3M B1644763 User Manual

MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 06/21/10

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Material Safety Data Sheet

Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME:

3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol)

MANUFACTURER:

3M

DIVISION:

Stationery Products

ADDRESS:

3M Center
St. Paul, MN 55144-1000

EMERGENCY PHONE: [phone] or [phone] (24 hours)

Issue Date:

06/21/10

Supercedes Date:

01/07/10

Document Group:

22-0408-9

Product Use:

Intended Use: Adhesive

SECTION 2: INGREDIENTS

Ingredient C.A.S. No. % by Wt

NON-VOLATILE COMPONENTS - N.J. TRADE SECRET REGISTRY NO.

04499600-6433P

Trade Secret 20 - 30

ACETONE 67-64-1 20 - 30
PROPANE 74-98-6 15 - 25
2-METHYLPENTANE 107-83-5 5 - 15
3-METHYLPENTANE 96-14-0 3 - 9
CYCLOHEXANE 110-82-7 4 - 8
2,2-DIMETHYLBUTANE 75-83-2 2 - 6
2,3-DIMETHYLBUTANE 79-29-8 2 - 6
HEXANE 110-54-3 < 1.5

SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW

Specific Physical Form: Aerosol
Odor, Color, Grade: Clear, sweet fruity odor

MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 06/21/10

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General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and

explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and
flash back. Aerosol container contains flammable material under pressure. May cause severe eye irritation. May cause
target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

3.2 POTENTIAL HEALTH EFFECTS

Eye Contact:

Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and
impaired vision.

Skin Contact:

Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.

Inhalation:

Intentional concentration and inhalation may be harmful or fatal.

Single exposure, above recommended guidelines, may cause:

Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.

Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.

Prolonged or repeated exposure may cause:

Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate,
bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.

May be absorbed following inhalation and cause target organ effects.

Ingestion:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May be absorbed following ingestion and cause target organ effects.

Target Organ Effects:

Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,

slowed reaction time, slurred speech, giddiness, and unconsciousness.

Prolonged or repeated exposure may cause:

Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of
the hands and feet, tremors and muscle atrophy.

MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 06/21/10

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Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES

The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.

Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. If signs/symptoms

develop, get medical attention. Wash contaminated clothing and clean shoes before reuse.

Inhalation: Remove person to fresh air. Get immediate medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never

give anything by mouth to an unconscious person. Get medical attention.

4.2 NOTE TO PHYSICIANS

Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Autoignition temperature

No Data Available

Flash Point

-42.00 ºF [Test Method: Tagliabue Closed Cup] [Details:

CONDITIONS: Propellant]

Flammable Limits - LEL

No Data Available

Flammable Limits - UEL

No Data Available

OSHA Flammability Classification:

Class IA Flammable Liquid

5.2 EXTINGUISHING MEDIA

Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed

containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).

Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely
flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol
container contains flammable material under pressure.

MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 06/21/10

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Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautions

Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. If possible,
seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary
outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Read and follow
safety precautions on the solvent label and MSDS.

Environmental procedures

Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities.
Dispose of collected material as soon as possible.

Clean-up methods

Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill.
Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent
material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools.
Clean up residue with an appropriate organic solvent. Seal the container.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLING

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,
sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static
or properly grounded shoes. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray
near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors,
mists, or spray. Keep out of the reach of children. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors ­open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation.
Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or
ignite matches, lighters, etc. Do not breathe vapors. Avoid contact with oxidizing agents.

7.2 STORAGE

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Do not store containers on
their sides. Store away from oxidizing agents.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLS

Use in an enclosed process area is recommended. Do not use in a confined area or areas with little or no air movement. Do not
remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control
airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use
respiratory protection equipment. Do not use in a confined area or areas with little or no air movement. If exhaust ventilation is not
adequate, use appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended

MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 06/21/10

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exposure limits and/or control spray or mist.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face Protection

Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Indirect Vented Goggles
.

8.2.2 Skin Protection

Avoid skin contact.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Fluoroelastomer (Viton)
Nitrile Rubber
Polyvinyl Alcohol (PVA)
Polyethylene/Ethylene Vinyl Alcohol
.

8.2.3 Respiratory Protection

Avoid breathing of vapors, mists or spray. Do not breathe vapors.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges
Half facepiece or fullface pressure demand self-contained breathing apparatus
. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.

8.2.4 Prevention of Swallowing

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES

Ingredient Authority Type Limit Additional Information

ACETONE ACGIH TWA 500 ppm
ACETONE ACGIH STEL 750 ppm
ACETONE OSHA TWA 2400 mg/m3
CYCLOHEXANE ACGIH TWA 100 ppm
CYCLOHEXANE OSHA TWA 1050 mg/m3
HEXANE ACGIH TWA 50 ppm Skin Notation*
HEXANE OSHA TWA 1800 mg/m3
HEXANE (ISOMERS OTHER THAN N­HEXANE)

ACGIH TWA 500 ppm

HEXANE (ISOMERS OTHER THAN N­HEXANE)

ACGIH STEL 1000 ppm

PROPANE OSHA TWA 1800 mg/m3

* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,

either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.

