1Protective hood
2Electrode
3Coupling ring
4Shaft
5Sleeve
6Cap
7Battery compartment with battery
8Key button
9Signal LED
10USB socket
11Blind plug
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OverviewWQL-pH
Recommended
fields of
application
pH measurements in wells, bore holes, rivers, water bodies and other surface
water, drinking water
1.2PC program WQL-Log
The WQL-Log PC program serves to operate a connected WTW data logger
of the WQL series type. The WQL-Log PC program automatically recognizes
the logger when it is connected to the USB interface and controls the menus
according to the type and measured parameter.
The PC program can carry out the following functions:
z Calibrate the electrode
z Set up and start a logging job
z Measure directly: The logger is connected to the PC via USB and the PC
program displays the current measured values.
z Read in measurement data of the logging job: Consistent data copying to
a PC-based database.
z Database-supported evaluation of measurement data, export functions
Note
The current version of the WQL-Log PC program is available on the Internet
on the site of the manufacturer of your device.
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WQL-pHOverview
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Fig. 1-1Overview of the communication of the logger and PC program
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OverviewWQL-pH
82
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WQL-pHSafety
2Safety
This component operating manual provides special instructions that must be
followed during the operation of the logger and PC program.
Always keep this operating manual in the vicinity of the logger and PC
program.
Symbols
used
Note
indicates notes that draw your attention to special features.
Note
indicates cross-references to other documents, e.g. application reports,
operating manuals of electrodes, etc.
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SafetyWQL-pH
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3Commissioning
3.1Preparing the logger
3.1.1General information on the installation of the battery and
electrode
z Normally, all screw joints of the logger housing can be opened and closed
by hand, without using any tools. If necessary, use a paper towel so you
get a better grip on the parts.
z Install the battery and electrode in a clean and preferably dry environment.
Moisture in the screw joint can affect the functioning of the logger.
Note
Please follow additionally the notes on commissioning in the operating
manual of the electrode.
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CommissioningWQL-pH
1
2
3
3.1.2Inserting the battery
Note
The logger is powered by a 3.6 V lithium battery, size AA, as provided in the
scope of the delivery (see chapter 13 T
ECHNICALDATAWQL-Log). Other
batteries of the same size such as alkaline manganese batteries do not
provide the required operational voltage.
Operating time, see section 11.4 B
ATTERY.
Fig. 3-1Inserting the battery
1Unscrew the cap (pos. 1 in Fig. 3-1).
2Unscrew the sleeve (pos. 2).
3Insert the battery When doing so, make sure that the battery is
correctly positioned (see label in the battery compartment).
4Screw the sleeve on the shaft with the shorter
thread. At the rear end
of the sleeve there is a thin O-ring inside (pos. 3). Make sure that this
O-ring is evenly positioned in the groove and is not twisted.
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5Screw on the sleeve and cap again. In the screwed condition, no gap
may be visible at the joints.
After the battery has been inserted the signal LED flashes once per second.
This means the logger has to be connected with the PC to set the date and
time (see section 7.3 S
JOB and section 7.4 SIGNAL LED TOINDICATETHEOPERATINGCONDITIONSOF
THELOGGER).
ETTINGTHEPARAMETERSANDSTARTINGTHELOGGING
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CommissioningWQL-pH
1
1
3
2
4
5
6
2
7
8
3.1.3Installing the electrode
88
Fig. 3-2Installing the electrode
1Unscrew the protective hood (pos. 1 in Fig. 3-2).
2Unscrew the coupling ring (pos. 2).
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3Pull out the blind plug (pos. 3).
4Prepare the electrode (pos. 4):
– Make sure that both O-rings (pos. 5 and 6 ) are mounted, clean
and dry.
– Remove the watering cap (pos. 7) and dab dry the shaft of the
electrode with a clean paper towel.
– Position the coupling ring (pos. 2) on the shaft of the electrode.
– Plug on the watering cap (pos. 7) to protect the electrode for the
time of the installation.
5Insert the thus prepared electrode (pos. 8) in the electrode
receptacle:
– Position the electrode at the opening and, against the pressure of
the air cushion inside, slowly push it in approx. 2 cm, until the air
escapes and the counter pressure is noticeably reduced.
– Then push in the electrode as far as it will go and turn it until the
electrical plug connection locks in place using light pressure. The
electrode is completely inserted when it cannot be turned any
more.
6Screw on the coupling ring (pos. 2) by hand to the limit.
7For calibrating and measuring remove the watering cap.
8Screw on the protective hood (pos. 1 in Fig. 3-2).
Note
The protection hood can be screwed on for transport or storage even if the
watering cap is plugged on. Please follow the notes on the storage of the
electrode in the operating manual of the electrode.
