

__________________________________________________________________________________________

Page 7 of 10

Dust/Mist

(4 hours)
Inorganic Fluoride Ingestion Rat LD50 5,000 mg/kg
Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg
Titanium Dioxide Inhalation-

Dust/Mist

(4 hours)

Rat LC50 > 6.82 mg/l

Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg
Pigment Dermal Not

available

LD50 3,100 mg/kg

Pigment Ingestion Not

available

LD50 3,700 mg/kg

Filler Dermal LD50 estimated to be > 5,000 mg/kg
Filler Ingestion Human LD50 > 15,000 mg/kg

Filler Dermal Rat LD50 > 2,000 mg/kg
Filler Inhalation-

Dust/Mist

(4 hours)

Rat LC50 3 mg/l

Filler Ingestion Rat LD50 6,450 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

Ceramic Aluminum Oxide / Aluminum Oxide Mineral Blend (non-fibrous) Rabbit No significant irritation
Inorganic Fluoride Rabbit No significant irritation
Inorganic Fluoride Multiple

animal
species

No significant irritation

Titanium Dioxide Rabbit No significant irritation
Pigment Rabbit No significant irritation
Filler Professio

nal
judgeme
nt

No significant irritation

Filler Rabbit No significant irritation

Serious Eye Damage/Irritation

Name Species Value

Ceramic Aluminum Oxide / Aluminum Oxide Mineral Blend (non-fibrous) Rabbit No significant irritation
Inorganic Fluoride Rabbit No significant irritation
Inorganic Fluoride Rabbit Mild irritant
Titanium Dioxide Rabbit No significant irritation
Pigment Rabbit No significant irritation
Filler Professio

nal
judgeme
nt

No significant irritation

Filler Rabbit No significant irritation

Skin Sensitization

Name Species Value

Titanium Dioxide Human

and
animal

Not sensitizing

Pigment Human Some positive data exist, but the data are not

sufficient for classification

Respiratory Sensitization

For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity

3M™ Abrasive Products, 747D PG Wheels 08/29/16

__________________________________________________________________________________________

Page 8 of 10

Name Route Value

Ceramic Aluminum Oxide / Aluminum Oxide Mineral Blend (non-fibrous) In Vitro Not mutagenic
Filler In Vitro Not mutagenic
Titanium Dioxide In Vitro Not mutagenic
Titanium Dioxide In vivo Not mutagenic
Pigment In Vitro Not mutagenic

Carcinogenicity

Name Route Species Value

Ceramic Aluminum Oxide / Aluminum Oxide Mineral Blend (non­fibrous)

Inhalation Rat Not carcinogenic

Titanium Dioxide Ingestion Multiple

animal
species

Not carcinogenic

Titanium Dioxide Inhalation Rat Carcinogenic
Pigment Inhalation Human Some positive data exist, but the data are not

sufficient for classification

Filler Inhalation Multiple

animal
species

Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure

Duration

Filler Ingestion Not toxic to development Rat NOAEL 625

mg/kg/day

premating &
during
gestation

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration

Filler Inhalation respiratory system All data are negative Rat NOAEL

0.812 mg/l

90 minutes

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration

Ceramic Aluminum Oxide
/ Aluminum Oxide Mineral
Blend (non-fibrous)

Inhalation pneumoconiosis |

pulmonary fibrosis

Some positive data exist, but the
data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

Filler Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

Filler Inhalation pulmonary fibrosis All data are negative Human

and
animal

NOAEL Not
available

Inorganic Fluoride Inhalation bone, teeth, nails,

and/or hair

Causes damage to organs through
prolonged or repeated exposure

Rat NOAEL

0.0005 mg/l

5 months

Inorganic Fluoride Inhalation respiratory system Causes damage to organs through

prolonged or repeated exposure

Rat NOAEL

0.00021 mg/l

90 days

Inorganic Fluoride Ingestion bone, teeth, nails,

and/or hair

Causes damage to organs through
prolonged or repeated exposure

Rat LOAEL 0.58

mg/kg/day

14 weeks

Titanium Dioxide Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Rat LOAEL 0.01

mg/l

2 years

Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not

available

occupational
exposure

Pigment Inhalation pulmonary fibrosis |

pneumoconiosis

Some positive data exist, but the
data are not sufficient for

Human NOAEL Not

available

occupational
exposure

3M™ Abrasive Products, 747D PG Wheels 08/29/16

__________________________________________________________________________________________

Page 9 of 10

classification

Filler Inhalation pneumoconiosis Causes damage to organs through

prolonged or repeated exposure

Human NOAEL NA occupational

exposure

Filler Inhalation pulmonary fibrosis Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL Not

available

Filler Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

Aspiration Hazard

For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

The substrate that was abraded must be considered as a factor in the disposal method for this product. Incinerate in a
permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes.
Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials.
As a disposal alternative, utilize an acceptable permitted waste disposal facility.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

Not regulated per U.S. DOT, IATA or IMO.

These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M
transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of applicable
current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to
transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified
for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory
requirements.

SECTION 15: Regulatory information

15.1. US Federal Regulations

Contact 3M for more information.

3M™ Abrasive Products, 747D PG Wheels 08/29/16

__________________________________________________________________________________________

Page 10 of 10

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No

15.2. State Regulations

Contact 3M for more information.

15.3. Chemical Inventories

This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.

Contact 3M for more information.

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification
Health: 0 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard Classification

Health: 0 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section.

Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV
program. HMIS® is a registered mark of the American Coatings Association (ACA).

Document Group:

28-1670-0

Version Number:

1.06

Issue Date:

08/29/16

Supercedes Date:

08/26/16

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com