SOURCE OF EXPOSURE LIMIT DATA:

ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)

MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 06/21/10

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Specific Physical Form:

Aerosol

Odor, Color, Grade:

Clear, sweet fruity odor

General Physical Form:

Liquid

Autoignition temperature

No Data Available

Flash Point

-42.00 ºF [Test Method: Tagliabue Closed Cup] [Details:

CONDITIONS: Propellant]

Flammable Limits - LEL

No Data Available

Flammable Limits - UEL

No Data Available

Boiling point

Not Applicable

Density

0.726 g/ml

Vapor Density

2.97 [Ref Std: AIR=1]

Specific Gravity

0.726 [Ref Std: WATER=1]

pH

Not Applicable

Melting point

Not Applicable

Solubility in Water

Negligible

Evaporation rate

1.90 [Ref Std: ETHER=1]

Hazardous Air Pollutants

0.4 % weight [Test Method: Calculated]

Hazardous Air Pollutants

0.016 lb HAPS/lb solids

Hazardous Air Pollutants

0.02 lb HAPS/gal [Test Method: Calculated]

Volatile Organic Compounds

Approximately 51 % [Test Method: calculated SCAQMD rule

443.1]

Kow - Oct/Water partition coef

No Data Available

Percent volatile

<=75 % weight

VOC Less H2O & Exempt Solvents

468 g/l

Viscosity

Not Applicable

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.

Materials and Conditions to Avoid:

10.1 Conditions to avoid

Heat
Sparks and/or flames

10.2 Materials to avoid

None known

Hazardous Polymerization: Hazardous polymerization will not occur.

Hazardous Decomposition or By-Products

MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 06/21/10

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Substance Condition

Aldehydes During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion

SECTION 11: TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

Not determined.

CHEMICAL FATE INFORMATION

Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product

in a permitted hazardous waste facility.
Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill.

EPA Hazardous Waste Number (RCRA): D001 (Ignitable)

Since regulations vary, consult applicable regulations or authorities before disposal.

SECTION 14:TRANSPORT INFORMATION

ID Number(s):

62-4977-2926-9, 62-4977-4830-1, 70-0050-1481-9, 70-0050-1706-9, 70-0050-1808-3, 70-0050-1809-1, 70-0050-8170-1, 70-0050­8171-9, 70-0050-8855-7, 70-0050-8856-5, 70-0050-9202-1, 70-0714-2173-2, 70-0714-2194-8, 70-0714-8197-5, 70-0714-9203-0, 70­0714-9575-1

Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.

SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONS

MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 06/21/10

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Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt

CYCLOHEXANE 110-82-7 4 - 8
HEXANE 110-54-3 < 1.5

STATE REGULATIONS

Contact 3M for more information.

CHEMICAL INVENTORIES

The components of this product are in compliance with the chemical notification requirements of TSCA.

All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.

Contact 3M for more information.

INTERNATIONAL REGULATIONS

Non hazardous according to WHMIS criteria.

This material contains one or more ingredients that may be regulated by the International Traffic in Arms Regulation (ITAR), an
export control of US military technology and chemicals. Prior to export of this material or any product containing this material,
determine whether a proper license from the Department of State must be obtained. See 22CFR 120-130 for anyspecific requirements.

Contact 3M for more information.

WHMIS: Non-hazardous

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION

MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 06/21/10

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NFPA Hazard Classification

Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None

Aerosol Storage Code: 3

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.

HMIS Hazard Classification

Health: 2 Flammability: 4 Reactivity: 0 Protection: X - See PPE section.

Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and
Coatings Association (NPCA).

Revision Changes:
Section 4: First aid for eye contact - decontamination - was modified.
Section 4: First aid for eye contact - medical assistance - was modified.
Section 3: Potential effects from eye contact was modified.
Section 3: Potential effects from skin contact information was modified.
Section 3: Potential effects from inhalation information was modified.
Section 8: Eye/face protection information was modified.
Section 8: Skin protection - recommended gloves information was modified.
Section 8: Respiratory protection - recommended respirators information was modified.
Section 3: Other health effects information was modified.
Section 14: ID Number(s) Template 1 was modified.
Section 2: Ingredient table was modified.
Section 8: Exposure guidelines ingredient information was modified.
Section 10: Materials to avoid physical property was modified.
Section 10: Conditions to avoid physical property was modified.
Section 3: Immediate eye hazard(s) was added.
Section 6: Environmental procedures heading was added.
Section 6: Personal precautions heading was added.
Section 6: Clean-up methods heading was added.
Section 6: Release measures heading was deleted.
Section 8: Exposure guidelines legend was deleted.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.

3M MSDSs are available at www.3M.com

MATERIAL SAFETY DATA SHEET 3M(TM) Super 77(TM) Multipurpose Adhesive (Aerosol) 06/21/10

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