Page 1
3M UK PLC 3M IRELAND
33+ MSDS 07 05 09.txt
3M CENTRE, CAIN RD, 3M HOUSE, ADELPHI
CENTRE,
BRACKNELL, BERKSHIRE, RG12 8HT DUN LAOGHAIRE, CO.
DUBLIN
Tel: 01344 858000 Tel: 01 2803555
========================================================================
MATERIAL SAFETY DATA SHEET
========================================================================
Document id : 16-6314-5 Issue date : 12/04/2005
Version : 3.00 Supersedes date : 17/09/2004
----------------------------------------------------------------------- 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION
------------------------------------------------------------------------
Tradename:
3M SUPER 33+ AND SUPER 88 VINYL ELECTRICAL TAPE-NO LEAD
3M Product ID:
80-6112-0701-2 80-6108-3386-7
----------------------------------------------------------------------- 2 COMPOSITION/INFORMATION ON INGREDIENTS
------------------------------------------------------------------------
Ingredient name and classification CAS number Percentage
------------------------------------- ------------------
------------ POLY(VINYL CHLORIDE) 9002-86-2 40 - 50
Regulatory Lists: IARC-NON
POLYESTER RESIN --- 15 - 25
PHENOLIC-CURED RUBBER ADHESIVE --- 10 - 20
TACKIFYING RESIN --- 5 - 10
SYNTHETIC RUBBER --- 1 - 5
RESIN --- 1 - 5
EPOXIDIZED VEGETABLE OIL 8013-07-8 1 - 3
DI-C8-10-BRANCHED ALKYL PHTHALATE, 68515-48-0 2 - 3
C9 RICH
ANTIMONY TRIOXIDE 1309-64-4 1 - 3
Regulatory Lists: IARC(Group 2B)
EU Hazard Symbols and Risk Phrases: EU - Adaptation 21 (Xn;
R:Carc.Cat.3;40)
CARBON BLACK 1333-86-4 1 - 3
Regulatory Lists: IARC(Group 2B)
IARC(Group 2B) - Category: CARBON BLACK EXTRACTS
P-TERT-BUTYLPHENOL-FORMALDEHYDE 25085-50-1 Less Than 2
RESIN
STABILIZER --- 1 - 2
----------------------------------------------------------------------- 3 HAZARDS IDENTIFICATION
------------------------------------------------------------------------
Page 1
Page 2
Critical hazards:
33+ MSDS 07 05 09.txt
None.
----------------------------------------------------------------------- 4 FIRST-AID MEASURES
------------------------------------------------------------------------
Eye Contact:
Flush eyes with large amounts of water. If signs/symptoms
persist, get medical attention.
Skin Contact:
Wash affected area with soap and water. If signs/symptoms
develop, get medical attention.
Inhalation:
Remove person to fresh air. If signs/symptoms develop, get
medical attention.
Ingestion:
Do not induce vomiting. Get immediate medical attention. Give
victim two glasses of water. Never give anything by mouth to
an unconscious person.
----------------------------------------------------------------------- 5 FIRE-FIGHTING MEASURES
------------------------------------------------------------------------
Suitable Extinguishing Media:
Use fire extinguishers with class B extinguishing agents
(e.g., dry chemical, carbon dioxide).
Exposure Hazards:
No unusual fire or explosion hazards are anticipated.
Hazardous Decomposition:
Carbon monoxide - During Combustion. Carbon dioxide - during
combustion. Hydrogen Chloride - During Combustion. Irritant
Vapours or Gases - During Combustion. Oxides of Antimony
During Combustion. Oxides of Zinc - During Combustion
Hydrocarbons - At Elevated Temperatures Under recommended
usage conditions, hazardous decomposition products are not
expected. Hazardous decomposition products may occur as a
result of oxidation, heating, or reaction with another
material.
Fire-Fighting Procedures:
Wear full protective equipment and a self-contained breathing
apparatus.
Special Instructions:
Not applicable. Contact with aluminum or zinc in a pressurised
system may generate hydrogen gas which could create an
explosion hazard.
----------------------------------------------------------------------- 6 ACCIDENTAL RELEASE MEASURES
------------------------------------------------------------------------
Personal Precautions:
Not applicable.
Methods for Cleaning up:
Not applicable.
Page 2
Page 3
33+ MSDS 07 05 09.txt
----------------------------------------------------------------------- 7 HANDLING AND STORAGE
------------------------------------------------------------------------
Incompatible Materials/Conditions:
Keep away from aluminium and zinc. Store away from oxidising
agents.
Precautions for Safe Handling:
This product is considered to be an article which does not
release or otherwise result in exposure to a hazardous
chemical under normal use conditions. Avoid contact with
oxidising agents.
----------------------------------------------------------------------- 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
------------------------------------------------------------------------
Eye Protection:
Not applicable. Avoid eye contact with vapours, mists, or
spray.
Hand Protection:
Not applicable.
Skin Protection:
Gloves not normally required. Avoid prolonged or repeated skin
contact.
Respiratory Protection:
Avoid inhalation of fumes. Avoid breathing of dust created by
cutting, sanding, grinding or machining.
Ingestion:
Do not eat, drink or smoke when using this product. Wash
exposed areas thoroughly with soap and water. Not applicable.
Keep out of the reach of children.
Recommended Ventilation:
Use with appropriate local exhaust ventilation. Not
applicable. Provide appropriate local exhaust for cutting,
grinding, sanding or machining. Use general dilution
ventilation and/or local exhaust ventilation to control
airborne exposures to below Occupational Exposure Limits
and/or control dust, fume, or airborne particles. If
ventilation is not adequate, use respiratory protection
equipment.