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CommissioningWQL-pH
3.1.4Mounting suspension
To attach the logger to a rope or chain, a suitable shackle is provided whose
bolt fits through the cross hole in the cap. As an alternative, you can screw
some different sling gear into the M6 threaded hole at the cap end (e.g. M6
eye bolt).
Corrosion
protection
In water, metal (e.g. zinc-plated) parts of the mounting suspension such as
thimbles, shackles or swivel connectors create voltages (chemically caused
according to the electrochemical series), which can cause corrosion of the
stainless steel of the logger or the above mentioned suspension parts.
Lightning
protection
Electrically conductive ropes or chains harbor the danger of the logger being
damaged by lightning.
RecommendationFor reasons of corrosion and lightning protection, we recommend to use a
nonconductive suspension, e.g. one with low-wear, resistant polypropylene
ropes.
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3.2Installing the WQL-Log program
3.2.1PC requirements
The WQL-Log PC program requires the following system components:
Hardware
requirements
Software
requirements
z Computer with Intel or Pentium III 500 MHz processor or higher (1 GHz or
quicker recommended.)
z At least 192 MB RAM (512 MB recommended)
z Hard disk with at least 600 MB available memory
z CD-ROM drive
z One free USB interface for each measuring instrument to be connected.
z 32-bit
-operating system Windows 2000 Service Pack 4, Windows 7,
Windows Server 2003 and higher, Windows Vista or Windows XP
3.2.2Installation routine
Note
The software is subject to continuous development. The current version of
the WQL-Log program is available for download on the Internet under http:/
/www.WTW.com.
Note
The following files and/or directories are on the supplied CD-Rom:
Installing the
driver
z The installation file for the PC program and the database server
z A directory with the installation program for the driver of the USB
interface
z A directory with the operating manual for the pH logger and the PC
program.
1Insert the enclosed CD-Rom in the corresponding disk drive of the
PC.
2Open the directory, USB_VCP_driver.
3Execute the file, CP210xVCPInstaller with a double click.
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CommissioningWQL-pH
4Follow the user guidance (click Install).
5Confirm the installation with OK. A virtual COM Port has been created
with the installation.
Installing thePC
program and
database server
6Execute the WQLLog_Vxxxx.exe file with a double click (xxxx =
current version number).
The installation wizard appears.
92
7Follow the user guidance (click OK).
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8Check off the checkbox, I accept the licensing terms and conditions.
9Click Next. An information window appears with the components
required for the installation.
10Click Install. The installation is carried out. Follow the user guidance
(click Next) until the Authentication Mode window appears.
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CommissioningWQL-pH
11Select the Mixed Mode option.
12In the Enter password field, enter the password (WTW!2009).
13Repeat the password entry (WTW!2009) in the Confirm password
field.
Note
The password WTW!2009 must be entered twice. If a different password is
entered, the PC program is not granted access to the database.
14Click Next. Then follow the user guidance (the default settings should
not be changed) until the following display appears:
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15Here you can change the location where the PC program should be
stored (click Change... ).
When the required location is displayed, click Next.
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16Here you find information on the installation. Click Install.
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CommissioningWQL-pH
17Click Finish to complete the installation.
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3.3Initial commissioning
1Start the WQL-Log program (the relevant icon is on the desktop).
The Login window appears.
2If the WQL-pH logger is connected to the PC via a USB cable and
should communicate with the WQL-Log PC program:
Confirm with OK. The WQL-Log program searches for the connection
with the logger.
3Confirm with OK.
During the initial commissioning, the Select database window
appears.
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CommissioningWQL-pH
4Confirm the option, Neue Datenbank anlegen (Create new database)
with OK. The window to save the newly created database appears.
98
5Change the location and name of the database as necessary.
Click Speichern (Save). The database is stored and the message,
Datenbank erfolgreich angelegt (Database was successfully created)
appears.
6Confirm with OK. A restart message appears:
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7Confirm with OK. The program is terminated.
Note
If the database cannot be created in the preselected directory (error
message, "Access denied"), select the following directory as the location:
(Windows program directory)\Microsoft SQL Server\
MSSQL.1\MSSQL\Data\
If you are in any doubt contact your system administrator.
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CommissioningWQL-pH
3.4Connection types
The PC program WQL-Log works with two types of connection:
z Work with database
(the logger and PC program do not communicate)
z Connected to logger
(the logger and PC program communicate)
Working with the
database
Connected to the
logger
In this type of connection it is only possible to process the measurement data
stored in the database and to change the system settings.
When the logger is logged on and connected to the WQL-Log PC program,
the program and the logger communicate with each other. The measurement
datasets present in the logger are read in to the database and are thus
available for processing.
You can parameterize the logger according to your requirements and set up
a logging job. When the logging job is started, the connection between the
logger and the WQL-Log PC program is cut. The cable connection between
the logger and PC does not have to be disconnected for this.
