3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
__________________________________________________________________________________________
Page 1 of 12
Safety Data Sheet
Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
11-6904-4
Version Number:
27.03
Issue Date:
11/06/15
Supercedes Date:
11/06/15
SECTION 1: Identification
1.1. Product identifier
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X,
666X, 666XW, 668X(PSA)
Product Identification Numbers
60-0000-1234-8, 60-0000-1235-5, 60-0000-1236-3, 60-0000-1282-7, 60-0000-1283-5, 60-0000-1284-3, 60-0000-1325-4, 600000-1326-2, 60-0000-1327-0, 60-0000-1328-8, 60-0000-1329-6, 60-0000-1330-4, 60-0000-1331-2, 60-0000-1332-0, 600000-1390-8, 60-0000-1585-3, 60-0000-1586-1, 60-0000-1600-0, 60-0000-1601-8, 60-0000-1602-6, 60-0000-2374-1, 600000-2412-9, 60-0000-2413-7, 60-0000-2414-5, 60-0000-2852-6, 60-0000-2855-9, 60-0000-2856-7, 60-0000-2857-5, 600000-2858-3, 60-0000-2859-1, 60-0000-4992-8, 60-0000-4993-6, 60-0000-5898-6, 60-0000-6139-4, 60-0000-6741-7, 600000-6742-5, 60-0000-7158-3, 60-0000-7592-3, 60-0000-7616-0, 60-0000-7630-1, 60-0000-7641-8, 60-0000-7642-6, 600000-7643-4, 60-0000-7644-2, 60-0000-7645-9, 60-0000-7646-7, 60-0000-7647-5, 60-0000-7648-3, 60-0000-7904-0, 600000-7905-7, 60-0000-9437-9, 60-0000-9732-3, 60-0001-2151-1, 60-0001-2152-9, 60-0001-2153-7, 60-0001-2154-5, 600001-2155-2, 60-0001-2156-0, 60-0001-2157-8, 60-0001-2255-0, 60-0001-3925-7, 60-0001-3926-5, 60-0001-4846-4, 600003-3615-0, 60-0003-3617-6, 60-0003-3618-4, 60-0003-3619-2, 60-0006-0002-7, 60-0006-0003-5, 60-0006-0008-4, 600006-0009-2, 60-0006-0022-5, 60-0006-0023-3, 60-0006-0031-6, 60-0006-0083-7, 60-0006-0084-5, 60-0006-0085-2, 600006-0086-0, 60-0006-0087-8, 60-0006-0088-6, 60-0006-0089-4, 60-0006-0090-2, 60-0006-0091-0, 60-0006-0092-8, 600200-0074-5, 60-0200-0162-8, 60-0200-0372-3, 60-0200-0379-8, 60-0200-0380-6, 60-0200-0382-2, 60-0200-0384-8, 600200-0387-1, 60-0200-0388-9, 60-0200-0389-7, 60-0200-0390-5, 60-0200-0392-1, 60-0200-0396-2, 60-0200-0397-0, 600200-0398-8, 60-0200-0399-6, 60-0200-0400-2, 60-0200-0401-0, 60-0200-0402-8, 60-0200-0403-6, 60-0200-0404-4, 600200-0405-1, 60-0200-0406-9, 60-0200-0407-7, 60-0200-0409-3, 60-0200-0413-5, 60-0200-0414-3, 60-0200-0415-0, 600200-0416-8, 60-0200-0418-4, 60-0200-0419-2, 60-0200-0420-0, 60-0200-0421-8, 60-0200-0422-6, 60-0200-0424-2, 600200-0425-9, 60-0200-0426-7, 60-0200-0427-5, 60-0200-0428-3, 60-0200-0432-5, 60-0200-0435-8, 60-0200-0436-6, 600200-0437-4, 60-0200-0438-2, 60-0200-0439-0, 60-0200-0440-8, 60-0200-0441-6, 