Exposure Limits:
POLY(VINYL CHLORIDE) (9002-86-2)
UK HSE TWA: 10 mg/m3 Total inhalable dust; Respirable dust 4
mg/m3 OES
DI-C8-10-BRANCHED ALKYL PHTHALATE, C9 RICH (68515-48-0)
CMRG TWA Exposure Limit: 5 mg/m3
ANTIMONY TRIOXIDE (1309-64-4)
UK HSE TWA: 0.5 mg/m3 as Sb OES
CARBON BLACK (1333-86-4)
UK HSE TWA: 3.5 mg/m3 OES
UK HSE STEL: 7 mg/m3 OES
----------------------------------------------------------------------- 9 PHYSICAL AND CHEMICAL PROPERTIES
------------------------------------------------------------------------
Page 3
Page 4
Appearance and Odour: Black adhesive tape with a
33+ MSDS 07 05 09.txt
slight odour.
pH: Not applicable
Boiling point/boiling range: Not applicable
Melting point/melting range: Not determined
Flash point: Not applicable
Autoflammability: Not determined
Vapour pressure: Not applicable
Water Solubility: Nil
Specific gravity: 1.22 g/ml
Vapour density: Not applicable
Volatile organic compounds: Not determined
Evaporation rate: Not applicable
Viscosity: Not applicable
Percent Volatile: Not applicable.
----------------------------------------------------------------------- 10 STABILITY AND REACTIVITY
------------------------------------------------------------------------
Materials to Avoid:
Strong oxidising agents. None known. Finely divided active
metals. Alkali and alkaline earth metals. Reactions with
metals in powder form occur from 370 C onwards.
Hazardous Decomposition:
Stable. Hazardous polymerisation will not occur.
----------------------------------------------------------------------- 11 TOXICOLOGICAL INFORMATION
------------------------------------------------------------------------
Effects from Eye Contact:
No health effects are expected.
Effects from Skin Contact:
No health effects are expected.
Effects from Inhalation:
No adverse health effects are expected. If thermal
decomposition occurs: Upper Respiratory Tract Irritation:
Signs/symptoms may include cough, sneezing, nasal discharge,
headache, hoarseness, and nose and throat pain.
Effects from Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include
abdominal pain, nausea, diarrhoea and vomiting.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Other Effects and Information:
This product, when used under reasonable conditions and in
accordance with the 3M directions for use, should not present
Page 4
Page 5
a health hazard. However, use or processing of the product in
33+ MSDS 07 05 09.txt
a manner not in accordance with the product's directions for
use may affect the performance of the product and may present
potential health and safety hazards.
----------------------------------------------------------------------- 12 ECOLOGICAL INFORMATION
------------------------------------------------------------------------
Ecotoxicity Data:
Not applicable.
Ecofate Data:
Not applicable.
Special statements for 2001/58/EC:
A conservative assessment indicates this product presents a
low environmental risk because use and disposal are unlikely
to result in the significant release of components to the
environment.
Other Effects and Information:
The environmental properties of this product present a low
environmental hazard.
----------------------------------------------------------------------- 13 DISPOSAL CONSIDERATIONS
------------------------------------------------------------------------
Product as Sold:
Not applicable.
Potential for Recycling:
Reclaim if feasible. If product can't be reclaimed, dispose of
waste product in a sanitary landfill. Alternatively,
incinerate the waste product in an industrial, commercial, or
municipal incinerator.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
----------------------------------------------------------------------- 14 TRANSPORT INFORMATION
------------------------------------------------------------------------
UN NUMBER:
UN number: Not restricted for
transportation.
UK ROAD/SEA FREIGHT (IMO) CLASSIFICATION:
Substance Identification Number:
Class:
Packing Group:
Proper Shipping Name:
ADR/RID CLASSIFICATION:
Class:
Page 5
Page 6
ADR classification:
33+ MSDS 07 05 09.txt
ICAO/IATA CLASSIFICATION:
Class:
Sub-Risk:
Packing Group:
Proper Shipping Name:
----------------------------------------------------------------------- 15 REGULATORY INFORMATION
------------------------------------------------------------------------
Disclosable Ingredients:
No ingredients required on label
Symbol(s):
None
Risk Phrases:
None
Safety Phrases:
None
----------------------------------------------------------------------- 16 OTHER INFORMATION
------------------------------------------------------------------------
Regulatory Information: The following UK Regulations
as amended may affect the
product as supplied: The
Chemicals (Hazard Information
and Packaging for supply)
Regulations, as amended. The
Carriage of Dangerous Goods
(Classification, Packaging and
Labelling) and use of
Transportable Pressure
Receptacles Regulations 1996,
as amended. Carriage of
Dangerous Goods by Road
regulations, 1996, as amended.
The Control of Substances
Hazardous to Health
Regulations 1999 as amended.
The Special Waste Regulations
1996, as amended. The
Environmental Protection Act,
1990 The Health and Safety at
Work Act, 1974.
Reissue date/Reason for reissue.
Updated sections 4, 6, 16 and added stock numbers.
Intended Use of Product:
Electrical tape.
The information on this Data Sheet is based on our experience and is
correct to the best of our knowledge at the date of publication, but
Page 6
Page 7
we do not accept any liability for any loss, damage or injury
resulting from its use (except as required by law). The information
may not be valid for any use not referred to in this Data Sheet or
use of the product in combination with other materials. For these
reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own
intended applications.
33+ MSDS 07 05 09.txt
Page 7
Loading...