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3.5Starting the WQL-Log program
1Start the WQL-Log program.
The Login window appears.
Connection to
logger
2If the WQL-pH logger is connected to the PC via a USB cable and
should communicate with the WQL-Log PC program:
Confirm with OK. The WQL-Log program searches for the connection
with the logger.
3Confirm with OK. The data window appears. During the initial
commissioning it does not yet contain data to be graphically
displayed.
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CommissioningWQL-pH
Working with the
database
4If you want to work with the database:
Select Work with database and confirm with OK.
The data window appears with the logger data that was last read in
(during the initial commissioning it does not yet contain any data).
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WQL-pHSetting the display (language etc.)
4Setting the display (language etc.)
With the Display menu can set the language and temperature unit for the
WQL-Log PC program and the WQL-pH logger.
4.1Setting the language
1In the Display menu, select the menu item, Language.
1In the Display menu, select the menu item, Temperature unit.
2The options, ° C (degrees Celsius) and ° F (degrees Fahrenheit)
appear.
3Select the required temperature unit with a mouse click.
The setting is immediately active.
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Setting the display (language etc.)WQL-pH
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WQL-pHCalibrating for pH measurements
5Calibrating for pH measurements
Why calibrate?During the operation of a pH electrode, the slope and asymmetry of the
electrode change with time. Calibrating determines the current slope and
asymmetry (zero point) of the electrode and stores them in the logger.
When to calibrate?Always calibrate:
z During the initial commissioning
z Before starting a logging job
z After installing another electrode
Calibration procedure, AutoCal :
AutoCalis a fully automatic single-point or two-point calibration using the datasets for
buffer solutions selected in the Buffer sets menu.
The buffer solutions are automatically recognized. Depending on the setting
(see page 116), the PC program displays the relevant nominal buffer value
or the current electrode voltage in mV. The calibration can be terminated after
the first buffer solution. This corresponds to a single-point calibration. For
this, the instrument uses the Nernst slope (-59.2 mV/pH at 25 °C) and
determines the asymmetry of the electrode.
AutoReadWhen calibrating with AutoCal, the AutoRead function is automatically
activated. The AutoRead function checks the stability of the measured pH
and temperature signal. The stability has a considerable effect on the
reproducibility of the measured value.
The current AutoRead measurement can be terminated at any time
(accepting the current value).
Note
In the delivery condition, the WQL-pH logger is equipped with default
calibration values (see chapter 10 R
ESETTINGTHELOGGER). To achieve
accurate measured values it is essential to calibrate with the electrode before
logging.
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Calibrating for pH measurementsWQL-pH
5.1Buffer sets
You can use the buffer sets quoted in the table for an automatic calibration.
The pH values are valid for the specified temperature values. The
temperature dependence of the pH values is taken into account during the
calibration.
Buffer setMenu
designation
WTW technical buffer
TEC2.00
solutions
pH
values
4.01
at temp.
25 °C
7.00
10.01
*
Standard buffer solutions
according to DIN 19266
NIST/DIN1.679
4.006
25 °C
6.865
9.180
12.454
The TEC calibration for pH 10.01 is optimized for the WTW technical buffer
solution TEP 10 Trace or TPL 10 Trace. Other buffer solutions can lead to an
erroneous calibration. The correct buffer solutions are given in the WTW
catalog or on the Internet.
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5.2Calibration settings
Buffer setsThe following buffer sets can be selected:
z NIST/DIN
z TEC
1In the Device menu, select the menu item, Calibrate.
2The calibration window appears.
Selecting the
buffer dataset
You can select the buffer dataset NIST/DIN or TEC.
3In the Buffer set menu, select and confirm the required buffer
set with a mouse click.
The selected setting is immediately active.
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Note
During calibration and direct measurement make sure that neither the
calibration or measurement solution nor the logger shaft are electrically
grounded (e.g. with a metal stand). Otherwise, this could result in erroneous
values.
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Calibrating for pH measurementsWQL-pH
5.3Calibrating with AutoCal
Note
Always check the selected buffer set before calibrating.
From the respective buffer set you can use any 2 buffers in any order.
Note
We recommend to always calibrate with the protective hood screwed on so
the electrode is protected. Use a stand as necessary.
Preparatory
activities
1Connect the WQL-pH logger (with installed electrode) to a USB
interface of your PC via the USB cable.
2Keep the buffer solutions ready.
3In the Device menu, select the menu item, Calibrate.
The calibration window appears.
Calibration
The following example covers the AutoCal calibration using WTW technical
buffer solutions.
4Immerse the logger (with the electrode installed) in the first
buffer solution.
108
5Use the Continue button to start the measurement.
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WQL-pHCalibrating for pH measurements
6The AutoRead running... note appears and the electrode voltage U
(mV) and temperature are displayed.