60-0200-0501-7, 60-0200-0515-7, 600200-0517-3, 60-0200-0518-1, 60-0200-0519-9, 60-0200-0520-7, 60-0200-0521-5, 60-0200-0522-3, 60-0200-0523-1, 600200-0524-9, 60-0200-0525-6, 60-0200-0526-4, 60-0200-0528-0, 60-0200-0529-8, 60-0200-0530-6, 60-0200-0531-4, 600200-0532-2, 60-0200-0533-0, 60-0200-0534-8, 60-0200-0536-3, 60-0200-0537-1, 60-0200-0538-9, 60-0200-0540-5, 600200-0541-3, 60-0200-0543-9, 60-0200-0544-7, 60-0200-0545-4, 60-0200-0548-8, 60-0200-0549-6, 60-0200-0550-4, 600200-0551-2, 60-0200-0552-0, 60-0200-0553-8, 60-0200-0554-6, 60-0200-0586-8, 60-0200-0587-6, 60-0200-0588-4, 600200-0589-2, 60-0200-0591-8, 60-0200-0592-6, 60-0200-0593-4, 60-0200-0594-2, 60-0200-0598-3, 60-0200-0599-1, 600200-0600-7, 60-0200-0601-5, 60-0200-0604-9, 60-0200-0605-6, 60-0200-0606-4, 60-0200-0607-2, 60-0200-0608-0, 600200-0610-6, 60-0200-0611-4, 60-0200-0612-2, 60-0200-0613-0, 60-0200-0753-4, 60-0200-0757-5, 60-0200-0758-3, 600200-0761-7, 60-0200-0762-5, 60-0200-0763-3, 60-0200-0765-8, 60-0200-0766-6, 60-0200-0767-4, 60-0200-0768-2, 600200-0777-3, 60-0200-0920-9, 60-0200-0926-6, 60-0200-0933-2, 60-0200-0935-7, 60-0200-0938-1, 60-0200-0942-3, 600200-0943-1, 60-0200-0948-0, 60-0200-0950-6, 60-0200-0954-8, 60-0200-0956-3, 60-0200-0957-1, 60-0200-0958-9, 600200-0959-7, 60-0200-0960-5, 60-0200-0961-3, 60-0200-0963-9, 60-0200-0964-7, 60-0200-0967-0, 60-0200-0975-3, 600200-0978-7, 60-0200-0979-5, 60-0200-0989-4, 60-0200-0990-2, 60-0200-1004-1, 60-0200-1007-4, 60-0200-1008-2, 60-
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
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Page 2 of 12
0200-1009-0, 60-0200-1010-8, 60-0200-1023-1, 60-0200-1025-6, 60-0200-1033-0, 60-0200-1041-3, 60-0200-1044-7, 600200-1046-2, 60-0200-1047-0, 60-0200-1048-8, 60-0200-1050-4, 60-0200-1051-2, 60-0200-1052-0, 60-0200-1058-7, 600200-1060-3, 60-0200-1061-1, 60-0200-1065-2, 60-0200-1068-6, 60-0200-1070-2, 60-0200-1071-0, 60-0200-1080-1, 600200-1081-9, 60-0200-1082-7, 60-0200-1083-5, 60-0200-1085-0, 60-0200-1086-8, 60-0200-1091-8, 60-0200-1096-7, 600200-1102-3, 60-0200-1111-4, 60-0200-1112-2, 60-0200-1117-1, 60-0200-1136-1, 60-0200-1139-5, 60-0200-1140-3, 600200-1141-1, 60-0200-1145-2, 60-0200-1148-6, 60-0200-1154-4, 60-0200-1155-1, 60-0200-1156-9, 60-0200-1157-7, 600200-1158-5, 60-0200-1160-1, 60-0200-1165-0, 60-0200-1172-6, 60-0200-1179-1, 60-0200-1180-9, 60-0200-1181-7, 600200-1186-6, 60-0200-1187-4, 60-0200-1188-2, 60-0200-1189-0, 60-0200-1190-8, 60-0200-1191-6, 60-0200-1192-4, 600200-1193-2, 60-0200-1194-0, 60-0200-1201-3, 