3M 59809 User Manual

3M™ TB Quat Disinfectant Ready-To-Use Cleaner 01/05/18

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Safety Data Sheet

Copyright,2018,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group:

24-9443-3

Version Number:

4.01

Issue Date:

01/05/18

Supercedes Date:

01/05/15

SECTION 1: Identification

1.1. Product identifier

3M™ TB Quat Disinfectant Ready-To-Use Cleaner

Product Identification Numbers

ID Number

UPC

ID Number

UPC

70-0715-9317-5

00-48011-59809-3

1.2. Recommended use and restrictions on use

Recommended use

Disinfectant, Rinse-free, EPA registered hospital germicide for disinfecting and cleaning non-critical items. Proven effective
in killing hepatitis B virus (HBV) and TB.

1.3. Supplier’s details

MANUFACTURER:

3M

DIVISION:

Commercial Solutions Division

ADDRESS:

3M Center, St. Paul, MN 55144-1000, USA

Telephone:

1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or [phone] (24 hours)

SECTION 2: Hazard identification

The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification

Serious Eye Damage/Irritation: Category 2B.
Skin Sensitizer: Category 1.

2.2. Label elements
Signal word

Warning

Symbols

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Exclamation mark |

Pictograms

Hazard Statements

Causes eye irritation.

May cause an allergic skin reaction.

Precautionary Statements

Prevention:

Avoid breathing dust/fume/gas/mist/vapors/spray.

Wear protective gloves, protective clothing, and eye/face protection.

Wash thoroughly after handling.

Contaminated work clothing must not be allowed out of the workplace.

Response:

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.

If eye irritation persists: Get medical advice/attention.

IF ON SKIN: Wash with plenty of soap and water.

If skin irritation or rash occurs: Get medical advice/attention.

Wash contaminated clothing before reuse.

Disposal:

Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

SECTION 3: Composition/information on ingredients

Ingredient

C.A.S. No.

% by Wt

WATER

7732-18-5

60 - 90 Trade Secret *

DIETHYLENE GLYCOL BUTYL ETHER

112-34-5

5 - 10 Trade Secret *

TETRASODIUM
ETHYLENEDIAMINETETRAACETATE

64-02-8

1 - 5 Trade Secret *
ETHOXYLATED C12-C15 ALCOHOLS

68131-39-5

0.1 - 1 Trade Secret *

SODIUM METASILICATE

6834-92-0

0.1 - 1 Trade Secret *

Fragrance added

Mixture

< 1 Trade Secret *

BENZYL-C12-18-ALKYLDIMETHYL AMMONIUM
CHLORIDES

68391-01-5

0.105

Quaternary ammonium compounds, C12-14­alkyl[(ethylphenyl)methyl]dimethyl, chlorides

85409-23-0

0.105

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

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Inhalation:

Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms
develop, get medical attention.

Eye Contact:

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If Swallowed:

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required

Not applicable.

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media

Material will not burn. Use a fire fighting agent suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

5.3. Special protective actions for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the
container. Dispose of collected material as soon as possible in accordance with applicable
local/regional/national/international regulations.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

For industrial or professional use only. NOTE: The above precautionary information presumes that this ready-to-use

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product has been diluted and dispensed from a chemical dispensing system. Keep out of reach of children. Avoid
breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when
using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing
agents (eg. chlorine, chromic acid etc.)

7.2. Conditions for safe storage including any incompatibilities

Store away from acids. Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.

Ingredient

C.A.S. No.

Agency

Limit type

Additional Comments

DIETHYLENE GLYCOL
BUTYL ETHER

112-34-5

ACGIH

TWA(inhalable fraction and
vapor):10 ppm

Fragrance added

Mixture

AIHA

TWA:165.5 mg/m3(30 ppm)

ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Full Face Shield
Indirect Vented Goggles

Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
Fluoroelastomer

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron – Butyl rubber

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Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

General Physical Form:

Liquid

Specific Physical Form:

Liquid

Odor, Color, Grade:

Clear colorless liquid with lemon fragrance

Odor threshold

No Data Available

pH

11.9 - 12.9

Melting point

Not Applicable

Boiling Point

> 212 ºF

Flash Point

No flash point

Evaporation rate

No Data Available

Flammability (solid, gas)

Not Applicable

Flammable Limits(LEL)

No Data Available

Flammable Limits(UEL)

No Data Available

Vapor Pressure

No Data Available

Vapor Density

No Data Available

Density

No Data Available

Specific Gravity

1.007 - 1.019 [Ref Std:WATER=1]

