3M B1768988 User Manual

3M™ Abrasive Products, Trizact™ 217EA, A30 - A100 04/21/14

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Safety Data Sheet

Copyright,2014,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group:

24-1175-9

Version Number:

1.06

Issue Date:

04/21/14

Supercedes Date:

03/22/13

SECTION 1: Identification

1.1. Product identifier

3M™ Abrasive Products, Trizact™ 217EA, A30 - A100

1.2. Recommended use and restrictions on use

Recommended use

Abrasive Product

1.3. Supplier’s details
MANUFACTURER:

3M

DIVISION:

Abrasive Systems Division

ADDRESS:

3M Center, St. Paul, MN 55144-1000, USA

Telephone:

1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or [phone] (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classification

Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.

2.2. Label elements

Signal word

Not applicable.

Symbols

Not applicable.

Pictograms

Not applicable.

2.3. Hazards not otherwise classified

None.

30% of the mixture consists of ingredients of unknown acute oral toxicity.

3M™ Abrasive Products, Trizact™ 217EA, A30 - A100 04/21/14

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SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt

Aluminum Oxide Mineral (non-fibrous) 1344-28-1 25 - 40
Inorganic Fluoride 14075-53-7 5 - 15
Titanium Dioxide 13463-67-7 0.4 - 1.5
Cured Resin Mixture 20 - 35
Cloth Backing Mixture 20 - 35

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:

Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:

Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye Contact:

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If Swallowed:

No need for first aid is anticipated.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media

In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide During Combustion
Carbon dioxide During Combustion

5.3. Special protective actions for fire-fighters

No unusual fire or explosion hazards are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Observe precautions from other sections.

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6.2. Environmental precautions

Not applicable.

6.3. Methods and material for containment and cleaning up

Not applicable.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

For industrial or professional use only. Avoid breathing of dust created by sanding, grinding or machining. Damaged
product can break apart during use and cause serious injury to face or eyes. Check product for damage such as cracks or nicks
prior to use. Replace if damaged. Always wear eye and face protection when working at sanding or grinding operations or
when near such operations. Combustible dust may form by action of this product on another material (substrate). Dust
generated from the substrate during use of this product may be explosive if in sufficient concentration with an ignition source.
Dust deposits should not be allowed to accumulate on surfaces because of the potential for secondary explosions.

7.2. Conditions for safe storage including any incompatibilities

No special storage requirements.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

Ingredient C.A.S. No. Agency Limit type Additional Comments

Aluminum Oxide Mineral (non­fibrous)

1344-28-1 Chemical

Manufacturer
Rec Guid

TWA:1 fiber/cc

Aluminum Oxide Mineral (non­fibrous)

1344-28-1 US Dept of

Labor - OSHA

TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3

Aluminum, insoluble compounds 1344-28-1 Amer Conf of

Gov. Indust.
Hyg.

TWA(respirable fraction):1
mg/m3

Titanium Dioxide 13463-67-7 Amer Conf of

Gov. Indust.
Hyg.

TWA:10 mg/m3

Titanium Dioxide 13463-67-7 Chemical

Manufacturer
Rec Guid

TWA(as respirable dust):5
mg/m3

Titanium Dioxide 13463-67-7 US Dept of

Labor - OSHA

TWA(as total dust):15 mg/m3

Amer Conf of Gov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists
American Indust. Hygiene Assoc : American Industrial Hygiene Association
Chemical Manufacturer Rec Guid : Chemical Manufacturer's Recommended Guidelines
US Dept of Labor - OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Provide appropriate local exhaust ventilation for sanding, grinding or machining. Use general dilution ventilation and/or

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local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control
dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide local exhaust at
process emission sources to control exposure near the source and to prevent the escape of dust into the work area. Ensure that
dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to
prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).

8.2.2. Personal protective equipment (PPE)

Eye/face protection

To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding
operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an
exposure assessment. The following eye/face protection(s) are recommended:
Safety Glasses with side shields

Skin/hand protection

Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or
sanding.