60-0200-1203-9, 60-0200-1204-7, 60-0200-1205-4, 60-0200-1207-0, 600200-1214-6, 60-0200-1215-3, 60-0200-1216-1, 60-0200-1217-9, 60-0200-1222-9, 60-0200-1223-7, 60-0200-1224-5, 600200-1225-2, 60-0200-1226-0, 60-0200-1232-8, 60-0200-1235-1, 60-0200-1237-7, 60-0200-1263-3, 60-0200-1271-6, 600200-1273-2, 60-0200-1274-0, 60-0200-1275-7, 60-0200-1277-3, 60-0200-1278-1, 60-0200-1279-9, 60-0200-1280-7, 600200-1281-5, 60-0200-1282-3, 60-0200-1283-1, 60-0200-1284-9, 60-0200-1285-6, 60-0200-1286-4, 60-0200-1288-0, 600200-1289-8, 60-0200-1290-6, 60-0200-1294-8, 60-0200-1329-2, 60-0200-1450-6, 60-0200-1454-8, 60-0200-1489-4, 600200-1491-0, 60-0200-1500-8, 60-0200-1509-9, 60-0200-1510-7, 60-0200-1539-6, 60-0200-1545-3, 60-0200-1547-9, 600200-1548-7, 60-0200-1646-9, 60-0200-1647-7, 60-0200-1675-8, 60-0200-1676-6, 60-0200-1677-4, 60-0200-1692-3, 600200-1693-1, 60-0200-1694-9, 60-0200-1696-4, 60-0200-1708-7, 60-0200-1709-5, 60-0200-1710-3, 60-0200-1711-1, 600200-2160-0, 60-0700-0510-7, 60-0700-0514-9, 60-0700-0823-4, 60-0700-0824-2, 60-0700-0825-9, 60-0700-0826-7, 600700-0830-9, 60-0700-0831-7, 60-0700-0833-3, 60-0700-0834-1, 60-0700-0835-8, 60-0700-0837-4, 60-0700-0838-2, 600700-0842-4, 60-0700-0843-2, 60-0700-0844-0, 60-0700-0845-7, 60-0700-0846-5, 60-0700-0847-3, 60-0700-0848-1, 600700-0851-5, 60-0700-0852-3, 60-0700-0853-1, 60-0700-0855-6, 60-0700-0856-4, 60-0700-0857-2, 60-0700-0858-0, 600700-0862-2, 60-0700-0863-0, 60-0700-0920-8, 60-0700-0921-6, 60-0700-0922-4, 60-0700-0923-2, 60-0700-0924-0, 600700-0926-5, 60-0700-0927-3, 60-0700-0929-9, 60-0700-0930-7, 60-0700-0931-5, 60-0700-0932-3, 60-0700-0933-1, 600700-0934-9, 60-0700-0935-6, 60-0700-0936-4, 60-0700-0938-0, 60-0700-0940-6, 60-0700-0941-4, 60-0700-0942-2, 600700-0951-3, 60-0700-0973-7, 60-0700-0974-5, 60-0700-1023-0, 60-0700-1024-8, 60-0700-1025-5, 60-0700-1028-9, 600700-1029-7, 60-6500-2568-1, 60-6500-2569-9, 60-6500-2571-5, 60-6500-2572-3, 60-6500-2573-1, 60-6500-2574-9, XC0047-0314-3, XC-0315-1394-5, XC-0315-1706-0
1.2. Recommended use and restrictions on use
Recommended use
Abrasive Product
1.3. Supplier’s details
MANUFACTURER:
3M
DIVISION:
Electronics Materials Solutions Division
ADDRESS:
3M Center, St. Paul, MN 55144-1000, USA
Telephone:
1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Skin Sensitizer: Category 1.
2.2. Label elements
Signal word
Warning
Symbols
Exclamation mark |
Pictograms
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
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Hazard Statements
May cause an allergic skin reaction.