Solubility in Water

Complete

Solubility- non-water

No Data Available

Partition coefficient: n-octanol/ water

No Data Available

Autoignition temperature

Not Applicable

Decomposition temperature

No Data Available

Viscosity

< 100 centipoise

Volatile Organic Compounds

< 1 % weight [Test Method:calculated per CARB title 2]

Percent volatile

60 - 100 % weight

VOC Less H2O & Exempt Solvents

< 50 g/l [Test Method:calculated per CARB title 2]

SECTION 10: Stability and reactivity

10.1. Reactivity

This material is considered to be non reactive under normal use conditions.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

Not determined

10.5. Incompatible materials

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Strong acids
Strong oxidizing agents

10.6. Hazardous decomposition products

Substance

Condition

Carbon monoxide

Not Specified

Carbon dioxide

Not Specified

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:

Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Skin Contact:

Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:

Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Ingestion:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name

Route

Species

Value

Overall product

Dermal

No data available; calculated ATE >5,000 mg/kg

Overall product

Inhalation­Vapor(4 hr)

No data available; calculated ATE >50 mg/l
Overall product

Ingestion

No data available; calculated ATE >5,000 mg/kg

DIETHYLENE GLYCOL BUTYL ETHER

Dermal

Rabbit

LD50 2,764 mg/kg

DIETHYLENE GLYCOL BUTYL ETHER

Ingestion

Rat

LD50 7,292 mg/kg

TETRASODIUM ETHYLENEDIAMINETETRAACETATE

Ingestion

Rat

LD50 1,658 mg/kg

ETHOXYLATED C12-C15 ALCOHOLS

Dermal

Rat

LD50 5,000 mg/kg

ETHOXYLATED C12-C15 ALCOHOLS

Ingestion

Rat

LD50 1,200 mg/kg

SODIUM METASILICATE

Dermal

Rabbit

LD50 > 4,640 mg/kg

SODIUM METASILICATE

Ingestion

Rat

LD50 500 mg/kg

Fragrance added

Inhalation­Vapor (4
hours)

Mouse

LC50 > 3.14 mg/l

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Fragrance added

Dermal

Rabbit

LD50 > 5,000 mg/kg

Fragrance added

Ingestion

Rat

LD50 4,400 mg/kg

BENZYL-C12-18-ALKYLDIMETHYL AMMONIUM
CHLORIDES

Dermal

Not
available

LD50 > 2,000 mg/kg

BENZYL-C12-18-ALKYLDIMETHYL AMMONIUM
CHLORIDES

Ingestion

Not
available

LD50 500 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name

Species

Value

DIETHYLENE GLYCOL BUTYL ETHER

Rabbit

Minimal irritation

SODIUM METASILICATE

Rabbit

Corrosive

Fragrance added

Rabbit

Mild irritant

BENZYL-C12-18-ALKYLDIMETHYL AMMONIUM CHLORIDES

Professio
nal
judgeme
nt

Corrosive

Serious Eye Damage/Irritation

Name

Species

Value

DIETHYLENE GLYCOL BUTYL ETHER

Rabbit

Corrosive

ETHOXYLATED C12-C15 ALCOHOLS

Not
available

Corrosive
SODIUM METASILICATE

Rabbit

Corrosive

Fragrance added

Rabbit

Mild irritant

BENZYL-C12-18-ALKYLDIMETHYL AMMONIUM CHLORIDES

Professio
nal
judgeme
nt

Corrosive

Skin Sensitization

Name

Species

Value

SODIUM METASILICATE

Mouse

Not classified

Fragrance added

Mouse

Sensitizing

Respiratory Sensitization

For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity

Name

Route

Value

SODIUM METASILICATE

In Vitro

Not mutagenic

SODIUM METASILICATE

In vivo

Not mutagenic

Fragrance added

In Vitro

Not mutagenic

Fragrance added

In vivo

Not mutagenic

Carcinogenicity

Name

Route

Species

Value

Fragrance added

Ingestion

Rat

Some positive data exist, but the data are not
sufficient for classification

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name

Route

Value

Species

Test Result

Exposure
Duration

SODIUM METASILICATE

Ingestion

Not classified for development

Mouse

NOAEL 200
mg/kg/day

during
gestation

Fragrance added

Ingestion

Not classified for female reproduction

Rat

NOAEL 750

premating &

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mg/kg/day

during
gestation

Fragrance added

Ingestion

Not classified for development

Multiple
animal
species

NOAEL 591
mg/kg/day

during
organogenesi
s

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name

Route

Target Organ(s)