The prompt for buffer 2 appears as soon as a stable value is
recognized.
Note
You can prematurely terminate the AutoRead function manually with Accept
at any time. If the AutoRead function is prematurely terminated, the current
measurement data are accepted immediately.
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Calibrating for pH measurementsWQL-pH
7If you want to carry out a single-point calibration: Press Complete.
This completes the single-point calibration; the calibration record is
displayed (with the Nernst slope of -59.2 mV/pH at 25 °C).
Or continue with the two-point calibration:
8Thoroughly rinse the logger and electrode with deionized water.
9Immerse the logger in the second buffer solution.
10Start the measurement with Continue.
The AutoRead running... note appears and the electrode voltage U
(mV) and temperature are displayed.
The calibration record with the value of the slope (mV/pH) and the
value of the asymmetry (mV) is displayed as soon as a stable value
is recognized.
Calibration record
110
11Accept the calibration with Accept. The message Calibration
successful appears and the new calibration will now be used for
measurement.
If you press Cancel, the logger discards the new calibration and will
continue to use the previous calibration values.
Note
The calibration line is determined by linear regression.
Note
You can view the calibration records at any time (see section 5.4 V
THECALIBRATIONRECORDS).
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IEWING
WQL-pHCalibrating for pH measurements
Calibration
evaluation
After calibrating, the current system condition is evaluated. The asymmetry
and slope are evaluated separately. The probe symbol shows the worse case
evaluation of both.
.
DisplayAsymmetry [mV]Slope
[mV/pH]
-15 ... +15-60.5 ... -58
-20 ... +20-58 ... -57
-25 ... +25-61 ... -60.5
or
-57 ... -56
Clean the electrode
according to the electrode
operating manual
-30 ... +30-62 ... -61
or
-56 ... -50
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Calibrating for pH measurementsWQL-pH
5.4Viewing the calibration records
The last 10 calibration records are stored in the PC program and can be
recalled. Proceed as follows:
1In the Device menu, select the menu item, Calibrate.
2The calibration window appears.
3Click the menu item, Calibration record. A list with the existing
calibration records appears.
4Click the required record. The record is displayed.
5Return to the calibration window with Back.
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6Measuring directly
In conjunction with the pH logger, the WQL-Log PC program can directly
measure and display the pH value or corresponding electrode voltage of a
solution. The directly measured values are not stored in the logger.
Note
During calibration and direct measurement make sure that neither the
calibration or measurement solution nor the logger shaft are electrically
grounded (e.g. with a metal stand). Otherwise, this could result in erroneous
values.
Proceed as follows when you want to measure directly:
1Connect the WQL-pH logger to the PC with the USB cable.
2In the Device/Login menu, connect the logger to the WQL-Log PC
program.
3If there are any logged data, import them with the query (direct
measurement is not possible without importing the logged data ).
4In the Device menu, click the Measure menu item.
5Immerse the WQL-pH logger (with installed electrode) in the test
sample.
6The measured value window pops up with the pH or mV value
(depending on the setting) and the temperature value of the test
sample.
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7Terminate the direct measurement with Quit.
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LoggingWQL-pH
7Logging
Listed below are the typical operating steps with which to set up and carry out
a logging job. The chapters where the operating steps are described in detail
are also mentioned.
7.1Typical sequence of a logging job (checklist)
1Connect the logger to the PC with the USB cable.
2Start the WQL-Log program (see section 3.5 S
PROGRAM).
TARTINGTHE WQL-LOG
3Register the logger (see section CONNECTIONTOLOGGER ).
4If there are measured values in the logger, read them in (see
chapter 7.5 R
EADINGINDATA).
5Clear the logger memory (see section 7.6 OVERVIEWOFTHEDATA
WINDOW).
6Calibrate the logger with the electrode (see chapter 5 C
FORPH MEASUREMENTS).
ALIBRATING
7Set up the logging job and send it (see section 7.3 SETTINGTHE
PARAMETERSANDSTARTINGTHELOGGINGJOB).
8Disconnect the USB cable from the logger.
9If necessary, start the logger with the key button.
10Check the operation of the logger based on the behavior of the signal
LED (see section 7.4 S
CONDITIONSOFTHELOGGER).
IGNAL LED TOINDICATETHEOPERATING
11Tightly close the logger with the cap.
114
12Install the logger at the measuring location.
13After completion of the logging job: Connect the logger to the PC with
the USB cable (see step 1 etc.).