Precautionary Statements
Prevention:
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves.
Contaminated work clothing must not be allowed out of the workplace.
Response:
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Specific treatment (see Notes to Physician on this label).
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
2.3. Hazards not otherwise classified
None.
40% of the mixture consists of ingredients of unknown acute oral toxicity.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
2,2-DIMETHOXY-2-PHENYLACETOPHENONE 24650-42-8 Trade Secret *
2-ETHYLHEXYL ACRYLATE 103-11-7 Trade Secret *
ACRYLIC ACID 79-10-7 Trade Secret *
DIAMOND 7782-40-3 Trade Secret *
ETHYLENE-VINYL ACETATE POLYMER 24937-78-8 Trade Secret *
POLYESTER FILM BACKING 25038-59-9 Trade Secret *
PSA 25134-51-4 Trade Secret *
TITANIUM DIOXIDE 13463-67-7 Trade Secret *
DYE (SOME PRODUCTS SUPPLIED WITHOUT
DYES)
None Trade Secret *
POLYMERIC RESIN (CURED) None Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
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Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and
health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Not applicable.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing of dust created by sanding, grinding or machining. Avoid breathing
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
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release to the environment. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
2-ETHYLHEXYL ACRYLATE 103-11-7 Manufacturer
determined
CEIL:5 ppm Skin Notation
TITANIUM DIOXIDE 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human
carcin
TITANIUM DIOXIDE 13463-67-7 CMRG TWA(as respirable dust):5
mg/m3
TITANIUM DIOXIDE 13463-67-7 OSHA TWA(as total dust):15 mg/m3
2,2-DIMETHOXY-2PHENYLACETOPHENONE
24650-42-8 CMRG TWA:10 mg/m3
POLYESTER FILM BACKING 25038-59-9 CMRG TWA(as respirable dust):5
mg/m3;TWA(as total dust):10
mg/m3
ACRYLIC ACID 79-10-7 Manufacturer
determined
STEL:5 ppm(15 mg/m3)
ACRYLIC ACID 79-10-7 ACGIH TWA:2 ppm A4: Not class. as human
carcin, Skin Notation
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding
operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an
exposure assessment. The following eye/face protection(s) are recommended:
Safety Glasses with side shields
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
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Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Nitrile Rubber
Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective
clothing material(s) are recommended: Apron – Nitrile
Respiratory protection
Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when
determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure.
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form:
Solid
Odor, Color, Grade:
Thin film backed abrasive, color varies by grade, no odor
Odor threshold
Not Applicable
pH
Not Applicable
Melting point
Not Applicable
Boiling Point
Not Applicable
Flash Point
Not Applicable
Flammability (solid, gas)
Not Classified
Flammable Limits(LEL)
Not Applicable
Flammable Limits(UEL)
Not Applicable
Vapor Pressure
Not Applicable
Vapor Density
Not Applicable
Specific Gravity
No Data Available
Solubility In Water
Not Applicable
Solubility- non-water
Not Applicable
Partition coefficient: n-octanol/ water
Not Applicable
Autoignition temperature
Not Applicable
Decomposition temperature
Not Applicable
Percent volatile
Not Applicable
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
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None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Dust from grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin Contact:
Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Photosensitization: Signs/symptoms may include a sunburn-like reaction such as blistering, redness, swelling, and itching
from minor exposure to sunlight.
Eye Contact:
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.
Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling,
pain, tearing, and blurred or hazy vision.
Ingestion:
No health effects are expected.
Carcinogenicity:
Ingredient CAS No. Class Description Regulation
TITANIUM DIOXIDE 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer
Additional Information:
This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material
being abraded must also be considered.