Value

Species

Test Result

Exposure
Duration

SODIUM
METASILICATE

Inhalation

respiratory irritation

May cause respiratory irritation

official
classifica
tion

NOAEL Not
available

Fragrance added

Ingestion

nervous system

Not classified

NOAEL Not
available

BENZYL-C12-18­ALKYLDIMETHYL
AMMONIUM
CHLORIDES

Inhalation

respiratory irritation

May cause respiratory irritation

NOAEL Not
available

Specific Target Organ Toxicity - repeated exposure

Name

Route

Target Organ(s)

Value

Species

Test Result

Exposure
Duration

SODIUM
METASILICATE

Ingestion

kidney and/or
bladder

Some positive data exist, but the
data are not sufficient for
classification

Dog

LOAEL
2,400
mg/kg/day

4 weeks
SODIUM
METASILICATE

Ingestion

endocrine system |
blood

Not classified

Rat

NOAEL 804
mg/kg/day

3 months

SODIUM
METASILICATE

Ingestion

heart | liver

Not classified

Rat

NOAEL
1,259
mg/kg/day

8 weeks
Fragrance added

Ingestion

kidney and/or
bladder

Not classified

Rat

LOAEL 75
mg/kg/day

103 weeks

Fragrance added

Ingestion

liver

Not classified

Mouse

NOAEL
1,000
mg/kg/day

103 weeks

Fragrance added

Ingestion

heart | endocrine
system | bone, teeth,
nails, and/or hair |
hematopoietic
system | immune
system | muscles |
nervous system |
respiratory system

Not classified

Rat

NOAEL 600
mg/kg/day

103 weeks

Aspiration Hazard

Name

Value

Fragrance added

Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information

A 3M Product Environmental Data Sheet (PED) is available.

Chemical fate information

A 3M Product Environmental Data Sheet (PED) is available.

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SECTION 13: Disposal considerations

13.1. Disposal methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated
& disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations

EPCRA 311/312 Hazard Classifications:

Physical Hazards

Not applicable

Health Hazards

Serious eye damage or eye irritation

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient

C.A.S. No

% by Wt

DIETHYLENE GLYCOL BUTYL ETHER
(GLYCOL ETHERS)

112-34-5

5 - 10

FIFRA

Status

Registration Number

Registered

1839-83-AA-10350

This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain
labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard
information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard
information required on the pesticide label is reproduced below. The pesticide label also includes other important information,
including directions for use.
PRECAUTIONARY STATEMENTS
HAZARDS TO HUMANS AND DOMESTIC ANIMALS
CAUTION
KEEP OUT OF REACH OF CHILDREN
Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling and
before eating, drinking, chewing gum or using tobacco.

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FIRST AID:
Have the product container or label with you when calling a poison control center or doctor, or going for treatment. If in eyes:
Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. If swallowed: Call a poison
control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce
vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person.
If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance then
give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further
treatment advice.
NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage.

STORAGE AND DISPOSAL:
DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL.
PESTICIDE STORAGE – Store in a dry place no lower in temperature than 50°F or higher than 120°F.
PESTICIDE DISPOSAL - Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or
rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact
your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional
Office for guidance.
CONTAINER DISPOSAL - Nonrefillable container. Do not reuse or refill container. Clean container promptly after
emptying. Triple rinse as follows: Fill container 1/4 full with water and recap. Agitate vigorously. Follow Pesticide Disposal
instructions for rinsate disposal. Drain for 10 seconds after the flow begins to drip. Repeat procedure two more times. Offer
for recycling or reconditioning, if available. If not available, puncture and dispose in a sanitary landfill.

15.2. State Regulations

California Proposition 65

Ingredient

C.A.S. No.

Listing

Formaldehyde

50-00-0

Carcinogen

15.3. Chemical Inventories

The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification
and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information.

The components of this product are in compliance with the new substance notification requirements of CEPA.

The components of this material are in compliance with the China "Measures on Environmental Management of New
Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information.

The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain
restrictions may apply. Contact the selling division for additional information.

The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain
restrictions may apply. Contact the selling division for additional information.

The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain
restrictions may apply. Contact the selling division for additional information.

The components of this product are in compliance with the chemical notification requirements of TSCA.

15.4. International Regulations

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

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SECTION 16: Other information

NFPA Hazard Classification
Health: 2 Flammability: 0 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard Classification
Health: 2 Flammability: 0 Physical Hazard: 0 Personal Protection: X - See PPE section.

Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV
program. HMIS® is a registered mark of the American Coatings Association (ACA).

Document Group:

24-9443-3

Version Number:

4.01

Issue Date:

01/05/18

Supercedes Date:

01/05/15

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for
user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of
which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine
whether it is fit for a particular purpose and suitable for user's method of use or application.

3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic
transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its
completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the
SDS available directly from3M

3M USA SDSs are available at www.3M.com