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7.2Setting up a logging job - setting parameters
You can set the following parameters for a logging job (i.e. the job to
determine and record measured values according to your requirements over
a certain period of time):
TabSettingSetting options
(default setting in bold)
RecordingIntervalz 1 second, 5 seconds,
10 seconds, 30 seconds
z 1 minute, 5 minutes, 10 minutes,
15 minutes, 30 minutes
z 1 hour, 2 hours, 3 hours,
6 hours, 9 hours, 12 hours,
24 hours
Startz Immediately
(when the setting mode is quit and the
logger is separated from the PC
program)
Stopz Time period
Measured
value ID
pH/mVMeasuring
mode
TimeAutomatic
time
adjustment
z Logger key button
(when the key button at the control
panel of the logger is pressed)
(1 hour ... 365 days)
z Memory full
(the loggers stops logging only when
the memory is full, i.e. when 600,000
datasets have been stored)
You can assign a measured value ID
(consisting of up to 20 alphanumerical
characters, no special characters) e.g.
the name of the measuring site).
Default setting: default
z pH
z mV
z Yes (date/time for the logger is
automatically synchronized with that
of the PC)
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z No
(date/time for the logger is set
manually)
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LoggingWQL-pH
7.3Setting the parameters and starting the logging job
To change one or several of the above listed settings proceed as follows:
1Connect the WQL-pH logger to the PC with the USB cable.
2Start the WQL-Log program.
The Login window appears.
3Confirm with OK. The WQL-Log program searches for the connection
with the logger.
4Confirm with OK.
5If the logger contains new data:
The prompt to read in the data appears.
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6Confirm the reading in of the data with OK.
The reading process can take some time (depending on the number
of datasets to be read in).
7When the reading of the measured values is completed, a message
appears (confirm with OK) and the prompt to erase the measured
value memory.
8Press OK or Cancel.
The data window appears with a graphic of the read-in data, no
matter whether or not the data memory was erased.
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LoggingWQL-pH
9In the Device menu, select the menu item, Set up logging job. A note
on calibration appears.
10Confirm with OK. The Logging tab appears, the first tab of the
window, Set up logging job.
118
11Interval: To set the logging interval, click the arrow on the right side
of the setting field. A drop-down menu appears with the possible
intervals. Select the required interval with a mouse click.
12Start: To set the start of the logging, click the arrow on the right side
of the setting field. A drop-down menu appears with the starting
times. Select the required starting time with a mouse click.
13Stop: To set the end of the logging, click the arrow on the right side
of the first setting field. A drop-down menu appears with the possible
settings. Select the required starting time with a mouse click. If Time period was selected:
14To set the time period of the logging, click the arrow on the right side
of the second setting field. A drop-down menu appears with the
possible time periods. Select the required time period with a mouse
click.
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15Enter the measured value ID (up to 20 alphanumerical characters, no
special characters).
16Click the pH/mV tab.
17Select the required mode for the logging, pH or mV.
18Click the Time tab.
19Select Yes or No for the automatic date/time adjustment. If No was
selected, click the arrows on the right side of the selection fields and
set the date and time for the logger.
Note
In the Logging tab, the memory capacity required with the selected settings
is displayed at the bottom (number x of 600,000 possible datasets).
Starting the
logging job
20To start the logging job, click the button, Send logging job. The
message, The settings have been successfully transferred appears.
21Confirm with OK. A window pops up with an overview of the logging
job just sent.
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22Confirm with OK. A note appears with the message that the logger
will now be disconnected from the PC program and, depending on the
setting, the information that the logging is started immediately or that
the logging is started when the logger key button is pressed.
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LoggingWQL-pH
Note
The setting routine for the logging job can be canceled at any time with the
Cancel button. In this case the logger does not start the logging job; instead,
the data window appears.
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7.4Signal LED to indicate the operating conditions of the
logger
Next to the key button on the control panel of the logger there is a signal LED.
When the logger is not connected to the WQL-Log PC program, this red LED
indicates the different operating conditions of the logger as follows:
Mode of flashingOperating condition
One short flashing per secondz The logging job is completed.
z The power supply of the logger
was interrupted. The logger has to
be connected to the PC program in
order to set the date and time.
Two short flashings, then a pause
of 3 seconds
The logger is ready to log and can be
started with the logger key button.
A short flashing every 15 secondsThe logging job is running (the logger
is logging).
Notes
z The flashing stops after 2 minutes to save energy. Pressing the logger
key button starts the flashing for 2 minutes again.
z Important: The logger can be started with the logger key button only while
the signal LED is flashing (if starting the logger with the key button was
set during the setting up of the logging job).
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LoggingWQL-pH
7.5Reading in data
Depending on the logging job, the WQL-pH logger measures for a certain
period of time and at certain intervals the pH value or mV value and the
temperature of a solution. The data is stored in the logger. The WQL-Log PC
program has to read in and store in a database the data before the data can
be displayed and processed.
Note
If the logger contains new data, the prompt to read in the data appears
automatically when the logger is connected to the PC program. If data stored
in the logger are not read in, the logger cannot be connected to the PC
program (data protection!).
To read in the data of the logging job, proceed as follows:
1Connect the WQL-pH logger to the PC with the USB cable.