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
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This product contains titanium dioxide. Cancer of the lungs has been observed in rats that inhaled high levels of titanium
dioxide. No exposure to inhaled titanium dioxide is expected during the normal handling and use of this product. Titanium
dioxide was not detected when air sampling was conducted during simulated use of similar products containing titanium
dioxide. Therefore, the health effects associated with titanium dioxide are not expected during the normal use of this product.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
POLYESTER FILM BACKING Dermal LD50 estimated to be > 5,000 mg/kg
POLYESTER FILM BACKING Ingestion Rat LD50 > 5,000 mg/kg
PSA Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
ETHYLENE-VINYL ACETATE POLYMER Dermal LD50 estimated to be > 5,000 mg/kg
ETHYLENE-VINYL ACETATE POLYMER Ingestion Rat LD50 > 1,000 mg/kg
2-ETHYLHEXYL ACRYLATE Dermal Rabbit LD50 > 10,000 mg/kg
2-ETHYLHEXYL ACRYLATE Ingestion Rat LD50 4,430 mg/kg
ACRYLIC ACID Dermal Rabbit LD50 295 mg/kg
ACRYLIC ACID Inhalation-
Dust/Mist
(4 hours)
Rat LC50 3.8 mg/l
ACRYLIC ACID Ingestion Rat LD50 1,250 mg/kg
TITANIUM DIOXIDE Dermal Rabbit LD50 > 10,000 mg/kg
TITANIUM DIOXIDE Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 6.82 mg/l
TITANIUM DIOXIDE Ingestion Rat LD50 > 10,000 mg/kg
2,2-DIMETHOXY-2-PHENYLACETOPHENONE Dermal Rat LD50 > 7,100 mg/kg
2,2-DIMETHOXY-2-PHENYLACETOPHENONE Ingestion Rat LD50 > 6,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
POLYESTER FILM BACKING Human No significant irritation
ETHYLENE-VINYL ACETATE POLYMER Professio
nal
judgeme
nt
No significant irritation
2-ETHYLHEXYL ACRYLATE Rabbit Irritant
ACRYLIC ACID Rabbit Corrosive
TITANIUM DIOXIDE Rabbit No significant irritation
2,2-DIMETHOXY-2-PHENYLACETOPHENONE Rabbit No significant irritation
Serious Eye Damage/Irritation
Name Species Value
POLYESTER FILM BACKING Human No significant irritation
ETHYLENE-VINYL ACETATE POLYMER Professio
nal
judgeme
nt
No significant irritation
2-ETHYLHEXYL ACRYLATE Rabbit No significant irritation
ACRYLIC ACID Rabbit Corrosive
TITANIUM DIOXIDE Rabbit No significant irritation
2,2-DIMETHOXY-2-PHENYLACETOPHENONE Rabbit No significant irritation
Skin Sensitization
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
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Page 9 of 12
Name Species Value
POLYESTER FILM BACKING Human Not sensitizing
2-ETHYLHEXYL ACRYLATE Human
and
animal
Sensitizing
ACRYLIC ACID Guinea
pig
Some positive data exist, but the data are not
sufficient for classification
TITANIUM DIOXIDE Human
and
animal
Not sensitizing
2,2-DIMETHOXY-2-PHENYLACETOPHENONE Guinea
pig
Not sensitizing
Photosensitization
Name Species Value
2,2-DIMETHOXY-2-PHENYLACETOPHENONE Guinea
pig
Sensitizing
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
POLYESTER FILM BACKING In Vitro Not mutagenic
2-ETHYLHEXYL ACRYLATE In Vitro Some positive data exist, but the data are not
sufficient for classification
ACRYLIC ACID In vivo Not mutagenic
ACRYLIC ACID In Vitro Some positive data exist, but the data are not
sufficient for classification
TITANIUM DIOXIDE In Vitro Not mutagenic
TITANIUM DIOXIDE In vivo Not mutagenic
2,2-DIMETHOXY-2-PHENYLACETOPHENONE In Vitro Not mutagenic
Carcinogenicity
Name Route Species Value
2-ETHYLHEXYL ACRYLATE Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
ACRYLIC ACID Ingestion Rat Not carcinogenic
ACRYLIC ACID Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
TITANIUM DIOXIDE Ingestion Multiple
animal
species
Not carcinogenic
TITANIUM DIOXIDE Inhalation Rat Carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
2-ETHYLHEXYL ACRYLATE Inhalation Not toxic to development Rat NOAEL 0.75
mg/l
during
gestation
ACRYLIC ACID Ingestion Not toxic to female reproduction Rat NOAEL 460
mg/kg/day
2 generation
ACRYLIC ACID Ingestion Not toxic to male reproduction Rat NOAEL 460
