Scotch(R) Super Glue Liquid AD110, AD114, AD117, AD118 05/19/15
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Safety Data Sheet
Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
18-8279-4
Version Number:
6.00
Issue Date:
05/19/15
Supercedes Date:
10/19/09
SECTION 1: Identification
1.1. Product identifier
Scotch(R) Super Glue Liquid AD110, AD114, AD117, AD118
Product Identification Numbers
44-0051-9065-5, 44-0052-0495-1, 44-0052-2170-8, 70-0050-1811-7, 70-0050-1902-4, 70-0050-3105-2, 70-0050-3328-0, 700050-3795-0, 70-0050-7735-2, 70-0051-0051-9, 70-0711-8246-6, 70-0712-1830-2, 70-0714-8107-4, 70-0715-0625-0
1.2. Recommended use and restrictions on use
Recommended use
Adhesive
1.3. Supplier’s details
MANUFACTURER:
3M
DIVISION:
Stationery and Office Supplies Division
ADDRESS:
3M Center, St. Paul, MN 55144-1000, USA
Telephone:
1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Flammable Liquid: Category 4.
Serious Eye Damage/Irritation: Category 2A.
Specific Target Organ Toxicity (respiratory irritation): Category 3.
2.2. Label elements
Signal word
Warning
Symbols
Exclamation mark |
Pictograms
Scotch(R) Super Glue Liquid AD110, AD114, AD117, AD118 05/19/15
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Hazard Statements
Combustible liquid.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statements
General:
Keep out of reach of children.
Prevention:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Call a POISON CENTER or doctor/physician if you feel unwell.
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.
Storage:
Store in a well-ventilated place. Keep cool.
Keep container tightly closed.
Store locked up.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
2.3. Hazards not otherwise classified
Avoid eye and skin contact. If eyelids are bonded, do not force open. In case of skin bonding, quickly soak in warm water and
avoid excessive force to free bonded area. May bond tissue rapidly.
SECTION 3: Composition/information on ingredients
Ingredient
C.A.S. No.
% by Wt
ETHYL CYANOACRYLATE
7085-85-0
90 - 95 Trade Secret *
POLY(METHYL METHACRYLATE)
9011-14-7
5 - 10
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
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4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
FOR SKIN BONDS: Quickly soak in warm water and avoid use of excessive force to free bonded area. If unable to free
bonded area, or if lips or mouth are bonded, get medical attention. If irritation persists, get medical attention.
Eye Contact:
Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. DO NOT force
eyelids open.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance
Condition
Carbon monoxide
During Combustion
Carbon dioxide
During Combustion
5.3. Special protective actions for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area
with fresh air. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to
burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory
protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic
absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not
Scotch(R) Super Glue Liquid AD110, AD114, AD117, AD118 05/19/15
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remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking
tools. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an
appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety
precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using
this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents
(eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep cool. Keep container tightly closed to prevent contamination with water or air. If
contamination is suspected, do not reseal container. Store away from acids. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient
C.A.S. No.
Agency
Limit type
Additional Comments
ETHYL CYANOACRYLATE
7085-85-0
ACGIH
TWA:0.2 ppm
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Do not wear cotton gloves.
Gloves made from the following material(s) are recommended: Nitrile Rubber
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Respiratory protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form:
Liquid
Specific Physical Form:
Gel
Odor, Color, Grade:
Transparent water white to straw colored with sharp, irritating
odor.
Odor threshold
No Data Available
pH
Not Applicable
Melting point
Not Applicable
Boiling Point
>=300 ºF
Flash Point
Approximately 176 ºF [Test Method: Closed Cup]
Evaporation rate
No Data Available
Evaporation rate
Negligible [Ref Std: BUOAC=1]
Flammability (solid, gas)
Not Applicable
Flammable Limits(LEL)
No Data Available
Flammable Limits(UEL)
No Data Available
Vapor Pressure
Approximately 1 mmHg [@ 20 ºC]
Vapor Density
Negligible [Ref Std: AIR=1]
Density
1.05 g/ml
Specific Gravity
1.05 [Ref Std: WATER=1]
Solubility in Water
Negligible
Solubility- non-water
No Data Available
Partition coefficient: n-octanol/ water
No Data Available
Autoignition temperature
No Data Available
Decomposition temperature
No Data Available
Viscosity
6,000 centistoke [@ 73.4 ºF ]
Percent volatile
90 - 95 %
VOC Less H2O & Exempt Solvents
No Data Available
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Sparks and/or flames
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10.5. Incompatible materials
Water
Alcohols
Amines
Alkali and alkaline earth metals
10.6. Hazardous decomposition products
Substance
Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
Bonds skin rapidly.
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye Contact:
Bonds eyelids rapidly.
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name
Route
Species
Value
Overall product
Ingestion
No data available; calculated ATE > 5,000 mg/kg
ETHYL CYANOACRYLATE
Dermal
Rabbit
LD50 > 2,000 mg/kg
ETHYL CYANOACRYLATE
Ingestion
Rat
LD50 > 5,000 mg/kg
POLY(METHYL METHACRYLATE)
Dermal
LD50 estimated to be > 5,000 mg/kg
POLY(METHYL METHACRYLATE)
Ingestion
Rat
LD50 > 5,000 mg/kg
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ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name
Species
Value
ETHYL CYANOACRYLATE
Rabbit
Mild irritant
POLY(METHYL METHACRYLATE)
Rabbit
No significant irritation
Serious Eye Damage/Irritation
Name
Species
Value
ETHYL CYANOACRYLATE
Rabbit
Severe irritant
POLY(METHYL METHACRYLATE)
Rabbit
Mild irritant
Skin Sensitization
Name
Species
Value
ETHYL CYANOACRYLATE
Human
Some positive data exist, but the data are not
sufficient for classification
Respiratory Sensitization
Name
Species
Value
ETHYL CYANOACRYLATE
Human
Some positive data exist, but the data are not
sufficient for classification
Germ Cell Mutagenicity
Name
Route
Value
ETHYL CYANOACRYLATE
In Vitro
Not mutagenic
Carcinogenicity
For the component/components, either no data are currently available or the data are not sufficient for classification.
Reproductive Toxicity
Reproductive and/or Developmental Effects
For the component/components, either no data are currently available or the data are not sufficient for classification.
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name
Route
Target Organ(s)
Value
Species
Test Result
Exposure
Duration
ETHYL
CYANOACRYLATE
Inhalation
respiratory irritation
May cause respiratory irritation
Human
NOAEL Not
available
occupational
exposure
Specific Target Organ Toxicity - repeated exposure
For the component/components, either no data are currently available or the data are not sufficient for classification.
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
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Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional
fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured
or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for
transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per
applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by
applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and
disposal facilities.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed
Hazard - No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
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NFPA Hazard Classification
Health: 2 Flammability: 2 Instability: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health: 2 Flammability: 2 Physical Hazard: 1 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III
program. HMIS® is a registered mark of the American Coatings Association (ACA).
Document Group:
18-8279-4
Version Number:
6.00
Issue Date:
05/19/15
Supercedes Date:
10/19/09
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED
WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a
particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the
user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or
application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic
transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its
completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from 3M
3M USA SDSs are available at www.3M.com
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