2Start the WQL-Log program.
The Login window appears.
3Confirm with OK. The WQL-Log program searches for the connection
with the logger.
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4Confirm with OK.
5If the logger contains new data:
The prompt to read in the data appears.
6Confirm the reading in of the data with OK.
The reading process can take some time (depending on the number
of datasets to be read in).
7When the reading of the measured values is completed, a message
appears (confirm with OK) and the prompt to erase the measured
value memory.
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8Press OK or Cancel.
The data window appears with a graphic of the read-in data, no
matter whether or not the data memory was erased.
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LoggingWQL-pH
Note
When the logger is connected to the WQL-Log PC program, any existing
new measured values must be read in. If data stored in the logger are not
read in, the logger cannot be connected to the PC program (data
protection!).
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WQL-pHLogging
Number of
selected
datasets
Name and series number of
the connected logger
Menu bar
Measured value ID
Name and series number of
the logger that provided the
data
7.6Overview of the data window
The measurement datasets read in from the logger are stored in a database
and graphically displayed in a data window.
The data window is structured as follows:
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LoggingWQL-pH
7.7Clearing the logger memory
The query to clear the logger memory always appears after the data from the
logger have been read in to the database. If the logger memory is not cleared
after the data has been read in, the query to clear the data reappears during
the setting up of a new logging job. At this point of time the logger memory
has to be cleared so the logging job can be set up.
You can also clear the logger memory manually.
Note
There is no danger of clearing data that have not been read in as the data
stored in the logger have to be read in (compulsory guide) when the logger is
connected. If data stored in the logger are not read in, the logger cannot be
connected to the PC program.
Proceed as follows to clear the logger memory:
1In the Device menu, select the menu item, Memory/Clear memory.
2A security prompt appears. Confirm the security prompt with OK.
3The data is cleared. A message appears after the clearing that
informs you that the memory was cleared. Confirm the message with
OK.
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WQL-pHProcessing measurement data
8Processing measurement data
8.1Querying data
The data recorded by the logger and stored in the database can be displayed
as a graphic via the Query menu item. Proceed as follows:
Querying current
data
1In the Query menu, click the menu item, New.
The New query window appears.
2The Standard tab appears when a logger is connected.
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3To graphically display the data last imported from the connected
logger, click Apply. The data appear as a graphic, broken according
to pH value or voltage value and temperature.
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Processing measurement dataWQL-pH
Note
The series number of the connected logger is displayed in the bottom left
corner of the data window (see section 7.6 O
VERVIEWOFTHEDATAWINDOW).
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WQL-pHProcessing measurement data
Querying user-
defined data
1Click the User-defined tab in the New query window. The User-
defined tab appears immediately in the Query menu if no logger is
connected.
2If you only want to query datasets with a certain measured value ID,
check off the box for Measured value ID and then click the arrow next
to the selection field for the measured value ID. Select the required
measured value ID.
3In the Sensors field, select one or two measured values to be
queried.
4If you only want to query datasets with a certain date, check off the
box for Time period and then click the arrow next to the selection
fields for the time (from and to). Select the required date in both fields.
Next to the date fields are the time fields where you enter the time
(hours, minutes, seconds) either with the arrow keys or by entering
the number with the keyboard.
5Click Apply to display the selected datasets.
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Processing measurement dataWQL-pH
6The queried data appear as a graphic.
Note
Always make the settings for the user-defined query from the top down , as
the data are filtered in this sequence.
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WQL-pHProcessing measurement data
8.2Exporting data
The data displayed as a graphic with the aid of the Query menu can be
exported to a *.csv file. In this form the data can be read and processed with
Microsoft Excel and many other spreadsheets.
Note
If the number of datasets to be exported is more than 60,000 and the data
should be processed with Microsoft Excel 2007 or older, export the data with
the function, "Export as *.csv file (splitted)", as Excel versions 2007 and older
can store only 60,000 datasets in one worksheet. The number of datasets is
given in the header of the graphic, next to the series number of the logger that
provided the data.
Proceed as follows to export the datasets displayed as a graphic:
1In the Export menu, click the menu item, Export as *.csv file or Export
as *.csv file (splitted).
The Save as window appears.
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2Save the data to be exported in the required directory and with the
required file name. The WQL-Log PC program suggests a file name.
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Processing measurement dataWQL-pH
Note
If the number of datasets to be exported is more than 60,000 and the data is
exported with the function, Export as *.csv file (splitted), the WQL-Log
program automatically divides the data into files with max. 60,000 datasets
and adds the number 1, 2 etc. to the suggested file names.
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WQL-pHInfo menus
9Info menus
9.1Database information
The data read in from the logger are saved in a database. You can query the
name, location, type and utilization (in %) of this database.