Respiratory protection

Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when
determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure.
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

General Physical Form:

Solid

Odor, Color, Grade:

Solid abrasive product

Odor threshold

Not Applicable

Melting point

Not Applicable

Boiling Point

Not Applicable

Flash Point

Not Applicable

Evaporation rate

Not Applicable

Flammability (solid, gas)

Not Classified

Flammable Limits(LEL)

Not Applicable

Flammable Limits(UEL)

Not Applicable

Vapor Pressure

Not Applicable

Vapor Density

Not Applicable

Specific Gravity

Not Applicable

Solubility In Water

Not Applicable

Solubility- non-water

Not Applicable

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Partition coefficient: n-octanol/ water

Not Applicable

Autoignition temperature

Not Applicable

Decomposition temperature

Not Applicable

Viscosity

Not Applicable

SECTION 10: Stability and reactivity

10.1. Reactivity

This material is considered to be non reactive under normal use conditions.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

None known.

10.5. Incompatible materials

None known.

10.6. Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:

Dust from grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Skin Contact:

Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.

3M™ Abrasive Products, Trizact™ 217EA, A30 - A100 04/21/14

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Allergic Skin Reaction (non-photo induced) in sensitive people: Signs/symptoms may include redness, swelling, blistering,
and itching.

Eye Contact:

Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.

Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling,
pain, tearing, and blurred or hazy vision.

Ingestion:

No health effects are expected.

Carcinogenicity:

Ingredient C.A.S. No. Class Description Regulation

Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer

Additional Information:

This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material
being abraded must also be considered.

This product contains titanium dioxide. Cancer of the lungs has been observed in rats that inhaled high levels of titanium
dioxide. No exposure to inhaled titanium dioxide is expected during the normal handling and use of this product. Titanium
dioxide was not detected when air sampling was conducted during simulated use of similar products containing titanium
dioxide. Therefore, the health effects associated with titanium dioxide are not expected during the normal use of this product.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
Aluminum Oxide Mineral (non-fibrous) Dermal LD50 estimated to be > 5,000 mg/kg
Aluminum Oxide Mineral (non-fibrous) Inhalation-

Dust/Mist
(4 hours)

Rat LC50 > 2.3 mg/l

Aluminum Oxide Mineral (non-fibrous) Ingestion Rat LD50 > 5,000 mg/kg
Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg
Titanium Dioxide Inhalation-

Dust/Mist
(4 hours)

Rat LC50 > 6.82 mg/l

Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

Aluminum Oxide Mineral (non-fibrous) Rabbit No significant irritation
Titanium Dioxide Rabbit No significant irritation

Serious Eye Damage/Irritation

Name Species Value

Aluminum Oxide Mineral (non-fibrous) Rabbit No significant irritation
Titanium Dioxide Rabbit No significant irritation

Skin Sensitization

Name Species Value

Titanium Dioxide Human

and
animal

Not sensitizing

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Respiratory Sensitization

Name Species Value

Germ Cell Mutagenicity

Name Route Value

Aluminum Oxide Mineral (non-fibrous) In Vitro Not mutagenic
Titanium Dioxide In Vitro Not mutagenic
Titanium Dioxide In vivo Not mutagenic

Carcinogenicity

Name Route Species Value

Aluminum Oxide Mineral (non-fibrous) Inhalation Rat Not carcinogenic
Titanium Dioxide Ingestion Multiple

animal
species

Not carcinogenic

Titanium Dioxide Inhalation Rat Carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure

Duration

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration

Aluminum Oxide Mineral
(non-fibrous)

Inhalation pneumoconiosis |

pulmonary fibrosis

Some positive data exist, but the
data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

Inorganic Fluoride Inhalation bone, teeth, nails,

and/or hair

Some positive data exist, but the
data are not sufficient for
classification

HHA

Titanium Dioxide Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Rat LOAEL

0.010 mg/l

2 years

Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not

available

occupational
exposure

Aspiration Hazard

Name Value

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material

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and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

The substrate that was abraded must be considered as a factor in the disposal method for this product. Incinerate in a
permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes.
As a disposal alternative, utilize an acceptable permitted waste disposal facility.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

Not regulated per U.S. DOT, IATA or IMO.

These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M

transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of
applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information
applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M
package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet
applicable regulatory requirements.

SECTION 15: Regulatory information

15.1. US Federal Regulations

Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No

15.2. State Regulations

Contact 3M for more information.

15.3. Chemical Inventories

This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.

Contact 3M for more information.

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

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NFPA Hazard Classification
Health: 0 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group:

24-1175-9

Version Number:

1.06

Issue Date:

04/21/14

Supercedes Date:

03/22/13

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com