mg/kg/day
2 generation
ACRYLIC ACID Inhalation Not toxic to development Rat NOAEL 1.1
mg/l
during
organogenesi
s
ACRYLIC ACID Ingestion Some positive developmental data exist,
but the data are not sufficient for
Rat NOAEL 53
mg/kg/day
2 generation
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
__________________________________________________________________________________________
Page 10 of 12
classification
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
2-ETHYLHEXYL
ACRYLATE
Inhalation respiratory irritation May cause respiratory irritation Rat NOAEL Not
available
ACRYLIC ACID Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
POLYESTER FILM
BACKING
Ingestion heart | skin |
endocrine system |
bone, teeth, nails,
and/or hair |
hematopoietic
system | liver |
immune system |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system
All data are negative Rat NOAEL Not
available
13 weeks
ETHYLENE-VINYL
ACETATE POLYMER
Ingestion liver Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL
4,000
mg/kg/day
90 days
2-ETHYLHEXYL
ACRYLATE
Inhalation endocrine system |
liver
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 0.75
mg/l
90 days
2-ETHYLHEXYL
ACRYLATE
Inhalation olfactory system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 0.08
mg/l
90 days
2-ETHYLHEXYL
ACRYLATE
Inhalation respiratory system All data are negative Rat NOAEL 0.75
mg/l
90 days
TITANIUM DIOXIDE Inhalation respiratory system Some positive data exist, but the
data are not sufficient for
classification
Rat LOAEL 0.01
mg/l
2 years
TITANIUM DIOXIDE Inhalation pulmonary fibrosis All data are negative Human NOAEL Not
available
occupational
exposure
2,2-DIMETHOXY-2PHENYLACETOPHENO
NE
Dermal photoirritation All data are negative Mouse NOAEL Not
available
not available
2,2-DIMETHOXY-2PHENYLACETOPHENO
NE
Ingestion liver Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 138
mg/kg/day
3 months
2,2-DIMETHOXY-2PHENYLACETOPHENO
NE
Ingestion hematopoietic
system | kidney
and/or bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 581
mg/kg/day
3 months
2,2-DIMETHOXY-2PHENYLACETOPHENO
NE
Ingestion auditory system |
eyes
All data are negative Rat NOAEL 581
mg/kg/day
3 months
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
__________________________________________________________________________________________
Page 11 of 12
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
The substrate that was abraded must be considered as a factor in the disposal method for this product. Dispose of waste
product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
Not regulated per U.S. DOT, IATA or IMO.
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M
transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of applicable
current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to
transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified
for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory
requirements.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
15.2. State Regulations
Contact 3M for more information.
California Proposition 65
Ingredient C.A.S. No. Classification
Toluene 108-88-3 Female reproductive toxin
Toluene 108-88-3 Developmental Toxin
TITANIUM DIOXIDE 13463-67-7 Carcinogen
WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive
harm.
3M™ Diamond Lapping Film, 631X, 638X (PSA), 641X, 651X, 661X, 661XA, 661XU, 661XY, 662XW, 663X, 664X, 666X, 666XW,
668X(PSA) 11/06/15
__________________________________________________________________________________________
Page 12 of 12
WARNING: This product contains a chemical known to the State of California to cause cancer.
15.3. Chemical Inventories
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:
11-6904-4
Version Number:
27.03
Issue Date:
11/06/15
Supercedes Date:
11/06/15
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3M USA SDSs are available at www.3M.com
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