To do so, proceed as follows:
Database
information
1In the File menu, click the menu item, Database info.
The Database info window appears.
2Confirm with OK. The Database info window disappears.
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Note
The size of a database file can be 4 GB max. When this amount of data is
stored, a new database file must be created. The new database file is
created in the Device/Create new database menu.
100,000 datasets need approx. 6.5 MB. Thus the database can store approx.
15 million datasets.
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Info menusWQL-pH
9.2Device information
If a logger is connected to the PC, you can query the device name, series
number and firmware version of the connected logger via the Device/Info
menu item.
To do so, proceed as follows:
Device information
1In the Device menu, click the menu item, Info.
The Device info window appears.
2Confirm with OK. The Device info window disappears.
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WQL-pHInfo menus
9.3Program info
In the Help/About WQL-Log menu you can look up which version of the WQL-
Log PC program was installed.
To do so, proceed as follows:
1In the Help menu, click the About WQL-Log menu item.
The About WQL-Log
Program info
window appears.
2Confirm with OK. The About WQL-Log window disappears.
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Resetting the loggerWQL-pH
10Resetting the logger
You can reset to the default condition the logger and the PC program with its
settings.
In the default condition, the settings are as follows:
Configuration parametersSetting
Logging interval1 second
Start of the logging Logger key button
End of the loggingTime period
1 hour
Measured value IDNone
Measuring mode pH
Date, time01.01.2008, 00:00
Resetting to
default condition
CalibrationDefault values
(Nernst slope = -59,2 mV/pH
at 25 °C, asymmetry = 0 mV)
To reset the logger and PC program to the default condition, proceed as
follows:
1In the Device menu, click the menu item, Reset. A security prompt
appears.
2Confirm with OK. The settings are reset to the default condition.
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WQL-pHMaintenance, cleaning, storage
11Maintenance, cleaning, storage
11.1General maintenance instructions
General
information
z Normally, all screw joints of the logger housing can be opened and closed
by hand, without using any tools. If necessary, use a paper towel so you
get a better grip on the parts. Should the coupling ring for the electrode be
stuck, for example after a long-term logging job, you can use a wrench
(wrench size 16 mm) on the hexagon.
z In the screwed condition, no gaps may be visible at the joints.
z Change the electrode in a clean and preferably dry environment.
Thoroughly dry all parts. Moisture in the screw joint can affect the
functioning of the logger.
z Prior to unscrewing any screw joints, clean the exterior of the logger (see
section 11.2 E
XTERIORCLEANING) and dry it thoroughly.
z Prior to reassembly, clean all internal and external threads thoroughly.
Contaminated threads can get stuck by-and-by. Normally, the threads can
be screwed together without using any effort and without noticeable
grinding (sand particles).
z Clean all O-rings prior to reassembly. Dirt, e.g. fibers, on the O-rings can
affect the tightness.
11.2Exterior cleaning
Clean the logger with tapwater and a soft sponge or brush. Remove the
protective hood. The electrode should be cleaned with a soft toothbrush or
paintbrush under running tap water.
Note
For the cleaning of the electrode please also read the operating manual of
the electrode.
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Maintenance, cleaning, storageWQL-pH
11.3Replacing the electrode
Note
When replacing the electrode the general maintenance instructions in
section 11.1 must be followed.
The electrode is replaced in the same way as it was installed during the
commissioning (see section 3.1.3 I
NSTALLINGTHEELECTRODE).
11.4Battery
11.4.1 Battery service life
The logger has an energy saving feature. The service life of the battery
depends very much on the usage of the logger, especially on the measuring
interval. The service life to be expected of a full battery (2600 mAh) can be
estimated by means of the following table:
When inserting the battery, note down the installation time on the battery to
be able to estimate the remaining operational lifetime. When a battery is
inserted, the logger consumes a small amount of energy even when it is not
working. Therefore, we recommend to remove the battery during longer
measuring breaks.
11.4.2 Battery replacement
138
Note
When replacing the battery the general maintenance instructions in
section 11.1 must be followed.
The battery is replaced in the same way as it is inserted during the
commissioning (see section 3.1.2 I
NSERTINGTHEBATTERY).
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WQL-pHMaintenance, cleaning, storage
Data preservationAfter the battery was removed all stored measured values are retained. Only
the date and time are reset to the default condition (01.01.2008, 00:00) when
the power supply is interrupted.
We recommend to connect the logger to the PC for the time of the battery
replacing process so the logger is supplied with power via the USB
connection while there is no battery inserted. Thus the date and time will be
retained. Otherwise, the date and time will be set the next time the logger is
connected to the PC with the WQL-Log PC program. Depending on the
setting in the WQL-Log program, this is either done automatically when the
connection is established (synchronization with the system time of the PC),
or manually.
State of the logger after the power supply was interrupted (battery empty or
removed, see also section 7.4 S
CONDITIONSOFTHELOGGER):
IGNAL LED TOINDICATETHEOPERATING
Case 1: Logging
job active at the
time of
interruption
Case 2: No logging
job at the time of
interruption
Case 3: Battery
removed for
storage
z The logging job is terminated.
z The time is reset to the default condition.
z All data logged up to this point of time are retained and are automatically
saved on the PC the next time the logger is connected to the PC.
z The terminated logging job can be continued with a corresponding new
logging job. To do so, the time must be set anew if the automatic time
synchronization is switched off.
z The time is reset to the default condition.
z Prior to setting up the next logging job, you have to set the time if the
automatic time synchronization is switched off.
z The time is reset to the default condition.
z Prior to setting up the next logging job, you have to set the time if the
automatic time synchronization is switched off.
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Maintenance, cleaning, storageWQL-pH
12
11.5Storage
For longer storage periods we recommend to leave the electrode installed
and to remove the battery and store it separately. Plug the watering cap filled
with the suitable reference electrolyte on the clean electrode (see electrode
operating manual).
If the logger is stored without the electrode, close the electrode receptacle
with the enclosed blind plug to protect the plug connector from dirt and
moisture. When doing so make sure that both O-rings of the blind plug are in
place (pos. 1 and 2 in Fig. 11-1).
Fig. 11-1 Blind plug
Store the logger in a dry place while observing the storing conditions
according to chapter 11.5 S
TORAGE. Low temperatures usually delay the
aging of the electrode.
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WQL-pHWhat to do if...
12What to do if...
12.1Calibration and measuring
Lengthy stability
check with
AutoRead
Implausible
measured values
Logger does not
react
CauseRemedy
No stable measured valueProvide stable measuring conditions
(e.g. temperature)
CauseRemedy
– Electrode not installed or
defective
– No calibration performed– Calibrate
– Watering cap still on the
electrode
– Electrode contaminated– Clean electrode
– Liquid penetrated into the plug
connector
CauseRemedy
– Battery depleted– Insert new battery (see
– Check electrode and electrode
connection
– Pull off watering cap and calibrate
– Rinse the plug connector with
deionized water, clean and dry it
section 11.4)
System cannot be
calibrated
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CauseRemedy
– Slope of the electrode not within
tolerance (see section 5.3)
– Slope of the electrode too low– Replace electrode
– Asymmetry of the electrode too
high
– Condition the electrode
– If the slope is still outside the
tolerance, replace the electrode
– Check the buffer solutions
– Replace electrode
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What to do if...WQL-pH
12.2Communication of the logger and PC program
Reading in of
measured values
is aborted
CauseRemedy
– Communication problem– Repeat the read in process
Data logging of the
logger aborted
CauseRemedy
– Power supply interrupted– Connect the logger to the PC
program and set up logging job.
– Make sure that the logger is
supplied with power (battery)
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WQL-pHTechnical data
13Technical data
13.1Measurement characteristics
Measuring
Potentiometric measurement by means of combination electrode
principle
pH measurementMeasuring range **0.000 ... +20.000
Resolution0.001
Accuracy **
≤ 0.005 ± 1 digit
mV measurementMeasuring range **-1000.0 ... +1000.0 mV
Resolution0,1 mV
Temperature
measurement
Accuracy **
Temperature sensorAutomatic recognition of the temperature
≤ 0.2 mV ± 1 digit
sensor of the electrode:
NTC 30 (30 k:at 25 °C / 77 °F) or Pt1000
Measuring range **-5.0 ... 105 °C (+23 ... 221 °F)
Resolution0.1 K
Accuracy **
≤ 0.1 K ± 1 digit
** Note:
The measuring ranges and accuracy exclusively refer to the measuring
electronics of the logger without the electrode. For the measuring ranges
and accuracy of the operable logger, the specifications of the electrode and
buffer solutions have also to be taken into account.
Logger functionMeasuring intervaladjustable:
1 / 5 / 10 / 30 s
1 / 5 / 10 / 15 / 30 min
1 / 2 / 3 / 6 / 9 / 12 / 24 h
Capacity of the data
600.000 measurement datasets
memory
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Technical dataWQL-pH
Thread M6
13.2Application characteristics
Measuring
Allowed temperature range0 ... 60 °C (32 ... 140 °F)
medium
Allowed pH range2 ... 12
Pressure
IP 68 (1 x 10
resistance
The WQL-pH logger meets all requirements according to article 3(3) of 97/
23/EC ("pressure equipment directive").
Storage
Recommended storing typeElectrode installed with the watering cap put
conditions
Storage temperature-25 ... 65 °C (-13 ... 149 °F)
13.3General data
Test certificatesCE
6
Pa or 10 bar)
on, or electrode receptacle closed with blind
plug, battery removed